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The imaginary-time path integral representation of the canonical partition function of a quantum system and non-equilibrium work fluctuation relations are combined to yield methods for computing free energy differences in quantum systems…

Statistical Mechanics · Physics 2009-11-13 Ramses van Zon , Lisandro Hernandez de la Pena , Gilles H. Peslherbe , Jeremy Schofield

Thermodynamics is the phenomenological theory of heat and work. Here we analyze to what extent quantum thermodynamic relations are immune to the underlying mathematical formulation of quantum mechanics. As a main result, we show that the…

Quantum Physics · Physics 2016-04-21 Bartłomiej Gardas , Sebastian Deffner , Avadh Saxena

Determining the statistics of work done on a quantum system while strongly coupled to a reservoir is a formidable task, requiring the calculation of the full eigenspectrum of the combined system and reservoir. Here we show that this issue…

Quantum Physics · Physics 2026-05-28 Owen Diba , Harry J. D. Miller , Jake Iles-Smith , Ahsan Nazir

Simple constructions and protocols are demonstrated to allow the implementation of universal quantum computation on an arbitrarily large quantum system by controlling a fixed number of spins, vastly reducing the engineering requirements in…

Quantum Physics · Physics 2009-04-23 Alastair Kay

We show that the quantum Jarzynski equality generalizes to $\mathcal{PT}$-symmetric quantum mechanics with unbroken $\mathcal{PT}$-symmetry. In the regime of broken $\mathcal{PT}$-symmetry the Jarzynski equality does not hold as also the…

Statistical Mechanics · Physics 2015-04-22 Sebastian Deffner , Avadh Saxena

Work in isolated quantum systems is a random variable and its probability distribution function obeys the celebrated fluctuation theorems of Crooks and Jarzynski. In this study, we provide a simple way to describe the work probability…

Quantum Physics · Physics 2019-12-04 Eric G. Arrais , Diego A. Wisniacki , Augusto J. Roncaglia , Fabricio Toscano

The interest in active matter stimulates the need to generalize thermodynamic description and relations to active matter systems, which are intrinsically out of equilibrium. One important example is the Jarzynski relation, which links the…

Statistical Mechanics · Physics 2023-05-31 Grzegorz Szamel

We consider closed quantum systems (into which baths may be integrated) that are driven, i.e., subject to time-dependent Hamiltonians. As a starting point we assume that, for systems initialized in microcanonical states at some energies,…

Quantum Physics · Physics 2021-06-30 Lars Knipschild , Andreas Engel , Jochen Gemmer

One particle in a classical perfect gas is driven out of equilibrium by changing its mass over a short time interval. The work done on the driven particle depends on its collisions with the other particles in the gas. This model thus…

Statistical Mechanics · Physics 2014-04-22 T. G. Philbin , J. Anders

In this work, we show that a universal quantum work relation for a quantum system driven arbitrarily far from equilibrium extend to $\mathcal{PT}$-symmetric quantum system with unbroken $\mathcal{PT}$ symmetry, which is a consequence of…

Statistical Mechanics · Physics 2018-01-17 Bo-Bo Wei

We show that quantum optical systems preserving the total number of excitations admit a simple classification of possible resonant transitions (including effective), which can be classified by analizying the free Hamiltonian and the…

Quantum Physics · Physics 2007-05-23 A. B. Klimov , I. Sainz

There is an extensive philosophical literature on the interrelated issues of identity, individuality, and distinguishability in quantum systems. A key consideration is whether quantum systems are subject to a strong form of individuality…

Quantum Physics · Physics 2023-09-07 Ruth E. Kastner

The separation of internal energy into heat and work in quantum thermodynamics is a controversial issue for a long time, and we revisit and solve this problem in this work. It is shown that the Hamiltonian plays dual roles for a quantum…

Quantum Physics · Physics 2025-01-03 Tao Zhou , Jiangyang Pu , Xiaohua Wu

The Jarzynski Equality is a well-known and widely used identity, relating the free energy difference between two states of a system to the work done over some arbitrary, nonequilibrium transformation between the two states. Despite being…

Statistical Mechanics · Physics 2018-12-18 Stuart J. Davie , Owen G. Jepps , Lamberto Rondoni , James C. Reid , Debra J. Searles

Based on previous studies in a single particle system in both the integrable [Jarzynski, Quan, and Rahav, Phys.~Rev.~X {\bf 5}, 031038 (2015)] and the chaotic systems [Zhu, Gong, Wu, and Quan, Phys.~Rev.~E {\bf 93}, 062108 (2016)], we study…

Quantum Physics · Physics 2017-03-15 Qian Wang , H. T. Quan

We obtain the Crooks and the Jarzynski non-equilibrium fluctuation relations using a direct quantum-mechanical approach for a finite system that is either isolated or coupled not too strongly to a heat bath. These results were hitherto…

Statistical Mechanics · Physics 2012-07-11 Doron Cohen , Yoseph Imry

Decoherence in Markovian systems can result indirectly from the action of a system Hamiltonian which is usually fixed and unavoidable. Here, we show that in general in Markovian systems, because of the system Hamiltonian, quantum…

Quantum Physics · Physics 2008-08-13 Manas K. Patra , Peter G. Brooke

We show that the rare events present in dissipated work that enters Jarzynski equality, when mapped appropriately to the phenomenon of large deviations found in a biased coin toss, are enough to yield a quantitative work probability…

Statistical Mechanics · Physics 2015-05-18 Arnab Saha , Sagar Chakraborty , Jayanta K. Bhattacharjee

A theory of transformation is presented for the diagonalization of a Hamiltonian that is quadratic in creation and annihilation operators or in coordinates and momenta. It is the systemization and theorization of Dirac and…

Mathematical Physics · Physics 2009-08-07 Ming-wen Xiao

The Jarzynski relation is a recently discovered result relating the average exponential of the work done under nonequilibrium conditions to an equilibrium free energy difference. We illustrate this remarkable relation by considering the…

Statistical Mechanics · Physics 2007-05-23 Rhonald C. Lua