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The validity of the Jarzynski equation for a very simple, exactly solvable quantum system is analyzed. The implications of two different definitions of work proposed in the literature are investigated. The first one derives from…

Statistical Mechanics · Physics 2009-11-11 A. Engel , R. Nolte

The quantum Jarzynski equality is an important theorem of modern quantum thermodynamics. We show that the Jarzynski equality readily generalizes to relativistic quantum mechanics described by the Dirac equation. After establishing the…

Statistical Mechanics · Physics 2015-09-30 Sebastian Deffner , Avadh Saxena

Since the first suggestion of the Jarzynski equality many derivations of this equality have been presented in both, the classical and the quantum context. While the approaches and settings greatly differ from one to another, they all appear…

Quantum Physics · Physics 2016-07-20 F. Jin , R. Steinigeweg , H. De Raedt , K. Michielsen , M. Campisi , J. Gemmer

We present a general scheme to obtain work distribution in closed systems under continuous quantum histories of corresponding "power" operator. The scheme is tested by analytically calculating the quantum work distribution for a prototype…

Statistical Mechanics · Physics 2013-04-24 Huanan Li , Jian-Sheng Wang

We give a quantum version of the Jarzynski relation between the distribution of work done over a certain time-interval on a system and the difference of equilibrium free energies. The main new ingredient is the identification of work…

Condensed Matter · Physics 2015-05-26 Wojciech De Roeck , Christian Maes

In this note, we will discuss how to compactly express and prove the Jarzynski identity for an open quantum system with dissipative dynamics. We will avoid explicitly measuring the work directly, which is tantamount to continuously…

Statistical Mechanics · Physics 2008-11-07 Gavin E. Crooks

Nonequilibrium work-Hamiltonian connection for a microstate plays a central role in diverse branches of statistical thermodynamics (fluctuation theorems, quantum thermodynamics, stochastic thermodynamics, etc.). We show that the change in…

Statistical Mechanics · Physics 2017-02-03 P. D. Gujrati

The Jarzynski equality equates the mean of the exponential of the negative of the work (per fixed temperature) done by a changing Hamiltonian on a system, initially in thermal equilibrium at that temperature, to the ratio of the final to…

High Energy Physics - Theory · Physics 2012-07-17 Don N. Page

The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasi-static process. This fluctuation…

Quantum Physics · Physics 2025-08-21 Konstantin Beyer , Walter T. Strunz

We develop a mathematical approach to the nonequilibrium work theorem which is traditionally referred to in statistical mechanics as Jarzynski's identity. We suggest a mathematically rigorous formulation and proof of the identity.

Probability · Mathematics 2008-03-31 Evelina Shamarova

The universal quantum work relation connects a functional of an arbitrary observable averaged over the forward process to the free energy difference and another functional averaged over the time-reversed process. Here, we ask the question…

Quantum Physics · Physics 2012-04-18 Arun Kumar Pati , Mamata Sahoo , Biswajit Pradhan

In open quantum systems, a clear distinction between work and heat is often challenging, and extending the quantum Jarzynski equality to systems evolving under general quantum channels beyond unitality remains an open problem in quantum…

Quantum Physics · Physics 2020-08-10 Akira Sone , Yi-Xiang Liu , Paola Cappellaro

We show a practical application of the Jarzynski equality in quantum computation. Its implementation may open a way to solve combinatorial optimization problems, minimization of a real single-valued function, cost function, with many…

Quantum Physics · Physics 2010-07-28 Masayuki Ohzeki

It has been established that the inclusive work for classical, Hamiltonian dynamics is equivalent to the two-time energy measurement paradigm in isolated quantum systems. However, a plethora of other notions of quantum work has emerged, and…

Statistical Mechanics · Physics 2021-04-08 Akira Sone , Sebastian Deffner

A quantum analogue of the Jarzynski equality is constructed. This equality connects an ensemble average of exponentiated work with the Helmholtz free-energy difference in a nonequilibrium switching process subject to a thermal heat bath. To…

Statistical Mechanics · Physics 2009-10-31 Satoshi Yukawa

A universal quantum work relation is proved for isolated time-dependent Hamiltonian systems in a magnetic field as the consequence of microreversibility. This relation involves a functional of an arbitrary observable. The quantum Jarzynski…

Statistical Mechanics · Physics 2009-11-13 David Andrieux , Pierre Gaspard

We present a generalization of Jarzynski's Equality, applicable to quantum systems, relating discretized mechanical work and free-energy changes. The theory is based on a step-wise pulling protocol. We find that work distribution functions…

Quantum Physics · Physics 2012-09-21 Van A. Ngo , Stephan Haas

The Jarzynski equality, which relates equilibrium free-energy difference to an average of non-equilibrium work, plays a central role in modern non-equilibrium statistical thermodynamics. In this paper, we study a weaker consequence of this…

Statistical Mechanics · Physics 2026-01-06 Dani R. Castellanos , Petr Jizba

The relation between the distribution of work performed on a classical system by an external force switched on an arbitrary timescale, and the corresponding equilibrium free energy difference, is generalized to quantum systems. Using the…

Statistical Mechanics · Physics 2007-05-23 Shaul Mukamel

Research on the out-of-equilibrium dynamics of quantum systems has so far produced important statements on the thermodynamics of small systems undergoing quantum mechanical evolutions. Key examples are provided by the Crooks and Jarzynski…

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