Related papers: Comparison of far-from-equilibrium work relations
The connection between work and changes in the Hamiltonian for a system with a time-dependent Hamiltonian has recently been called into question, casting doubt on the usefulness of the Jarzynski equality for calculating free energy changes.…
Far-from-equilibrium systems are ubiquitous in nature. They are also rich in terms of diversity and complexity. Therefore, it is an intellectual challenge to be able to understand the physics of far-from-equilibrium phenomena. In this paper…
Thermodynamic length is a path function that generalizes the notion of length to the surface of thermodynamic states. Here, we show how to measure thermodynamic length in far-from-equilibrium single molecule experiments using the work…
We show that the recently postulated non-standard definition of work proportional to force variation rather than to displacement [A. Imparato and L. Peliti, cond-mat arXiv:0706.1134v1] is thermodynamically inconsistent at both microscopic…
We analyze the microscopic evolution of a system undergoing a far-from-equilibrium thermodynamic process. Explicitly accounting for the degrees of freedom of participating heat reservoirs, we derive a hybrid result, similar in form to both…
The work content of non-equilibrium systems in relation to a heat bath is often analyzed in terms of expectation values of an underlying random work variable. However, we show that when optimizing the expectation value of the extracted…
The Jarzynski equality, which relates equilibrium free-energy difference to an average of non-equilibrium work, plays a central role in modern non-equilibrium statistical thermodynamics. In this paper, we study a weaker consequence of this…
We give a quantum version of the Jarzynski relation between the distribution of work done over a certain time-interval on a system and the difference of equilibrium free energies. The main new ingredient is the identification of work…
Generalizing response theory of open systems far from equilibrium is a central quest of nonequilibrium statistical physics. Using stochastic thermodynamics, we develop an algebraic method to study the response of nonequilibrium steady state…
Jarzynski's identity for the free energy difference between two equilibrium states can be viewed as a special case of a more general procedure based on phase space mappings. Solving a system's equation of motion by approximate means…
The Kawasaki nonlinear response relation, the transient fluctuation theorem, and the Jarzynski nonequilibrium work relation are all expressions that describe the behavior of a system that has been driven from equilibrium by an external…
Small thermodynamic systems exhibit peculiar behavior different from that observed in long-scale systems. Non-equilibrium processes taking place in those systems are strongly influenced by the presence of fluctuations which can be large.…
Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult. For systems that undergo…
The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains…
We experimentally realize protocols that allow to extract work beyond the free energy difference from a single electron transistor at the single thermodynamic trajectory level. With two carefully designed out-of-equilibrium driving cycles…
We discuss the conditions for which the non-equilibrium work relation is valid by means of thermodynamic and microscopic arguments.
Fluctuation relations (FRs) are among the few existing general results in non-equilibrium systems. Their verification requires the measurement of the total work (or entropy production) performed on a system. Nevertheless in many cases only…
Fluctuation theorems have become an important tool in single molecule biophysics to measure free energy differences from non-equilibrium experiments. When significant coarse-graining or noise affect the measurements, the determination of…
Nonthermal fixed points are paradigmatic far-from-equilibrium phenomena of relevance to high-energy physics, cosmology, and cold atomic gases. We propose that, despite their intrinsically nonequilibrium nature, nonthermal fixed points give…
Ergotropy, as a measure for extractable work from a quantum system, has garnered significant attention due to its relevance in quantum thermodynamics and information processing. In this work, the dynamics of ergotropy will be investigated…