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The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

Statistical Mechanics · Physics 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

This article presents a heuristic combination of the local and global formulations of the second law of thermodynamics that suggests the possibility of theoretical existence of thermodynamics processes with positive and negative entropy…

General Physics · Physics 2010-12-06 Jose Iraides Belandria

Validity of local equilibrium has been questioned for non-equilibrium systems which are characterized by delayed response. In particular, for systems with non-zero thermodynamic inertia, the assumption of local equilibrium leads to negative…

Statistical Mechanics · Physics 2015-07-29 K. S. Glavatskiy

The second law of thermodynamics states that for a thermally isolated system entropy never decreases. Most physical processes we observe in nature involve variations of macroscopic quantities over spatial and temporal scales much larger…

High Energy Physics - Theory · Physics 2017-02-20 Paolo Glorioso , Hong Liu

We show for a large class of interacting particle systems that whenever the stationary measure is not reversible for the dynamics, then the mean entropy production in the steady state is strictly positive. This extends to the thermodynamic…

Statistical Mechanics · Physics 2015-05-26 C. Maes , F. Redig , M. Verschuere

The second law of thermodynamics states that entropy production cannot be negative. Recent developments concerning uncertainty relations in stochastic thermodynamics, such as thermodynamic uncertainty relations and speed limits, have…

Statistical Mechanics · Physics 2023-10-09 Tomohiro Nishiyama , Yoshihiko Hasegawa

The entropy production rate is a key quantity in non-equilibrium thermodynamics of both classical and quantum processes. No universal theory of entropy production is available to date, which hinders progress towards its full grasping. By…

Quantum Physics · Physics 2020-12-18 Alessio Belenchia , Luca Mancino , Gabriel T. Landi , Mauro Paternostro

The reliability of physical theories depends on whether they agree with well established physical laws. In this work, we address the compatibility of the Hamiltonian formulation of linear-response theory with the Second Law of…

Statistical Mechanics · Physics 2020-01-16 Pierre Nazé , Marcus V. S. Bonança

We consider a finite chain of non-linear oscillators coupled at its ends to two infinite heat baths which are at different temperatures. Using our earlier results about the existence of a stationary state, we show rigorously that for…

chao-dyn · Physics 2015-06-24 Jean-Pierre Eckmann , Claude-Alain Pillet , Luc Rey-Bellet

We discuss fundamental features of the local expression for the entropy production rate of the nonequilibrium quantum dynamics of open systems and its relations to memory effects and the spectrum of the generator of the dynamics. Defining…

Quantum Physics · Physics 2026-03-03 Irene Ada Picatoste , Alessandra Colla , Heinz-Peter Breuer

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…

Statistical Mechanics · Physics 2018-03-14 Hyun-Myung Chun , Jae Dong Noh

Linear, irreversible thermodynamics predicts that the entropy production rate can become negative. We demonstrate this prediction for metals under AC-driving whose conductivity is well-described by the Drude-Sommerfeld model. We then show…

Statistical Mechanics · Physics 2022-01-26 Marcus V. S. Bonança , Sebastian Deffner

The irreversible currents and entropy production rate of a dilute colloidal suspension are calculated using the linear irreversible thermodynamics and the linear response theory. The \anomalous" or \hidden" entropy recently discussed in the…

Statistical Mechanics · Physics 2018-08-24 Kunimasa Miyazaki , Yohei Nakayama , Hiromichi Matsuyama

Fluctuating entropy production is studied for a set of linearly coupled complex fields. The general result is applied to non-equilibrium fluctuating hydrodynamic equations for coarse-grained fields (density, temperature and velocity), in…

Statistical Mechanics · Physics 2012-07-09 Giacomo Gradenigo , Andrea Puglisi , Alessandro Sarracino

We study the entropy production in non-equilibrium quantum systems without dissipation, which is generated exclusively by the spontaneous breaking of time-reversal invariance. Systems which preserve the total energy and particle number and…

Statistical Mechanics · Physics 2020-03-26 Mihail Mintchev , Paul Sorba

Entropy production provides a general way to state the second law of thermodynamics for non-equilibrium scenarios. In open quantum system dynamics, it also serves as a useful quantifier of the degree of irreversibility. In this work we shed…

Quantum Physics · Physics 2020-10-06 Giorgio Zicari , Matteo Brunelli , Mauro Paternostro

We report on a numerical experiment performed to analyze fluctuations of the entropy production in turbulent thermal convection, a physical configuration that represents here a prototypical case of an out-of-equilibrium dissipative system.…

Statistical Mechanics · Physics 2016-07-12 Francesco Zonta , Sergio Chibbaro

The second law of nonequilibrium thermodynamics within the open system paradigm (a small system coupled to one or multiple baths) is derived. This is done by showing positivity of entropy production for arbitrary Hamiltonian dynamics for a…

Statistical Mechanics · Physics 2020-08-28 Philipp Strasberg

The entropy production in dissipative processes is the essence of the arrow of time and the second law of thermodynamics. For dissipation of quantum systems, it was recently shown that the entropy production contains indeed two…

Quantum Physics · Physics 2020-10-28 Camille L. Latune , Ilya Sinayskiy , Francesco Petruccione

We derive an exact (classical and quantum) expression for the entropy production of a finite system placed in contact with one or several finite reservoirs each of which is initially described by a canonical equilibrium distribution.…

Statistical Mechanics · Physics 2015-05-13 Massimiliano Esposito , Katja Lindenberg , Christian Van den Broeck
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