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4-n-octyl-4-cyanobiphenyl (8CB) has been recently shown to display an unusual sequence of phases when confined into porous silicon (PSi). The gradual increase of oriented short-range smectic (SRS) correlations in place of a phase transition…

Optical birefringence measurements on a rod-like liquid crystal (8OCB), imbibed in silica channels (7 nm diameter), are presented and compared to the thermotropic bulk behavior. The orientational and positional order of the confined liquid…

Soft Condensed Matter · Physics 2015-05-20 Andriy V. Kityk , Patrick Huber

We report the observation of a doubly-periodic surface defect-pattern in the liquid crystal 8CB, formed during the nematic--smectic A phase transition. The pattern results from the antagonistic alignment of the 8CB molecules, which is…

Soft Condensed Matter · Physics 2013-05-21 O. V. Manyuhina , G. Tordini , W. Bras , J. C. Maan , P. C. M. Christianen

We present an x-ray study of freely suspended hexatic films of the liquid crystal 3(10)OBC. Our results reveal spatial inhomogeneities of the bond-orientational (BO) order in the vicinity of the hexatic-smectic phase transition and the…

It has been found that in mixtures of nematic E7 and smectogenic cholesteryl oleyl carbonate (COC) the S$_A$-N* transition temperature is substantially (by ~20 K) increased, as compared with pure COC, at E7 concentrations around ~40%.…

We study the layer-to-layer diffusion in smectic-A liquid crystals of colloidal hard rods with different length-to-diameter ratios using computer simulations. The layered arrangement of the smectic phase yields a hopping-type diffusion due…

Soft Condensed Matter · Physics 2010-06-16 Alessandro Patti , Djamel El Masri , René van Roij , Marjolein Dijkstra

We study a model for the Nematic--Smectic-A (NA) transition in aerogel, and find that even arbitrarily weak quenched disorder (i.e., low aerogel density) destroys translational (smectic) order. Ignoring elastic anharmonicities, but keeping…

Soft Condensed Matter · Physics 2009-10-30 Leo Radzihovsky , John Toner

The liquid crystalline compound, forming the glass of the smectic C$_A$* phase, is investigated by the X-ray diffraction in the 18-298 K range. The characteristic distances within the smectic C$_A$* phase are determined. The electron…

We study a new mechanism of active matter confinement of a thin, active nematic sample consisting of microtubules, activated by Adenosine Triphosphate (ATP), placed between a slab of passive liquid crystal, the compound 8CB, and water. The…

Soft Condensed Matter · Physics 2024-07-03 M. Carme Calderer , Lingxing Yao , Longhua Zhao , Dmitry Golovaty , Jordi Ignés-Mullol , Francesc Sagués

We study smectic-liquid-crystal order in a cell with a heterogeneous substrate imposing surface random positional and orientational pinnings. Proposing a minimal random elastic model, we demonstrate that, for a thick cell, the smectic state…

Soft Condensed Matter · Physics 2015-03-20 Quan Zhang , Leo Radzihovsky

We report a molecular dynamics simulation demonstrating that the Smectic B crystalline phase (Cr-B), commonly observed in mesogenic systems of anisotropic molecules, can be formed by a system of identical particles interacting via a…

Soft Condensed Matter · Physics 2013-12-16 A. Metere , T. Oppelstrup , S. Sarman , A. Laaksonen , M. Dzugutov

We report on strong pretransitional effects across the isotropic liquid-plastic crystal melting temperature in linear and nonlinear dielectric response. Studies were carried out for cyclooctanol (C8H16O) in the unprecedented range of…

Soft Condensed Matter · Physics 2019-12-10 A. Drozd-Rzoska , S. Starzonek , S. J. Rzoska , J. Łoś , Z. Kutnjak , S. Kralj

Charged colloids can form ordered structures like Wigner crystals or glasses at very low concentrations due to long-range electrostatic repulsions. Here, we combine small-angle x-ray scattering (SAXS) and optical experiments with…

Soft Condensed Matter · Physics 2025-03-19 Hanna Anop , Laura Dal Compare , Frederic Nallet , Achille Giacometti , Eric Grelet

Nanoconfined liquid crystals (LCs) and their nanocomposites are driving the next generation of photonic applications. Consequently, deepening our understanding of mesophase stability, defect topology, and the dynamic response of LCs at the…

We present an x-ray study of liquid crystal membranes in the vicinity of hexatic-smectic phase transition by means of angular x-ray cross-correlation analysis (XCCA). By applying two-point angular intensity cross-correlation functions to…

Particle tracking with a 0.98$\mu$m silica sphere is used in determining precessional motion of nematic director in nematic phase of 8CB liquid crystals, as it probes those oriented structures which are of the same wavelength as of the…

Soft Condensed Matter · Physics 2015-05-12 Balaji Yendeti , Ashok Vudaygiri

The bent-core liquid crystals (LCs) are highly regarded as the next-generation materials for electro-optic devices. The nematic (N) phase of these LCs possesses highly ordered smectic-like cybotactic clusters which are promising in terms of…

Soft Condensed Matter · Physics 2019-02-06 Sourav Patranabish , Yiwei Wang , Aloka Sinha , Apala Majumdar

Particle tracking passive microrheology in 8CB liquid crystals is used to redefine the precessional motion of the orientation of nematic director in liquid crystals. Physical origin of tumbling director in presence of presmectic clusters…

Soft Condensed Matter · Physics 2015-04-02 Balaji Yendeti , Ashok Vudayagiri

The effect of short chain grafting on the liquid crystalline (LC) ordering of nano-crystals is investigated using molecular dynamics simulations of a coarse-grained grafted nano-rod model. Monodisperse nano-rods, with aspect ratios typical…

Soft Condensed Matter · Physics 2025-06-05 William S. Fall , Henricus H. Wensink

Molecular arrangement in the chiral smectic phases of the glassforming (S)-4'-(1-methylheptylcarbonyl)biphenyl-4-yl 4-[7-(2,2,3,3,4,4,4-heptafluorobutoxy) heptyl-1-oxy]benzoate is investigated by X-ray diffraction. An increased correlation…

Soft Condensed Matter · Physics 2025-01-15 Aleksandra Deptuch , Natalia Górska , Stanisław Baran , Magdalena Urbańska