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Using first-principles density functional theory we predict a ferroelectric ground state -- driven by off-centering of the magnetic Mn$^{4+}$ ion -- in perovskite-structure BaMnO$_3$. Our finding is surprising, since the competition between…

Materials Science · Physics 2009-05-28 James M. Rondinelli , Aaron S. Eidelson , Nicola A. Spaldin

The modulation of charge density and spin order in (LaMnO$_3$)$_{2n}$/(SrMnO$_3$)$_n$ ($n$=1-4) superlattices is studied via Monte Carlo simulations of the double-exchange model. G-type antiferromagnetic barriers in the SrMnO$_{3}$ regions…

Strongly Correlated Electrons · Physics 2008-11-24 Shuai Dong , Rong Yu , Seiji Yunoki , Gonzalo Alvarez , J. -M. Liu , Elbio Dagotto

Commencing from the centrosymmetric MnRMnSbO$_6$ compound, we explore the realm of magnetic polar double-double perovskite oxides characterized by significant ferroelectric polarization. Employing symmetry operations, first-principles…

Materials Science · Physics 2024-03-11 Monirul Shaikh , Duo Wang , Saurabh Ghosh

We have identified, for the first time, the change in symmetry at the ferroelectric transition TFE near 1023K of the ferroelectromagnet YMnO3. This transition takes place 300K below the transition to the centrosymmetric state at TIP. Single…

Materials Science · Physics 2007-05-23 Gwilherm Nenert , Yang Ren , Harold T. Stokes , Thomas T. M. Palstra

Complex oxides exhibit a variety of unusual physical properties, which can be used for designing novel electronic devices. Here we fabricate and study experimentally nano-scale Superconductor/ Ferromagnet/Superconductor junctions with the…

Superconductivity · Physics 2019-06-26 R. de Andres Prada , T. Golod , O. M. Kapran , E. A. Borodianskyi , Ch. Bernhard , V. M. Krasnov

We propose a tunneling heterostructure by replacing one of the metal electrodes in a metal/ferroelectric/metal ferroelectric tunnel junction with a heavily doped semiconductor. In this metal/ferroelectric/semiconductor tunnel diode, both…

Materials Science · Physics 2013-05-22 Zheng Wen , Chen Li , Di Wu , Aidong Li , Naiben Ming

Multiferroic perovskites that exhibit room temperature magnetization and polarization have immense potential in the next generation of magneto-electric and spintronic memory devices. In this work, the magnetic and ferroelectric properties…

We propose a method of controlling the metal-insulator transition of one perovskite material at its interface with a another ferroelectric material based on first principle calculations. The operating principle is that the rotation of…

Materials Science · Physics 2016-03-11 Xu He , Kui-juan Jin , Chen Ge , Zhong-shui Ma , Guo-zhen Yang

Insertion of layers displaying field-induced metal-to-insulator (M/I) transition in ferroelectric tunnel junctions (FTJs) has received attention as a potentially useful way to enlarge junction tunnel electroresistance (TER). Half-doped…

An effective Hamiltonian for the ferroelectric transition in $PbTiO_3$ is constructed from first-principles density-functional-theory total-energy and linear-response calculations through the use of a localized, symmetrized basis set of…

mtrl-th · Physics 2009-10-28 K. M. Rabe , U. V. Waghmare

The microstructure and phase transition in relaxor ferroelectric Pb(Mg1/3Nb2/3)O3 (PMN) and its solid solution with PbTiO3 (PT), PMN-xPT, remain to be one of the most puzzling issues of solid state science. In the present work we have…

Materials Science · Physics 2009-11-07 Z. -G. Ye , Y. Bing , J. Gao , A. A. Bokov , P. Stephens , B. Noheda , G. Shirane

Thin films and heterostructures of hexagonal manganites as promising multiferroic materials have attracted a considerable interest recently. We report structural transformations of high quality epitaxial h-TMO/YSZ(111) films, analyzed by…

Strongly Correlated Electrons · Physics 2020-09-23 R. Mandal , M. Hirsbrunner , V. Roddatis , L. Schüler , U. Roß , S. Merten , V. Moshnyaga

We report magnetic, transport, neutron diffraction, and muon spin rotation data showing that Pb$_2$CoOsO$_6$, a newly synthesized metallic double-perovskite with a centrosymmetric space group at room temperature, exhibits a continuous…

Ferroelectricity is observed in orthorhombic $HoMnO_3$ and $YMnO_3$ at the magnetic lock-in transitions into an E-type structure or an incommensurate phase with a temperature independent wave vector, respectively. In $HoMnO_3$ the…

Strongly Correlated Electrons · Physics 2011-11-09 B. Lorenz , Y. Q. Wang , C. W. Chu

In ferroelectricity, atomic-scale dipole moments interact collectively to produce strong electro-mechanical coupling and switchable macroscopic polarization. Hence, the functionality of ferroelectrics emerges at a solid-solid phase…

Materials Science · Physics 2019-08-21 Maya Barzilay , Hemaprabha Elangovan , Yachin Ivry

Specific heat studies of the Sr$_{1-x}$Ba$_x$Mn$_{1-y}$Ti$_y$O$_3$ polycrystalline samples performed by the relaxation and DSC methods over the temperature range 2 - 450 K are reported. Anomalies accompanying the…

Statistical Mechanics · Physics 2025-07-31 J. Wieckowski , A. Szewczyk , M. U. Gutowska , B. Dabrowski

Novel phenomena appear when two different oxide materials are combined together to form an interface. For example, at the interface of LaAlO3/SrTiO3, two dimensional conductive states form to avoid the polar discontinuity and magnetic…

Materials Science · Physics 2017-02-23 Fang Wang , Zhaohui Ren , He Tian , Shengyuan A. Yang , Yanwu Xie , Yunhao Lu , Jianzhong Jiang , Gaorong Han , Kesong Yang

BaMF4 (M=Fe, Co, Ni and Mn) family are typical multiferroic materials, having antiferromagnetism at around liquid nitrogen temperature. In this work, polycrystalline BaFeF4 has been prepared by solid state reaction. The slight deficiency of…

It was discovered in La1-xSrxMnO3(x~1/8) that a field induced phase transition occurs from a ferromagnetic metal(FM) phase to a ferromagnetic insulator (FI) phase. The magnetization shows a sharp jump at the transition field accompanying…

Strongly Correlated Electrons · Physics 2016-08-31 H. Nojiri , K. Kaneko , M. Motokawa , K. Hirota , K. Takahashi , Y. Endoh

Investigation of the oxygen-deficient 112-type ordered oxides of the type LnBaCoMnO5+\delta (Ln = Nd, Eu) evidences certain unusual magnetic behavior at low temperatures, compared to the LnBaCo2O5+\delta cobaltites. One observes that the…

Materials Science · Physics 2015-05-18 Asish K. Kundu , V. Pralong , B. Raveau , V. Caignaert