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The present work proposes to use density-functional theory (DFT) to correct for the basis-set error of wave-function theory (WFT). One of the key ideas developed here is to define a range-separation parameter which automatically adapts to a…

This paper concerns the study of optimal (supremum and infimum) uncertainty bounds for systems where the input (or prior) probability measure is only partially/imperfectly known (e.g., with only statistical moments and/or on a coarse…

Machine Learning · Computer Science 2023-01-02 Xingsheng Sun , Burigede Liu

The effective potential formalism is applied to glass forming liquids, choosing a coupling potential such that the "order parameter", conjugated to the coupling strength, is the mean square displacement of the particles from their position…

Disordered Systems and Neural Networks · Physics 2007-05-23 Antonio de Candia

In orbital-free density functional theory the kinetic potential (KP), the functional derivative of the kinetic energy density functional, appears in the Euler equation for the electron density and may be more amenable to simple…

Other Condensed Matter · Physics 2015-05-13 Jeng-Da Chai , Vincent L. Ligneres , Gregory Ho , Emily A. Carter , John D. Weeks

The basis-set correction method based on density-functional theory consists in correcting the energy calculated by a wave-function method with a given basis set by a density functional. This basis-set correction density functional…

Chemical Physics · Physics 2023-07-05 Diata Traore , Emmanuel Giner , Julien Toulouse

Model-based planners for partially observable problems must accommodate both model uncertainty during planning and goal uncertainty during objective inference. However, model-based planners may be brittle under these types of uncertainty…

Artificial Intelligence · Computer Science 2024-02-15 Harrison Delecki , Marcell Vazquez-Chanlatte , Esen Yel , Kyle Wray , Tomer Arnon , Stefan Witwicki , Mykel J. Kochenderfer

Previous studies have used numerical methods to optimize the hyperpolarizability of a one-dimensional quantum system. These studies were used to suggest properties of one-dimensional organic molecules, such as the degree of modulation of…

Optics · Physics 2015-05-18 Urszula B. Szafruga , Mark G. Kuzyk , David S. Watkins

Density functional theory (DFT) has greatly expanded our ability to affordably compute and understand electronic ground states, by replacing intractable {\em ab initio} calculations by models based on paradigmatic physics from high- and…

Chemical Physics · Physics 2023-03-29 Tim Gould , Derk P. Kooi , Paola Gori-Giorgi , Stefano Pittalis

A set of bi-orthogonal potential-density basis functions is introduced to model the density and its associated gravitational field of three dimensional stellar systems. Radial components of our basis functions are weighted integral forms of…

Astrophysics · Physics 2009-11-13 Alireza Rahmati , Mir Abbas Jalali

This work aims at providing a mathematical and numerical framework for the analysis on the effects of pulsed electric fields on biological media. Biological tissues and cell suspensions are described as having a heteregeneous permittivity…

Analysis of PDEs · Mathematics 2015-04-03 Habib Ammari , Dehan Chen , Jun Zou

We consider the problem of estimating the population probability distribution given a finite set of multivariate samples, using the maximum entropy approach. In strict keeping with Jaynes' original definition, our precise formulation of the…

Data Analysis, Statistics and Probability · Physics 2007-07-13 Sabbir Rahman , Mahbub Majumdar

The massive integration of distributed energy resources changes the operational demands of the electric power distribution system, motivating optimization-based approaches. The added computational complexities of the resulting optimal power…

Optimization and Control · Mathematics 2023-07-04 Yunqi Luo , Rabayet Sadnan , Bala Krishnamoorthy , Anamika Dubey

We establish necessary and sufficient conditions for the N-representability of the universal one-electron reduced density matrix functional. Functionals satisfying these conditions are guaranteed to yield variational upper bounds on the…

Quantum Physics · Physics 2026-04-08 Jannis Erhard , Paul W. Ayers

We propose novel methods for max-cost Discrete Function Evaluation Problem (DFEP) under budget constraints. We are motivated by applications such as clinical diagnosis where a patient is subjected to a sequence of (possibly expensive) tests…

Machine Learning · Computer Science 2015-01-13 Feng Nan , Joseph Wang , Venkatesh Saligrama

We construct a theory to introduce the concept of topologically robust exceptional points (EP). Starting from an ordered system with $N$ elements, we find the necessary condition to have the highest order exceptional point, namely…

Optics · Physics 2018-12-07 Cem Yuce , Hamidreza Ramezani

In many real world problems, optimization decisions have to be made with limited information. The decision maker may have no a priori or posteriori data about the often nonconvex objective function except from on a limited number of points…

Optimization and Control · Mathematics 2011-11-10 Tansu Alpcan

This paper presents a density-based topology optimization approach to design structures under self-weight load. Such loads change their magnitude and/or location as the topology optimization advances and pose several unique challenges,…

Computational Engineering, Finance, and Science · Computer Science 2022-04-26 Prabhat Kumar

An accurate expression of the kinetic energy density of an electronic distribution in terms of the single particle reduced density matrix for atomic and molecular systems is a long-standing problem in electron structure theory. Existing…

Chemical Physics · Physics 2024-10-30 Priya , Mainak Sadhukhan

One of the most common control decisions faced by power system operators is the question of how to dispatch generation to meet demand for power. This is a complex optimization problem that includes many nonlinear, non convex constraints as…

Optimization and Control · Mathematics 2013-06-14 Russell Bent , Daniel Bienstock , Michael Chertkov

Optimal power flow problems (OPFs) are mathematical programs used to determine how to distribute power over networks subject to network operation constraints and the physics of power flows. In this work, we take the view of treating an OPF…

Optimization and Control · Mathematics 2020-03-06 Fengyu Zhou , James Anderson , Steven H. Low