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Characteristics of hybridization and multipole orders of $4f$-electrons in Pr skutterudites are explained in terms of a pseudo-quartet composed of crystalline electric field (CEF) singlet and the triplet. It is shown that the contrasting…

Strongly Correlated Electrons · Physics 2015-06-25 Yoshio Kuramoto , Annamaria Kiss , Junya Otsuki , Hiroaki Kusunose

In contrary to widely spread view about the substantial delocalization of f electrons in heavy- fermion (h-f) compounds it is argued that h-f phenomena can be understood with localized f electrons. Then the role of crystal-field…

Strongly Correlated Electrons · Physics 2008-10-08 R. J. Radwanski

High magnetic fields induce a pronounced in-plane electronic anisotropy in the tetragonal antiferromagnetic metal CeRhIn$_{5}$ at $H^{*} \gtrsim 30$ T for fields $\simeq 20^{\mathrm{o}}$ off the $c$-axis. Here we investigate the response of…

Strongly Correlated Electrons · Physics 2019-01-16 P. F. S. Rosa , S. M. Thomas , F. F. Balakirev , E. D. Bauer , R. M. Fernandes , J. D. Thompson , F. Ronning , M. Jaime

The influence of a partial substitution with S, Te, Co, Ni and Cu atoms on the electronic structure of the FeSe superconductor has been investigated within the density functional theory. The results of the supercell calculations reveal…

Superconductivity · Physics 2013-08-13 A. Ciechan , M. J. Winiarski , M. Samsel-Czekała

Spin- and angle-resolved resonant (Ce $4d\to4f$) photoemission spectra of a monolayer Ce on Fe(110) reveal spin-dependent changes of the Fermi-level peak intensities. That indicate a spin-dependence of $4f$ hybridization and, thus, of $4f$…

Strongly Correlated Electrons · Physics 2007-05-23 Yu. S. Dedkov , M. Fonin , Yu. Kucherenko , S. L. Molodtsov , U. Rüdiger , C. Laubschat

The microscopic mechanism of heavy band formation, relevant for unconventional superconductivity in CeCoIn$_5$ and other Ce-based heavy fermion materials, depends strongly on the efficiency with which $f$ electrons are delocalized from the…

The polarizability of nearby ions may have a significant impact on electron interactions in solids, but only limited experimental data are available to support this picture. In this work, using a highly simplified description of the…

Superconductivity · Physics 2024-08-26 Xiaoxiao Xiong , Fabio Boschini , Mona Berciu

Theoretical account is given of 4f-electron dynamics and multipole orders in Pr skutterudites with particular attention to (i) mechanism of the crystalline electric field (CEF) splitting leading to a pseudo-quartet ground state;(ii) Kondo…

Strongly Correlated Electrons · Physics 2009-11-11 Y. Kuramoto , J. Otsuki , A. Kiss , H. Kusunose

Searching for new functionality in next generation electronic devices is a principal driver of material physics research. Multiferroics simultaneously exhibit electric and magnetic order parameters that may be coupled through…

Materials Science · Physics 2017-06-06 Sae Hwan Chun , Kwang Woo Shin , Kee Hoon Kim , John F. Mitchell , Philip J. Ryan , Jong-Woo Kim

We have investigated the orbital-dependent electronic states of Cd6Ce, a prototype of strongly correlated rare-earth-based Tsai-type quasicrystals and approximants (ACs) by soft and hard x-ray photoemission spectroscopy. Our results reveal…

We present linear polarization-dependent soft x-ray absorption spectroscopy data at the Ce $M_{4,5}$ edges of Cd and Sn doped CeCoIn$_5$. The 4$f$ ground state wave functions have been determined for their superconducting, antiferromagnetic…

Discovering Dirac fermions with novel properties has become an important front in condensed matter and materials sciences. Here, we report the observation of unusual Dirac fermion states in a strongly-correlated electron setting, which are…

Ce 3d-4f resonant angle-resolved photoemission measurements on CeCoGe$_{1.2}$Si$_{0.8}$ and CeCoSi$_{2}$ have been performed to understand the Fermi surface topology as a function of hybridization strength between Ce 4$f$- and conduction…

Strongly Correlated Electrons · Physics 2015-04-16 H. J. Im , T. Ito , H. Miyazaki , S. Kimura , Y. S. Kwon , Y. Saitoh , S. -I. Fujimori , A. Yasui , H. Yamagami

The electronic structure of the heavy fermion compound CeB6 is probed by resonant inelastic soft X-ray scattering using photon energies across the Ce 3d and 4d absorption edges. The hybridization between the localized 4f orbitals and the…

Materials Science · Physics 2012-01-04 M. Magnuson , S. M. Butorin , J. -H. Guo , A. Agui , J. Nordgren , H. Ogasawara , A. Kotani , T. Takahashi , S. Kunii

We present a new method to compute the electronic structure of correlated materials combining the hybrid functional method with the dynamical mean-field theory. As a test example of the method we study cerium sesquioxide, a strongly…

Materials Science · Physics 2008-12-15 D. Jacob , K. Haule , G. Kotliar

We report the synthesis, crystal structure and characterization by means of single crystal x-ray diffraction, neutron powder diffraction, magnetic, thermal and transport measurements of the new heavy fermion compounds…

The physical properties of single-crystalline SmBe$_{13}$ with a NaZn$_{13}$-type cubic structure have been studied by electrical resistivity ($\rho$), specific heat ($C$), and magnetization ($M$) measurements in magnetic fields of up to 9…

Strongly Correlated Electrons · Physics 2017-06-14 Hiroyuki Hidaka , Seigo Yamazaki , Yusei Shimizu , Naoyuki Miura , Chihiro Tabata , Tatsuya Yanagisawa , Hiroshi Amitsuka

We have calculated the band-$f$ hybridizations for Ce$_x$La$_{1-x}$M$_3$ compounds ($x=1$ and $x\rightarrow 0$; M=Pb, In, Sn, Pd) within the local density approximation and fed this into a non-crossing approximation for the Anderson…

Condensed Matter · Physics 2009-10-28 J. E. Han , M. Alouani , D. L. Cox

We show that the strong hybridization between the iron 3d and the arsenic 4p orbitals, in the newly discovered iron-based high-T$_{c}$ superconductors, leads to an explanation of certain experimental observations that are presently not well…

Superconductivity · Physics 2015-05-13 R. A. Jishi , H. M. Alyahyaei

We have measured the crystalline electric field (CEF) excitations of the CeMIn5 (M = Co, Rh, Ir) series of heavy fermion superconductors by means of inelastic neutron scattering. Fits to a CEF model reproduce the inelastic neutron…