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We study the density-density correlation function $G({\bf r},{\bf r}')$ in the interfacial region of a fluid (or Ising-like magnet) with short-ranged interactions using square gradient density functional theory. Adopting a simple double…

Statistical Mechanics · Physics 2015-06-19 A. O. Parry , C. Rascón , G. Willis , R. Evans

A density functional theory of two-dimensional freezing is presented for a soft interaction potential that scales as inverse cube of particle distance. This repulsive potential between parallel, induced dipoles is realized for paramagnetic…

Soft Condensed Matter · Physics 2009-05-28 Sven van Teeffelen , Christos N. Likos , Norman Hoffmann , Hartmut Löwen

We investigate the evolution of a system of colloidal particles, trapped at a fluid interface and interacting via capillary attraction, as function of the range of the capillary interaction and temperature. We address the collapse of an…

Soft Condensed Matter · Physics 2013-12-13 J. Bleibel , A. Dominguez , M. Oettel , S. Dietrich

Molecular dynamics simulations of two-dimensional soft Yukawa fluids are performed to analyze the effect that the range of interaction has on coexisting densities and line tension. The attractive one-component fluid and equimolar mixtures…

Soft Condensed Matter · Physics 2012-07-16 G. A. Méndez-Maldonado , M. González-Melchor , J. Alejandre

A simple theoretical approach is used to investigate active colloids at the free interface and near repulsive substrates. We employ dynamical density functional theory to determine the steady-state density profiles in an effective…

Soft Condensed Matter · Physics 2017-02-03 René Wittmann , Joseph M. Brader

Using numerical simulations we study the slow dynamics of a colloidal hard-sphere fluid adsorbed in a matrix of disordered hard-sphere obstacles. We calculate separately the contributions to the single-particle dynamic correlation functions…

Soft Condensed Matter · Physics 2011-06-16 Jan Kurzidim , Daniele Coslovich , Gerhard Kahl

A geometry-based density functional theory is presented for mixtures of hard spheres, hard needles and hard platelets; both the needles and the platelets are taken to be of vanishing thickness. Geometrical weight functions that are…

Soft Condensed Matter · Physics 2009-11-11 Ansgar Esztermann , Hendrik Reich , Matthias Schmidt

We develop a dynamical density functional theory based model for the drying of colloidal films on planar surfaces. We consider mixtures of two different sizes of hard-sphere colloids. Depending on the solvent evaporation rate and the…

Soft Condensed Matter · Physics 2021-01-28 Boshen He , Ignacio Martin-Fabiani , Roland Roth , Gyula I. Tóth , Andrew J. Archer

Using both dynamical density functional theory and particle-resolved Brownian dynamics simulations, we explore the flow of two-dimensional colloidal solids and fluids driven through a linear channel with a geometric constriction. The flow…

Soft Condensed Matter · Physics 2016-05-25 Urs Zimmermann , Frank Smallenburg , Hartmut Löwen

I use the method of classical density-functional theory in the weighted-density approximation of Tarazona to investigate the phase diagram and the interface structure of a two-dimensional lattice-gas model with three phases -- vapour,…

Statistical Mechanics · Physics 2009-11-10 S. Prestipino

We have measured the phase behavior of a binary mixture of like-charged colloidal spheres with a size ratio of 0.9 and a charge ratio of 0.96 as a function of particle number density n and composition p. Under exhaustively deionized…

Soft Condensed Matter · Physics 2011-04-05 Nina J. Lorenz , Thomas Palberg

We study, using Density Functional theory and Monte Carlo simulations, aqueous electrolyte solutions between charged infinite planar surfaces, in a contact with a bulk salt reservoir. In agreement with recent experimental observations [Z.…

Soft Condensed Matter · Physics 2016-09-21 Thiago Colla , Matheus Girotto , Alexandre P. dos Santos , Yan Levin

In our study we investigate the behaviour of the net force (NF) emerging between an ellipsoidal particle and a thick plate (slab), when the interaction takes place in a near critical fluid medium with account for the omnipresent van der…

Statistical Mechanics · Physics 2019-03-27 G. S. Valchev , D. M. Dantchev

A fundamental assumption of the dynamical density functional theory (DDFT) of colloidal systems is that a grand-canonical free energy functional may be employed to generate the thermodynamic driving forces. Using one-dimensional hard-rods…

Soft Condensed Matter · Physics 2013-06-04 Johannes Reinhardt , Joseph Michael Brader

While the theory of diffusion of a single Brownian particle in confined geometries is well-established by now, we discuss here the theoretical framework necessary to generalize the theory of diffusion to dense suspensions of strongly…

Soft Condensed Matter · Physics 2014-12-18 H. Löwen , M. Heinen

Computer simulations and theory are used to systematically investigate how the effective force between two big colloidal spheres in a sea of small spheres depends on the basic (big-small and small-small) interactions. The latter are modeled…

Soft Condensed Matter · Physics 2009-11-07 A. A. Louis , E. Allahyarov , H. Lowen , R. Roth

A fluid in equilibrium in a finite volume $V$ with particle number $N$ at a density $\rho = N/V$ exceeding the onset density $\rho_f $ of freezing may exhibit phase coexistence between a crystalline nucleus and surrounding fluid. Using a…

Statistical Mechanics · Physics 2015-06-23 Antonia Statt , Peter Virnau , Kurt Binder

In order to give a basis for the structure and correlation analysis of fine particle (dusty) plasma and colloidal suspensions, thermodynamic treatment of mixtures of macroscopic and microscopic charged particles within the adiabatic…

Plasma Physics · Physics 2015-06-11 Hiroo Totsuji

Based on classical density functional theory (DFT), we investigate the demixing phase transition of a two-dimensional, binary Heisenberg fluid mixture. The particles in the mixture are modeled as Gaussian soft spheres, where one component…

Soft Condensed Matter · Physics 2012-08-31 K. Lichtner , A. J. Archer , S. H. L. Klapp

Using classical density functional theory (DFT) we calculate the density profile $\rho({\mathbf r})$ and local compressibility $\chi({\mathbf r})$ of a simple liquid solvent in which a pair of blocks with (microscopic) rectangular…

Soft Condensed Matter · Physics 2017-04-05 Blesson Chacko , Robert Evans , Andrew J. Archer