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We have studied the electronic structure of the spin-1/2 quantum magnet TiOCl by polarization-dependent momentum-resolved photoelectron spectroscopy. From that, we confirm the quasi-one-dimensional nature of the electronic structure along…

Strongly Correlated Electrons · Physics 2007-05-23 M. Hoinkis , M. Sing , J. Schaefer , M. Klemm , S. Horn , H. Benthien , E. Jeckelmann , T. Saha-Dasgupta , L. Pisani , R. Valenti , R. Claessen

We report on the magnetic, thermodynamic and optical properties of the quasi-one-dimensional quantum antiferromagnets TiOCl and TiOBr, which have been discussed as spin-Peierls compounds. The observed deviations from canonical spin-Peierls…

Strongly Correlated Electrons · Physics 2009-11-11 R. Rückamp , J. Baier , M. Kriener , M. W. Haverkort , T. Lorenz , G. S. Uhrig , L. Jongen , A. Möller , G. Meyer , M. Grüninger

We report on a detailed single crystal x-ray diffraction study of the unconventional spin-Peierls compound TiOCl. The intermediate phase of TiOCl is characterized by an incommensurate modulation which is virtually identical to that recently…

Strongly Correlated Electrons · Physics 2007-05-23 A. Krimmel , J. Strempfer , B. Bohnenbuck , B. Keimer , M. Hoinkis , M. Klemm , S. Horn , A. Loidl , M. Sing , R. Claessen , M. v. Zimmermann

We present first principles density functional calculations and downfolding studies of the electronic and magnetic properties of the layered quantum spin system TiOCl. We discuss explicitely the nature of the exchange pathes and attempt to…

Strongly Correlated Electrons · Physics 2016-08-31 T. Saha-Dasgupta , Roser Valenti , H. Rosner , Claudius Gros

Pressure-dependent transmittance and reflectance spectra of TiOBr and TiOCl single crystals at room temperature suggest the closure of the Mott-Hubbard gap, i.e., the gap is filled with additional electronic states extending down to the…

Strongly Correlated Electrons · Physics 2018-02-02 C. A. Kuntscher , A. Pashkin , H. Hoffmann , S. Frank , M. Klemm , S. Horn , A. Schönleber , S. van Smaalen , M. Hanfland , S. Glawion , M. Sing , R. Claessen

Electronic structure calculations on the low dimensional spin-1/2 compound TiOCl were performed at several pressures in the orthorhombic phase, finding that the structure is quasi-one-dimensional. The Ti3+ (d1) ions have one t2g orbital…

Strongly Correlated Electrons · Physics 2010-12-15 A. Piñeiro , V. Pardo , D. Baldomir , S. Blanco-Canosa , F. Rivadulla , J. E. Arias , J. Rivas

The one-dimensional electron gas exhibits spin-charge separation and power-law spectral responses to many experimentally relevant probes. Ordering in a quasi one-dimensional system is necessarily associated with a dimensional crossover, at…

Superconductivity · Physics 2009-10-31 E. W. Carlson , D. Orgad , S. A. Kivelson , V. J. Emery

We investigated the electronic response of the quasi-two-dimensional spin gap compound La4Ru2O10 using optical spectroscopy. We observed drastic changes in the optical spectra as the temperature decreased, resulting in anisotropy in the…

Strongly Correlated Electrons · Physics 2009-11-13 S. J. Moon , W. S. Choi , S. J. Kim , Y. S. Lee , P. G. Khalifah , D. Mandrus , T. W. Noh

Reduced dimensionality and strong electronic correlations, which are among the most important ingredients for cupratelike high-Tc superconductivity, characterize also the physics of nickelate-based heterostructures. Starting from the…

Strongly Correlated Electrons · Physics 2011-11-07 P. Hansmann , A. Toschi , Xiaoping Yang , O. K. Andersen , K. Held

We have studied the electronic structure of the two-dimensional Heisenberg antiferromagnet VOCl using photoemission spectroscopy and density functional theory including local Coulomb repulsion. From calculated exchange integrals and the…

Strongly Correlated Electrons · Physics 2009-10-16 S. Glawion , M. R. Scholz , Y. -Z. Zhang , R. Valenti , T. Saha-Dasgupta , M. Klemm , J. Hemberger , S. Horn , M. Sing , R. Claessen

The ground state of the spin-Peierls system TiOCl was probed using synchrotron x-ray diffraction on a single-crystal sample at T = 6 K. We tracked the evolution of the structural superlattice peaks associated with the dimerized ground state…

Strongly Correlated Electrons · Physics 2012-08-23 A. Prodi , J. S. Helton , Yejun Feng , Y. S. Lee

We study the electronic structure of the quasi-one-dimensional organic conductor TTF-TCNQ by means of density-functional band theory, Hubbard model calculations, and angle-resolved photoelectron spectroscopy (ARPES). The experimental…

Strongly Correlated Electrons · Physics 2009-11-10 M. Sing , U. Schwingenschlögl , R. Claessen , P. Blaha , J. M. P. Carmelo , L. M. Martelo , P. D. Sacramento , M. Dressel , C. S. Jacobsen

The electronic and magnetic properties of transition metal oxyhalide compound Co2TeO3Cl2 is investigated using first principle calculations within the framework of density functional theory. In order to find underlying spin lattice of this…

Materials Science · Physics 2017-09-13 Jayita Chakraborty

Hybridization effects play a crucial role in determining the electronic properties of hybrid inorganic/organic interfaces. To gain insight into these important interactions, we perform a first-principles study based on hybrid…

Materials Science · Physics 2022-04-06 Jannis Krumland , Caterina Cocchi

Temperature-dependent x-ray diffraction of the low-dimensional spin 1/2 quantum magnet TiOCl shows that the phase transition at T_{c2} = 90 K corresponds to a lowering of the lattice symmetry. Below T_{c1} = 66 K a twofold superstructure…

Materials Science · Physics 2009-11-11 M. Shaz , S. van Smaalen , L. Palatinus , M. Hoinkis , M. Klemm , S. Horn , R. Claessen

The results of investigations of intercalated compounds Cr_xTiSe_2 and Co_xTiSe_2 by X-ray photoelectron spectroscopy (XPS) and X-ray emission spectroscopy (XES) are presented. The data obtained are compared with theoretical results of…

There is a class of electronic liquids in dimensions greater than one, which show all essential properties of one dimensional electronic physics. These are topological liquids - correlated electronic systems with a spectral flow.…

Strongly Correlated Electrons · Physics 2009-10-31 P. B. Wiegmann

The sequence of phase transitions and the symmetry of in particular the low temperature incommensurate and spin-Peierls phases of the quasi one-dimensional inorganic spin-Peierls system TiOX (TiOBr and TiOCl) have been studied using…

Generally, lattice distortions play a key role in determining the ground states of materials. Although it is well known that trigonal distortions are generic to most two-dimensional transition metal dichalcogenides, the impact of this…

Materials Science · Physics 2018-04-24 Banabir Pal , Yanwei Cao , Xiaoran Liu , Fangdi Wen , M. Kareev , A. T. N Diaye , P. Shafer , E. Arenholz , J. Chakhalian

Temperature-dependent x-ray diffraction of the low-dimensional spin 1/2 quantum magnet TiOBr shows that the phase transition at T_{c2} = 47.1 (4) K corresponds to the development of an incommensurate superstructure. Below T_{c1} = 26.8 \pm…

Other Condensed Matter · Physics 2007-05-23 Sander van Smaalen , Lukas Palatinus , Andreas Schonleber
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