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A systematic theoretical study of thermoelectric effect and temperature-gradient-driven electrokinetic flow of electrolyte solutions in charged nanocapillaries is presented. The study is based on a semianalytical model developed by…

Fluid Dynamics · Physics 2023-09-14 Wenyao Zhang , Qiuwang Wang , Min Zeng , Cunlu Zhao

Thermodiffusion in aqueous electrolyte solutions exhibits complex dependencies on temperature, concentration, and salt composition, yet its microscopic origins remain incompletely understood. Here, we employ non-equilibrium molecular…

Soft Condensed Matter · Physics 2026-04-21 Guansen Zhao , Fernando Bresme

We consider a particle moving with equation of motion $\dot x=f(t)$, where $f(t)$ is a random function with statistics which are independent of $x$ and $t$, with a finite drift velocity $v=\langle f\rangle$ and in the presence of a…

Chaotic Dynamics · Physics 2016-08-24 Robin Guichardaz , Alain Pumir , Michael Wilkinson

A variant of continuous nonequilibrium thermodynamic theory based on the postulate of the scale invariance of the local relation between generalized fluxes and forces has been proposed. This single postulate replaces the assumptions on…

Statistical Mechanics · Physics 2015-06-05 Leonid M. Martyushev , V. D. Seleznev

We study hydrodynamic slowing-down of a particle moving in a temperature gradient perpendicular to a wall. At distances much smaller than the particle radius, $h\ll a$, lubrication approximation leads to the reduced velocity…

Soft Condensed Matter · Physics 2016-04-06 Alois Würger

Quasiparticle theory gives a local relation between heat current and temperature gradient, provided the quasiparticle mean free path is smaller than the scale of variation of temperature. When mean free paths are comparable to sample size,…

Mesoscale and Nanoscale Physics · Physics 2013-08-14 Philip B. Allen

Temperature gradients drive asymmetric ion distributions via thermodiffusion (the Soret effect), leading to deviations from the classical Debye--H\"uckel potential.We introduce the Eastman entropy of transfer, $\hat{S}_\pm = \alpha_\pm…

Soft Condensed Matter · Physics 2026-03-24 Kazuhiko Seki

When applied to binary solutions, thermal gradients lead to the generation of concentration-gradients and thus to inhomogeneous systems. While being known for more than 150 years, the molecular origins for this phenomenon are still debated,…

Soft Condensed Matter · Physics 2023-12-21 Mario Araujo-Rocha , Alejandro Diaz-Marquez , Guillaume Stirnemann

We discuss the non-equilibrium critical phenomena in liquids, and the models for these phenomena based on local equilibrium and extended scaling assumptions. Special situations are proposed for experimental tests of the theory.…

Statistical Mechanics · Physics 2009-10-31 Alexander Patashinski

Convective instability in a ferrofluid layer heated from below or from above in the presence of a uniform vertical magnetic field is investigated theoretically. Convection is caused by a magnetic mechanism based on the temperature and…

Soft Condensed Matter · Physics 2007-05-23 Mark I. Shliomis

Thermal gradients impart thermophoretic forces on colloidal particles, pushing colloids towards cold or hot regions, a phenomenon called thermophoresis. Current theoretical approaches relate the Soret coefficient to local changes in the…

Soft Condensed Matter · Physics 2024-06-11 Juan D. Olarte-Plata , Fernando Bresme

The properties of the thermal force driving micron particles in incompressible fluids are studied within the hydrodynamic theory of the Brownian motion. It is shown that the assumption used for the hydrodynamic Langevin equation in its…

Statistical Mechanics · Physics 2012-10-16 Vladimir Lisy , Jana Tothova , Lukas Glod

A nonequilibrium distribution function of microscopic thermal current is studied by a direct numerical simulation in a thermal conducting steady state of particle systems. Two characteristic temperatures of the thermal current are…

Statistical Mechanics · Physics 2009-04-01 Satoshi Yukawa , Takashi Shimada , Fumiko Ogushi , Nobuyasu Ito

We report and explain a convective phenomenon observed in molecular dynamics simulations that cannot be classified either as a hydrodynamics instability nor as a macroscopically forced convection. Two complementary arguments show that the…

Condensed Matter · Physics 2009-10-22 Jorge Ibsen , Rodrigo Soto , Patricio Cordero

The Seebeck and Soret coefficients of ionically stabilized suspension of maghemite nanoparticles in dimethyl sulfoxide are experimentally studied as a function of nanoparticle volume fraction. In the presence of a temperature gradient, the…

The Brownian motion of microscopic particles is driven by the collisions with the molecules of the surrounding fluid. The noise associated with these collisions is not white, but coloured due, e.g., to the presence of hydrodynamic memory.…

Statistical Mechanics · Physics 2012-10-04 Scott Hottovy , Giovanni Volpe , Jan Wehr

Nonequilibrium thermodynamics formalism is proposed to derive the flux of grainy (bubbles-containing) matter, emerging in a nucleation growth process. Some power and non-power limits, due to the applied potential as well as owing to basic…

Soft Condensed Matter · Physics 2009-11-10 J. M. Rubi , A. Gadomski

The motion of a fluid induced by thermal gradients in the absence of driving forces is known as thermo-osmosis. The physical explanation of this phenomenon stems from the emergence of gradients in the tangential pressure due to the presence…

Statistical Mechanics · Physics 2024-11-13 Pietro Anzini , Zeno Filiberti , Alberto Parola

The fluctuation-dissipation-theorem connects equilibrium to mildly (linearly) perturbed situations in a thermodynamic manner: It involves the observable of interest and the entropy production caused by the perturbation. We derive a relation…

Statistical Mechanics · Physics 2021-03-24 Tristan Holsten , Matthias Krüger

We generalize a theory of Biot for a porous solid based on nonlinear elasticity theory to incorporate temperature effects. Acceleration waves are studied in detail in the fully nonlinear theory. The wavespeeds are found explicitly and the…

Soft Condensed Matter · Physics 2018-11-29 Brian Straughan , Vincenzo Tibullo