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The thermoelectric properties of polythiophene (PT) coupled to the Au (111) electrodes are studied based on density functional theory combined with nonequilibrium Green function formalism. Specially, the effect of Li and Cl adsorbents on…

Mesoscale and Nanoscale Physics · Physics 2018-04-04 Zahra Golsanamlou , Meysam Bagheri Tagani , Hamid Rahimpour Soleimani

For electronic and photoelectronic devices based on GeSe, an emergent two dimensional monochalcogenide with many exciting properties predicted, good electrical contacts are of great importance for achieving high device performances and…

Mesoscale and Nanoscale Physics · Physics 2019-01-11 Ranran Li , Wei Xia , Yanfeng Guo , Jiamin Xue

We consider several fundamental optical phenomena involving single molecules in biased metal-molecule-metal junctions. The molecule is represented by its highest occupied and lowest unoccupied molecular orbitals, and the analysis involves…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan

We calculate transmission eigenvalue distributions for Pt-benzene-Pt and Pt-butadiene-Pt junctions using realistic state-of-the-art many-body techniques. An effective field theory of interacting $\pi$-electrons is used to include screening…

Mesoscale and Nanoscale Physics · Physics 2011-08-04 J. P Bergfield , J. D. Barr , C. A. Stafford

In contrast to silicon-based transistors, single molecule junctions can be gated by simple mechanical means. Specifically, charge can be transferred between the junction's electrodes and its molecular bridge when the interelectrode distance…

Mesoscale and Nanoscale Physics · Physics 2023-05-24 Biswajit Pabi , Jakub Šebesta , Richard Korytár , Oren Tal , Atindra Nath Pal

The electronic and thermoelectric properties of molecular junctions formed from iron and ruthenium metal-acetylide were studied using complementary experimental techniques and quantum chemical simulations. We performed physical…

Extreme near-field heat transfer between metallic surfaces is a subject of debate as the state-of-the-art theory and experiments are in disagreement on the energy carriers driving heat transport. In an effort to elucidate the physics of…

Mesoscale and Nanoscale Physics · Physics 2022-01-19 Takuro Tokunaga , Amun Jarzembski , Takuma Shiga , Keunhan Park , Mathieu Francoeur

We present results of electronic structure and transport calculations for metallic interfaces, based on density functional theory and the non-equilibrium Green's functions method. Starting from the electronic structure of smooth Al, Cu, Ag,…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 M. M. Fadlallah , C. Schuster , U. Schwingenschloegl , T. Wunderlich , S. Sanvito

We calculate quantum transport for metal-graphene nanoribbon heterojunctions within the atomistic self-consistent Schr\"odinger/Poisson scheme. Attention is paid on both the chemical aspects of the interface bonding as well the…

Mesoscale and Nanoscale Physics · Physics 2010-10-22 I. Deretzis , G. Fiori , G. Iannaccone , A. La Magna

We study the electronic transport in a molecular junction in which each site is coupled to a local phonon bath using the non-equilibrium Green's function method. We observe the length period of the oscillatory conductance in odd-numbered…

Strongly Correlated Electrons · Physics 2011-08-12 Ya-Lin Lo , Shih-Jye Sun , Ying-Jer Kao

Employing the nonequilibrium Green's function method, we develop a fully quantum mechanical model to study the coupled electron-phonon transport in one-dimensional atomic junctions in the presence of a weak electron-phonon interaction. This…

Mesoscale and Nanoscale Physics · Physics 2008-03-04 J. T. Lü , Jian-Sheng Wang

Interfaces play a crucial role in energy transport at the nanoscale. However, direct experimental observations of interfacial thermal conductance across molecular junctions have remained challenging due to the high spatiotemporal resolution…

Chemical Physics · Physics 2025-12-23 Md. Shahriar Hossain Shuvo , Xing He , Mithun Ghosh , Ding-Shyue Yang

The electron transport properties of a four-terminal molecular device are computed within the framework of density functional theory and non-equilibrium Keldysh theory. The additional two terminals lead to new properties, including a…

Mesoscale and Nanoscale Physics · Physics 2009-09-01 Kamal K. Saha , Wenchang Lu , J. Bernholc , Vincent Meunier

Understanding the properties of electronic transport across metal-molecule interfaces is of central importance for controlling a large variety of molecular-based devices such as organic light emitting diodes, nanoscale organic spin-valves…

Mesoscale and Nanoscale Physics · Physics 2016-02-03 T. Yelin , R. Korytar , N. Sukenik , R. Vardimon , B. Kumar , C. Nuckolls , F. Evers , O. Tal

The effect of anchoring group on the electrical conductance of a single molecule bridging two Au electrodes was studied using di-substituted (isocyanide (CN-), thiol (S-) or cyanide (NC-)) benzene. The conductance of a single…

Materials Science · Physics 2009-11-11 Manabu Kiguchi , Shinichi Miura , Kenji Hara , Masaya Sawamura , Kei Murakoshi

Inspired by recent measurements of forces and conductances of bipyridine nano-junctions, we have performed density functional theory calculations of structure and electron transport in a bipyridine molecule attached between gold electrodes…

Materials Science · Physics 2009-11-11 R. Stadler , K. S. Thygesen , K. W. Jacobsen

In transport calculations for molecular junctions based on density functional theory the choice of exchange and correlation functional may dramatically affect the results. In particular local and semi-local functionals tend to…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 C. Toher , S. Sanvito

We present a microscopic theory of single-electron tunneling through metallic nanoparticles connected to the electrodes through molecular bridges. It combines the theory of electron transport through molecular junctions with the description…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark A. Ratner

The conductance of a single-atom contact is sensitive to the coupling of this contact atom to the atoms in the leads. Notably for the transition metals this gives rise to a considerable spread in the observed conductance values. The mean…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 S. K. Nielsen , Y. Noat , M. Brandbyge , R. H. M. Smit , K. Hansen , L. Y. Chen , A. I. Yanson , F. Besenbacher , J. M. van Ruitenbeek

Motivated by recent experiments, we study the variability of the thermal conductance of single dithiolated alkane molecules of varying length connecting two gold electrodes. For this purpose, we examine (i) the influence of the…

Mesoscale and Nanoscale Physics · Physics 2019-10-08 J. C. Klöckner , F. Pauly
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