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In this work, we demonstrate the formation of a "red-phase" poly[2-methoxy, 5-(2'- ethyl-hexoxy)-1,4-phenylene vinylene-PPV] (MEH-PPV) embedded into a host matrix of highly entangled ultra-high molecular weight polystyrene (MEH-PPV/UHMW PS…

Thermally stable polymers have attracted a lot of interest due to their potential use as the active component in electronic, optical and optoelectronic applications, such as light-emitting diodes, light emitting electrochemical cells,…

Other Condensed Matter · Physics 2007-05-23 O. S. Prelipceanu , M. Prelipceanu , O. G. Tudose , B. Grimm , S. Schrader

Ferroelectric films in the paraelectric phase exhibit two undesirable properties: hysteresis in the voltage-capacitance characteristics and a significant relaxation time of the capacitance. Our experiments show that suppression of both of…

BDMO-PPV is a photoluminescent semiconducting polymer related to others in the well-studied polyphenylene vinylene family such as MEH-PPV. These materials are known for their instability, degradation, and low efficiency in device…

Chemical Physics · Physics 2019-10-28 M. J. Deutsch , H. Park

Surface alignment of a recently discovered ferroelectric nematic liquid crystal (NF) is usually achieved by buffed polymer films, which produce a unidirectional polar alignment of the spontaneous electric polarization. We demonstrate that…

Hybrid-halide perovskite (HHP) films exhibit exceptional photo-electric properties. These materials are utilized for highly efficient solar cells and photoconductive technologies. Both ion migration and polarization have been proposed as…

Applied Physics · Physics 2021-04-21 Rohit Saraf , Cecile Saguy , Vivek Maheshwari , Hemaprabha Elangovan , Yachin Ivry

This work reports the fabrication and optical characterization of ultraviolet-emitting plastic scintillators based on polystyrene [-(CH2-CH(C6H5))n-] and polyvinyltoluene [-(CH2-CH(C6H4CH3))n-] doped with different concentrations of…

This work proposes a new photophysical phenomenon whereby UV/vis excitation of a molecule involving a Franck-Condon (FC) active vibration yields infrared (IR) emission by strong coupling to an optical cavity. The resulting UV/vis-to-IR…

Chemical Physics · Physics 2022-12-01 Connor K. Terry Weatherly , Justin Provazza , Emily A. Weiss , Roel Tempelaar

We report on the rejuvenation of thin films of polystyrene (PS) as they are heated from stable glassy states - prepared either through vapour deposition or physical aging. For films with thickness $h \gtrsim 200$ nm, the rejuvenation of…

Soft Condensed Matter · Physics 2024-08-22 Saba Karimi , Junjie Yin , James A. Forrest

In this work, the polar tetrahedron [PN$_2$O$_2$] was revealed as a new deep-ultraviolet (deep-UV) nonlinear optically active unit. Accordingly, a thermodynamically stable compound (PNO) consisting of the polar [PN$_2$O$_2$] units was…

Optics · Physics 2022-08-29 Congwei Xie , Abudukadi Tudi , Artem R. Oganov

The internal photoeffect in polythiopentacene (PTP) films is investigated. It is discovered that, in capacitor cells, the spectral dependence of the frontal photo-emf Vf correlates with the PTP absorption spectrum, while that of the back…

Materials Science · Physics 2015-03-23 M. P. Gorishnyi

Manipulating materials properties with light drives advances in materials science and photonics. Hyperbolic metamaterials are promising candidates as next-generation quantum optical media. They support Bloch plasmon polaritons, which are…

It is demonstrated that persistent-photoconductivity (PPC), well-studied in lightly-doped semiconductors, is observable in GeSbTe compounds using infrared excitation at cryogenic temperatures. The low level of energy-flux necessary to…

Strongly Correlated Electrons · Physics 2015-03-26 Z. Ovadyahu

Efficient solid-state photon emitters with longer operating lifetimes in the ultraviolet (UV) wavelength range are crucial for optoelectronic devices. However, finding suitable material candidates has been a significant challenge. Here, we…

Mesoscale and Nanoscale Physics · Physics 2024-09-04 Pushpendra Yadav , Amit Agarwal , Sitangshu Bhattacharya

Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

Quantum Gases · Physics 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

For an optically thick metallic film, the transmission for both s- and p-polarized waves is extremely low. If the metallic film is coated on both sides with a finite dielectric layer, light transmission for $p$-polarized waves can be…

Optics · Physics 2012-12-27 Dezhuan Han , Xin Li , Fengqin Wu , Jian Zi

Transition metal oxides possess complex free energy surfaces with competing degrees of freedom. Photoexcitation allows shaping of such rich energy landscapes. In epitaxially strained $\mathrm{La_{0.67}Ca_{0.33}MnO_3}$, optical excitation…

In a recent paper Segal et al. [1] attempted to explain the dynamics of spin 1/2 photoluminescence detected magnetic resonance (PLDMR) in films of a pi-conjugated polymer, namely a soluble de-rivative of poly(phenylene-vinylene) [MEH-PPV]…

Materials Science · Physics 2009-11-11 C. G. Yang , E. Ehrenfreund , Z. V. Vardeny

We propose that UV radiation can stimulate the formation of planetesimals in externally-illuminated protoplanetary disks. We present a numerical model of disk evolution including vertical sedimentation and photo-evaporation by an external O…

Astrophysics · Physics 2009-11-10 Henry B. Throop , John Bally

Mixed-halide based hybrid perovskite semiconductors have attracted tremendous attention as a promising candidate for high efficient photovoltaic and light-emitting devices. However, these advanced perovskite materials may undergo phase…

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