Related papers: Microscopic chaos and macroscopic entropy in fluid…
We show how the macroscopic state variables pressure, entropy and temperature of equilibrium thermodynamics can be consistently derived from the (quantum) chaotic spectral structure of one or two particles in two-dimensional domains. This…
Entropy serves as a central observable in equilibrium thermodynamics. However, many biological and ecological systems operate far from thermal equilibrium. Here we show that entropy production can characterize the behavior of such…
Diffusivity, a measure for how rapidly a fluid self-mixes, shows an intimate, but seemingly fragmented, connection to thermodynamics. On one hand, the "configurational" contribution to entropy (related to the number of mechanically-stable…
The thermodynamic equilibrium conditions for compact structures composed by mass varying particles are discussed assuming that the so-called dynamical mass behaves like an additional extensive thermodynamic degree of freedom. It then…
We distinguish a mechanical representation of the world in terms of point masses with positions and momenta and the chemical representation of the world in terms of populations of different individuals, each with intrinsic stochasticity,…
We study spacetime thermodynamics for non-equilibrium processes. We first generalize the formulation of spacetime thermodynamics by using an observer outside the horizon. Then we construct the entropy balance equation of spacetime…
The rate of entropy production by a stochastic process quantifies how far it is from thermodynamic equilibrium. Equivalently, entropy production captures the degree to which detailed balance and time-reversal symmetry are broken. Despite…
Most natural systems operate far from equilibrium, displaying time-asymmetric, irreversible dynamics characterized by a positive entropy production while exchanging energy and matter with the environment. Although stochastic thermodynamics…
We study a spatial diffusion process generated by velocity fluctuations of intermittent nature. We note that intermittence reduces the entropy production rate while enhancing the diffusion strength. We study a case of space-dependent…
An overview is given of recent advances in nonequilibrium statistical mechanics about the statistics of random paths and current fluctuations. Although statistics is carried out in space for equilibrium statistical mechanics, statistics is…
Microcanonical analysis is a powerful method for studying phase transitions of finite-size systems. This method has been used so far only for studying phase transitions of equilibrium systems, which can be described by microcanonical…
Non-equilibrium real-space condensation is a phenomenon in which a finite fraction of some conserved quantity (mass, particles, etc.) becomes spatially localised. We review two popular stochastic models of hopping particles that lead to…
We derive a functional for the entropy contributed by any microscopic degrees of freedom as arising from their measurable pair correlations. Applicable both in and out of equilibrium, this functional yields the maximum entropy which a…
The thermodynamic definition of entropy can be extended to nonequilibrium systems based on its relation to information. To apply this definition in practice requires access to the physical system's microstates, which may be prohibitively…
In classical thermodynamics the entropy is an extensive quantity, i.e.\ the sum of the entropies of two subsystems in equilibrium with each other is equal to the entropy of the full system consisting of the two subsystems. The extensitivity…
This paper presents alternative ideas on the physics of time that lead to a new interpretation of cosmological redshifts. These ideas are based on the close relationship between the speed of time and entropy processes in our universe. I…
We argue that Gaspard and coworkers [Nature 394, 865 (1998)] do not give evidence for microscopic chaos in the sense in which they use the term. The effectively infinite number of molecules in a fluid can generate the same macroscopic…
Using information entropy formalism, we consider a one-dimensional system with heat flux and extend the meaning of equilibrium variables to non equilibrium scenarios when classical local equilibrium approach is not applicable; this is…
We propose a general definition of nonequilibrium entropy of a classical stochastic field. As an example of particular interest in cosmology we apply this definition to compute the entropy of density perturbations in an inflationary…
The excess entropy, Se, defined as the difference between the entropies of the liquid and the ideal gas under identical density and temperature conditions, is shown to be the critical quantity connecting the structural, diffusional and…