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Related papers: Dielectric anisotropy in the GW space-time method

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We present an implementation of the $GW$ space-time approach that allows cubic-scaling all-electron calculations with standard Gaussian basis sets without exploiting any localization nor sparsity considerations. The independent-electron…

Computational Physics · Physics 2021-04-29 Ivan Duchemin , Xavier Blase

We present a many-body $GW$ formalism for quantum subsystems embedded in discrete polarizable environments containing up to several hundred thousand atoms described at a fully ab initio random phase approximation level. Our approach is…

Chemical Physics · Physics 2024-01-26 David Amblard , Xavier Blase , Ivan Duchemin

The evaluation of electrostatic energy for a set of point charges in a periodic lattice is a computationally expensive part of molecular dynamics simulations (and other applications) because of the long-range nature of the Coulomb…

We present a systematic study of the variables affecting the electronic and optical properties of two-dimensional(2D) crystals within \textit{ab initio} GW and GW plus Bethe Salpeter Equation (GW-BSE) calculations. As a prototypical 2D…

Materials Science · Physics 2016-07-20 Diana Y. Qiu , Felipe H. da Jornada , Steven G. Louie

The electron self-energy for long-range Coulomb interactions plays a crucial role in understanding the many-body physics of interacting electron systems (e.g. in metals and semiconductors), and has been studied extensively for decades. In…

Strongly Correlated Electrons · Physics 2020-08-25 Yunxiang Liao , Donovan Buterakos , Mike Schecter , Sankar Das Sarma

The pseudospectral method is a powerful tool for finding highly precise solutions of Schr\"{o}dinger's equation for few-electron problems. We extend the method's scope to wave functions with non-zero angular momentum and test it on several…

Atomic Physics · Physics 2013-05-29 Paul E. Grabowski , David F. Chernoff

First principles calculations based on many-electron perturbation theory methods, such as the \textit{ab initio} GW and GW plus Bethe-Salpeter equation (GW-BSE) approach, are reliable ways to predict quasiparticle and optical properties of…

Materials Science · Physics 2017-01-11 Felipe H. da Jornada , Diana Y. Qiu , Steven G. Louie

We derive formulas for the Coulomb matrix within the full-potential linearized augmented-plane-wave (FLAPW) method. The Coulomb matrix is a central ingredient in implementations of many-body perturbation theory, such as the Hartree-Fock and…

Materials Science · Physics 2010-03-01 Christoph Friedrich , Arno Schindlmayr , Stefan Bluegel

An efficient all-electron G$^0$W$^0$ method and a quasiparticle selfconsistent GW (QSGW) method for molecules are proposed in the molecular orbital space with the full random phase approximation. The convergence with basis set is examined.…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 San-Huang Ke

With a super-high-efficient numerical algorithm, we are able to self-consistently calculate the Green's function in the renormalized-ring-diagram approximation for a two-dimensional electron system with long-range Coulomb interactions. The…

Strongly Correlated Electrons · Physics 2011-11-09 Xin-Zhong Yan , C. S. Ting

We present GW calculations of molecules, ordered and disordered solids and interfaces, which employ an efficient contour deformation technique for frequency integration, and do not require the explicit evaluation of virtual electronic…

Materials Science · Physics 2015-01-14 Marco Govoni , Giulia Galli

On the basis of the exact relations the general formula for the static dielectric permittivity for Coulomb system is found in the region of small wave vectors. The obtained formula describes the dielectric function of the Coulomb system in…

Statistical Mechanics · Physics 2017-08-02 V. B. Bobrov , S. A. Trigger

We propose a pseudopotential for the electron-electron Coulomb interaction to improve the efficiency of many-body electronic structure calculations. The pseudopotential accurately replicates the scattering properties of the Coulomb…

Strongly Correlated Electrons · Physics 2015-09-02 J. H. Lloyd-Williams , R. J. Needs , G. J. Conduit

Ab initio GW calculations are a standard method for computing the spectroscopic properties of many materials. The most computationally expensive part in conventional implementations of the method is the generation and summation over the…

Materials Science · Physics 2015-06-11 Jack Deslippe , Georgy Samsonidze , Manish Jain , Marvin L. Cohen , Steven G. Louie

Starting from the random phase approximation for the weakly coupled multiband tightly-bounded electron systems, we calculate the dielectric matrix in terms of intraband and interband transitions. The advantages of this representation with…

Condensed Matter · Physics 2016-08-31 P. Zupanovic , A. Bjelis , S. Barisic

The effective interaction of the electron magnetic moment anomaly with the Coulomb field of superheavy nuclei is investigated by taking into account its dynamical screening at small distances. The shift of the electronic levels, caused by…

Atomic Physics · Physics 2019-02-05 Artem Roenko , Konstantin Sveshnikov

Charged-defect calculation using a periodic supercell is a significant class of problems in solid state physics. However, the finite supercell size induces an undesirable long-range image charge Coulomb interaction. Although a variety of…

Materials Science · Physics 2020-12-30 Zhao-Jun Suo , Jun-Wei Luo , Shu-Shen Li , Lin-Wang Wang

A technique to deal with Coulomb electron distortions in the analysis of (e,e'p) reactions is presented. Thereby, no approximations are made. The suggested technique relies on a partial-wave expansion of the electron wave functions and a…

Nuclear Theory · Physics 2008-11-26 V. Van der Sluys , K. Heyde , J. Ryckebusch , M. Waroquier

Describing the Coulomb interactions between electrons in atomic or molecular systems is an important step to help us obtain accurate results for the different observables in the system. One convenient approach is to separate the dynamic…

Chemical Physics · Physics 2025-01-22 Claude Le Sech , Antonio Sarsa

Ab initio electronic structure calculations of two-dimensional layered structures are typically performed using codes that were developed for three-dimensional structures, which are periodic in all three directions. The introduction of a…

Strongly Correlated Electrons · Physics 2016-06-22 Paolo E. Trevisanutto , Giovanni Vignale