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Highly conductive molecular junctions were formed by direct binding of benzene molecules between two Pt electrodes. Measurements of conductance, isotopic shift in inelastic spectroscopy and shot noise compared with calculations provide…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 M. Kiguchi , O. Tal , S. Wohlthat , F. Pauly , M. Krieger , D. Djukic , J. C. Cuevas , J. M. van Ruitenbeek

In contrast to silicon-based transistors, single molecule junctions can be gated by simple mechanical means. Specifically, charge can be transferred between the junction's electrodes and its molecular bridge when the interelectrode distance…

Mesoscale and Nanoscale Physics · Physics 2023-05-24 Biswajit Pabi , Jakub Šebesta , Richard Korytár , Oren Tal , Atindra Nath Pal

The realization of molecular-based electronic devices depends to a large extent on the ability to mechanically stabilize the involved molecular bonds, while making use of efficient resonant charge transport through the device. Resonant…

Mesoscale and Nanoscale Physics · Physics 2018-09-11 David Gelbwaser-Klimovsky , Alán Aspuru-Guzik , Michael Thoss , Uri Peskin

The experimentally obtained (Venkataraman {\em et al}. \cite{latha}) cosine squared relation of electronic conductance in a biphenyl molecule is verified theoretically within a tight-binding framework. Using Green's function formalism we…

Mesoscale and Nanoscale Physics · Physics 2014-04-25 Santanu K. Maiti

Temperature ($T$) dependent conductance $G = G(T)$ data measured in molecular junctions are routinely taken as evidence for a two-step hopping mechanism. The present paper emphasizes that this is not necessarily the case. A curve of $\ln G$…

Mesoscale and Nanoscale Physics · Physics 2022-12-01 Ioan Baldea

The solid-state structures of organic charge transfer (CT) salts are critical in determining their mode of charge transport, and hence their unusual electrical properties, which range from semiconducting through metallic to superconducting.…

Mesoscale and Nanoscale Physics · Physics 2016-01-05 Andrea Vezzoli , Iain Grace , Carly Brooke , Kun Wang , Colin J. Lambert , Bingqian Xu , Richard J. Nichols , Simon J. Higgins

Single molecule junctions exhibit dynamic structural configurations that strongly influence their electronic and thermoelectric properties. Here, we combine conductance (G) and Seebeck coefficient (S) measurements using the novel AC based…

We investigate transport properties of molecular junctions under two types of bias--a short time pulse or an AC bias--by combining a solution for the Green functions in the time domain with electronic structure information coming from ab…

Mesoscale and Nanoscale Physics · Physics 2010-06-18 San-Huang Ke , Rui Liu , Weitao Yang , Harold U. Baranger

Molecule-electrode contact atomic structures are a critical factor that characterizes molecular devices, but their precise understanding and control still remain elusive. Based on combined first-principles calculations and single-molecule…

Mesoscale and Nanoscale Physics · Physics 2017-08-24 Yong-Hoon Kim , Hu Sung Kim , Juho Lee , Makusu Tsutsui , Tomoji Kawai

Electron transport properties of a biphenyl molecule are studied based on the Green's function formalism. The molecule is sandwiched between two metallic electrodes, where each benzene ring is threaded by a magnetic flux $\phi$. The results…

Mesoscale and Nanoscale Physics · Physics 2009-09-15 Santanu K. Maiti

The influence of decoherence and bonding on the linear conductance of single double-stranded DNA molecules is examined by fitting a phenomenological statistical model developed recently (EPJB {\bf 68}, 237 (2009)) to experimental results.…

Soft Condensed Matter · Physics 2010-09-30 M. Zilly , O. Ujsaghy , D. E. Wolf

It is shown that the conductance of a superconductor-normal metal-superconductor junction can exhibit a significant dependence on the phase of the superconducting order parameter in the situation when the size of the normal region of the…

Condensed Matter · Physics 2007-05-23 F. Zhou , B. Spivak

The influence of vibrational motion on electron conduction through single molecules bound to metal electrodes is investigated employing first-principles electronic-structure calculations and projection-operator Green's function methods.…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 C. Benesch , M. Thoss , W. Domcke , M. Cizek

Understanding the formation of metal-molecule contact at the microscopic level is the key towards controlling and manipulating atomic scale devices. Employing two isomers of bipyridine, $4, 4^\prime$ bipyridine and $2, 2^\prime$ bipyridine…

Mesoscale and Nanoscale Physics · Physics 2021-10-04 Biswajit Pabi , Debayan Mondal , Priya Mahadevan , Atindra Nath Pal

We measure electronic conductance through single conjugated molecules bonded to Au metal electrodes with direct Au-C covalent bonds using the scanning tunneling microscope based break-junction technique. We start with molecules terminated…

Transport properties of metal-molecule-metal junctions containing monolayer of conjugated and saturated molecules with characteristic dimensions in the range of 30-300 nm are correlated with microscopic topography, stress and chemical…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Nikolai B. Zhitenev , Weirong Jiang , Artur Erbe , Zhenan Bao , Eric Garfunkel , Donald M. Tennant , Raymond A. Cirelli

The interaction of carbon monoxide molecules with atomic-scale platinum nanojunctions is investigated by low temperature mechanically controllable break junction experiments. Combining plateaus' length analysis, two dimensional…

Mesoscale and Nanoscale Physics · Physics 2016-01-27 Péter Makk , Zoltán Balogh , Szabolcs Csonka , András Halbritter

A scanning tunnelling microscope has been used to determine the conductance of single molecular wires with the configuration X-bridge-X, X-bridge-Y and Y-bridge-Y (X = thiol terminus and Y = COOH). We find that for molecular wires with…

Mesoscale and Nanoscale Physics · Physics 2015-09-04 S. Martin , D. Manrique , V. M. Garcia-Suarez , W. Haiss , S. J. Higgins , C. J. Lambert , R. J. Nichols

We consider electronic transport through break-junctions bridged by a single molecule in the Kondo regime. We describe the system by a two-channel Anderson model. We take the tunneling matrix elements to depend on the position of the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Jernej Mravlje , Anton Ramsak

Using a break junction technique, we find a clear signature for the formation of conducting hybrid junctions composed of a single organic molecule (benzene, naphthalene or anthracene) connected to chains of platinum atoms. The hybrid…

Mesoscale and Nanoscale Physics · Physics 2015-06-23 Tamar Yelin , Ran Vardimon , Natalia Kuritz , Richard Korytár , Alexei Bagrets , Ferdinand Evers , Leeor Kronik , Oren Tal