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We show that in the presence of ferromagnetic electronic reservoirs and spin-dependent tunnel couplings, molecular vibrations in nonmagnetic single molecular transistors induce an effective intramolecular exchange magnetic field. It…

Mesoscale and Nanoscale Physics · Physics 2015-07-29 S. Weiss , J. Brüggemann , M. Thorwart

Solid state physics deals with systems composed of atoms with strongly bound electrons. The tunneling probability of each electron is determined by interactions that typically extend to neighboring sites, as their corresponding wave…

Materials Science · Physics 2019-11-27 F. Ramírez-Ramírez , E. Flores-Olmedo , G. Báez , E. Sadurní , R. ~A. Méndez-Sánchez

We investigate the effect on molecular transport due to the different structural aspects of metal-molecule interfaces. The example system chosen is the prototypical molecular device formed by sandwiching the phenyl dithiolate molecule (PDT)…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark Ratner

Electron transport properties of a biphenyl molecule are studied based on the Green's function formalism. The molecule is sandwiched between two metallic electrodes, where each benzene ring is threaded by a magnetic flux $\phi$. The results…

Mesoscale and Nanoscale Physics · Physics 2009-09-15 Santanu K. Maiti

In single-molecule transistors, we observe inelastic cotunneling features that correspond energetically to vibrational excitations of the molecule, as determined by Raman and infrared spectroscopy. This is a form of inelastic electron…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. H. Yu , Z. K. Keane , J. W. Ciszek , L. Cheng , M. P. Stewart , J. M. Tour , D. Natelson

We present a microscopic theory of single-electron tunneling through metallic nanoparticles connected to the electrodes through molecular bridges. It combines the theory of electron transport through molecular junctions with the description…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark A. Ratner

We present an analysis of the vibrational dynamics of metal vicinal surfaces using the embedded atom method to describe the interaction potential and both a real space Green's function method and a slab method to calculate the phonons. We…

Materials Science · Physics 2016-08-31 Abdelkader Kara , Talat S. Rahman

The conductance of a single metal-molecule-metal junction depends critically on the conformations of the molecule. In the simple case of a biphenyl, two phenyl rings linked together by a single C-C bond, the conductance is expected to…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Latha Venkataraman , Jennifer E. Klare , Colin Nuckolls , Mark S. Hybertsen , Michael L. Steigerwald

Using first-principles calculations based on density functional theory combined with the non-equilibrium Green's function approach, the transport behaviors of a single-molecule junction formed by benzenedithiol connected to gold electrodes…

Materials Science · Physics 2022-09-20 Rigao Wang , Feng Shuang , Xiaowen Shi , Mingyan Chen

We calculate characteristic correlation functions for the Anderson model with additional phonon-assisted coupling to the odd conduction channel. This model describes, for example, the behavior of a molecule embedded between two electrodes…

Mesoscale and Nanoscale Physics · Physics 2008-03-05 Jernej Mravlje , Anton Ramsak , Rok Zitko

Inspired by recent measurements of forces and conductances of bipyridine nano-junctions, we have performed density functional theory calculations of structure and electron transport in a bipyridine molecule attached between gold electrodes…

Materials Science · Physics 2009-11-11 R. Stadler , K. S. Thygesen , K. W. Jacobsen

We investigate bistability and memory effects in a molecular junction weakly coupled to metallic leads with the latter being subject to an adiabatic periodic change of the bias voltage. The system is described by a simple Anderson-Holstein…

Mesoscale and Nanoscale Physics · Physics 2012-09-20 Andrea Donarini , Abdullah Yar , Milena Grifoni

A theoretical model of a single molecule coupled to many vibronic modes is presented. At low energies, transport is dominated by electron-vibron processes where transfer of an electron through the dot is accompanied by the…

Mesoscale and Nanoscale Physics · Physics 2011-08-19 Abdullah Yar , Andrea Donarini , Sonja Koller , Milena Grifoni

A theoretical model of a single molecule coupled to many vibronic modes is presented. At low energies, transport is dominated by electron-vibron processes where transfer of an electron through the dot is accompanied by the…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 Abdullah Yar , Andrea Donarini , Sonja Koller , Milena Grifoni

We present a way of partly reincorporate the effects of the localized bonding electrons on the dynamics of their itinerant counterparts in Hubbard-like Hamiltonians. This is done by relaxing the constraint that the former should be entirely…

Strongly Correlated Electrons · Physics 2020-09-23 T. V. Trevisan , Gustavo M. Monteiro , A. O. Caldeira

We measure the low bias conductance of a series of substituted benzene diamine molecules while breaking a gold point contact in a solution of the molecules. Transport through these substituted benzenes is by means of nonresonant tunneling…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Latha Venkataraman , Young S. Park , Adam C. Whalley Colin Nuckolls , Mark S. Hybertsen , Michael L. Steigerwald

The thermoelectric transport through a molecular bridge is discussed, with an emphasis on the effects of inelastic processes of the transport electrons caused by the coupling to the vibrational modes of the molecule. In particular it is…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 O. Entin-Wohlman , Y. Imry , A. Aharony

Single-molecule magnets are among the most promising platforms for achieving molecular-scale data storage and processing. Their magnetisation dynamics are determined by the interplay between electronic and vibrational degrees of freedom,…

We study a scheme for electrical detection, using electron spin resonance, of coherent vibrations in a molecular single electron level trapped near a conduction channel. Both equilibrium spin-currents and non-equilibrium spin- and charge…

Mesoscale and Nanoscale Physics · Physics 2008-09-17 J. Fransson , Jian-Xin Zhu

We explore electron transport properties in molecular wires made of heterocyclic molecules (pyrrole, furan and thiophene) by using the Green's function technique. Parametric calculations are given based on the tight-binding model to…

Mesoscale and Nanoscale Physics · Physics 2009-09-13 Santanu K. Maiti , S. N. Karmakar
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