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We use an all-electron implementation of the GW approximation to analyze several possible sources of error in the theory and its implementation. Among these are convergence in the polarization and Green's functions, the dependence of QP…

Materials Science · Physics 2013-05-29 M. van Schilfgaarde , T. Kotani , S. Faleev

Using the finite simulation-cell homogeneous electron gas (HEG) as a model, we investigate the convergence of the correlation energy to the complete basis set (CBS) limit in methods utilising plane-wave wavefunction expansions. Simple…

Computational Physics · Physics 2012-09-11 James J. Shepherd , Andreas Grüneis , George H. Booth , Georg Kresse , Ali Alavi

Methods of bound-state QED that treat the self-energy contributions to the Lamb shift within the partial-wave expansion usually face the problem of slow convergence of the latter. Inspired by an approach formulated in [J. Sapirstein and K.…

Atomic Physics · Physics 2024-04-09 A. V. Malyshev , E. A. Prokhorchuk , V. M. Shabaev

We present a relativistic correction scheme to improve the accuracy of 1s core-level binding energies calculated from Green's function theory in the $GW$ approximation, which does not add computational overhead. An element-specific…

Chemical Physics · Physics 2020-09-23 Levi Keller , Volker Blum , Patrick Rinke , Dorothea Golze

We derive the equations to calculate the reduced width amplitudes (RWA) of the different size clusters and deformed clusters without any approximation. These equations named Laplace expansion method are applicable to the nuclear models…

Nuclear Theory · Physics 2017-03-16 Yohei Chiba , Masaaki Kimura

The GW approximation is a well-known method to improve electronic structure predictions calculated within density functional theory. In this work, we have implemented a computationally efficient GW approach that calculates central…

This PhD thesis is concerned with one-loop virtual electroweak corrections to arbitrary processes in the high-energy limit. Complete results are presented for the leading and subleading logarithms of large ratios of energy scales to mass…

High Energy Physics - Phenomenology · Physics 2007-05-23 Stefano Pozzorini

The electronic band structure of SrTiO$_3$ is investigated in the all-electron QS$GW$ approximation. Unlike previous pseudopotential based QS$GW$ or single-shot $G_0W_0$ calculations, the gap is found to be significantly overestimated…

Materials Science · Physics 2018-01-31 Churna Bhandari , Mark van Schilfgaarde , Takao Kotani , Walter R. L. Lambrecht

We formulate a Hartree-Fock-LAPW method for electronic band structure calculations. The method is based on the Hartree-Fock-Roothaan approach for solids with extended electron states and closed core shells where the basis functions of…

Materials Science · Physics 2016-08-31 A. V. Nikolaev , P. N. Dyachkov

We analyze a data set comprising 370 GW band structures composed of 61716 quasiparticle (QP) energies of two-dimensional (2D) materials spanning 14 crystal structures and 52 elements. The data results from PAW plane wave based one-shot…

Materials Science · Physics 2021-01-05 Asbjørn Rasmussen , Thorsten Deilmann , Kristian S. Thygesen

We present an approach to calculate the electronic structure for a range of materials using the quasiparticle self-consistent GW method with vertex corrections included in the screened Coulomb interaction W. This is achieved by solving the…

Materials Science · Physics 2023-10-10 Brian Cunningham , Myrta Gruening , Dimitar Pashov , Mark van Schilfgaarde

The optimized-effective-potential (OEP) method is a special technique to construct local Kohn-Sham potentials from general orbital-dependent energy functionals. In a recent publication [M. Betzinger, C. Friedrich, S. Bl\"ugel, A. G\"orling,…

Materials Science · Physics 2012-06-22 Markus Betzinger , Christoph Friedrich , Andreas Görling , Stefan Blügel

The LDA-1/2 method has proven to be a viable approach for calculating band gaps of semiconductors. To address its accuracy for finite systems, we apply LDA-1/2 to atoms and the molecules of the $GW100$ test set. The obtained energies of the…

Materials Science · Physics 2018-08-31 Ronaldo Rodrigues Pela , Andris Gulans , Claudia Draxl

The cross-section for W^+W^- \to W^+W^- with arbitrarily polarized W bosons is calculated within the Electroweak Standard Model including the complete virtual and soft-photonic O(alpha) corrections. We show the numerical importance of the…

High Energy Physics - Phenomenology · Physics 2008-11-26 A. Denner , T. Hahn

We present a simple and accurate GW implementation based on a combination of a Laplace transformation (LT) and other acceleration techniques used in post-SCF quantum chemistry, namely, natural auxiliary functions and the frozen-core…

Chemical Physics · Physics 2023-11-16 Johannes Tölle , Niklas Niemeyer , Johannes Neugebauer

The projector-augmented wave (PAW) method is one of the approaches that are widely used to approximately treat core electrons and thus to speed-up plane-wave basis set electronic structure calculations. However, PAW involves approximations…

Chemical Physics · Physics 2023-08-24 Sirous Yourdkhani , Jiri Klimes

We present a simple, robust and black-box approach to the implementation and use of local, periodic, atom-centered Gaussian basis functions within a plane wave code, in a computationally efficient manner. The procedure outlined is based on…

Strongly Correlated Electrons · Physics 2016-09-21 George H. Booth , Theodoros Tsatsoulis , Garnet Kin-Lic Chan , Andreas Grüneis

A method for performing variable-width (thawed) Gaussian wavepacket (GWP) variational dynamics on machine-learned potentials is presented. Instead of fitting the potential energy surface (PES), the anharmonic correction to the global…

Chemical Physics · Physics 2024-12-17 Rami Gherib , Ilya G. Ryabinkin , Scott N. Genin

We present a novel algorithm which can overcome the drawbacks of the conventional linear scaling method with minimal computational overhead. This is achieved by introducing additional constraints, thus eliminating the redundancy of the…

Materials Science · Physics 2015-06-25 Eiji Tsuchida

In solid-state physics, energies of molecular systems are usually computed with a plane-wave discretization of Kohn-Sham equations. A priori estimates of plane-wave convergence for periodic Kohn-Sham calculations with pseudopotentials have…

Numerical Analysis · Mathematics 2023-01-02 Mi-Song Dupuy