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This paper studies a mathematical formalism of nonequilibrium thermodynamics for chemical reaction models with $N$ species, $M$ reactions, and general rate law. We establish a mathematical basis for J. W. Gibbs' macroscopic chemical…

Mathematical Physics · Physics 2017-01-04 Hao Ge , Hong Qian

At low temperature a thermodynamic system undergoes a phase transition when a physical parameter passes through a singularity point of the free energy, corresponding to formation of a new order. At high temperature the thermal fluctuations…

Statistical Mechanics · Physics 2014-06-17 Bo-Bo Wei , Shao-Wen Chen , Hoi-Chun Po , Ren-Bao Liu

The problem of the insensitivity of the macroscopic behavior of any thermodynamical system to partitioning generates a bias between the reproducibility of its macroscopic behavior viewed as the simplest form of causality and its long-term…

General Physics · Physics 2007-05-23 Maria K. Koleva

The response of thermodynamic systems perturbed out of an equilibrium steady-state is described by the reciprocal and the fluctuation-dissipation relations. The so-called fluctuation theorems extended the study of fluctuations far beyond…

Statistical Mechanics · Physics 2020-02-21 Matteo Polettini , Massimiliano Esposito

Macroscopic thermodynamics of equilibrium is constructed for systems obeying power-law canonical distributions. With this, the connection between macroscopic thermodynamics and microscopic statistical thermodynamics is generalized. This is…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , A. K. Rajagopal

Thermodynamic conventions suffer from describing dynamical distinctions, especially when the structural and energetic changes induced by localized rare events are insignificant. By using the ensemble theory in the trajectory space, we…

Statistical Mechanics · Physics 2023-03-30 Qi-Jun Ye , Xin-Zheng Li

We consider the thermodynamic approach to the description of economic systems and processes. The first and second laws of thermodynamics as applied to economic systems are derived and analyzed. It is shown that there is a deep analogy…

General Finance · Quantitative Finance 2021-02-03 Sergey Rashkovskiy

A thermodynamic description of cosmological spacetimes may provide insights into the fundamentals of the cosmic evolution that remain otherwise obscure, similar to `black hole thermodynamics'. We investigate the thermodynamic properties of…

General Relativity and Quantum Cosmology · Physics 2026-03-31 Dipayan Mukherjee , Harkirat Singh Sahota , Swati Gavas

We introduce a new tool for the quantitative characterisation of the departure form Markovianity of a given dynamical process. Our tool can be applied to a generic $N$-level system and extended straightforwardly to Gaussian…

Quantum Physics · Physics 2015-06-15 S. Lorenzo , F. Plastina , M. Paternostro

In isolated quantum many-body systems periodically driven in time, the asymptotic dynamics at late times can exhibit distinct behavior such as thermalization or dynamical freezing. Understanding the properties of and the convergence towards…

Strongly Correlated Electrons · Physics 2025-10-23 Luke Staszewski , Asmi Haldar , Pieter W. Claeys , Alexander Wietek

In economics, construction of perfect models in a way that would be comparable to the standards customary in physical sciences is generally not feasible. In particular, the observed value for an economic equilibrium may deviate…

Probability · Mathematics 2026-01-05 Esa Nummelin , Elja Arjas

We present in detail a Langevin formalism for constructing stochastic dynamical equations for active-matter systems coupled to a thermal bath. We apply the formalism to clarify issues of principle regarding the sources and signatures of…

Soft Condensed Matter · Physics 2018-12-26 Lokrshi Prawar Dadhichi , Ananyo Maitra , Sriram Ramaswamy

We introduce a hydrodynamic framework for describing monitored classical stochastic processes. We study the conditional ensembles for these monitored processes -- i.e., we compute spacetime correlation functions conditioned on a fixed,…

Statistical Mechanics · Physics 2026-02-19 Sarang Gopalakrishnan , Ewan McCulloch , Romain Vasseur

Traditional quantum thermodynamic frameworks associate work to energy exchanges induced by unitary transformations generated by external controls, and heat to energy exchanges induced by bath interaction. Recently, a framework was…

Quantum Physics · Physics 2026-01-06 Tiago F. F. Santos , Camille Latune

We propose a Gaussian ensemble as a description of the long-time dynamics of isolated quantum integrable systems. Our approach extends the Generalized Gibbs Ensemble (GGE) by incorporating fluctuations of integrals of motion. It is…

Statistical Mechanics · Physics 2017-05-24 Hyungwon Kim , Anatoli Polkovnikov , Emil A. Yuzbashyan

Dynamical equations describing physical systems at statistical equilibrium are commonly extended by mathematical tools called "thermostats". These tools are designed for sampling ensembles of statistical mechanics. We propose a dynamic…

Data Analysis, Statistics and Probability · Physics 2018-01-17 A. Samoletov , B. Vasiev

Lack of knowledge about the detailed many-particle motion on the microscopic scale is a key issue in any theoretical description of a macroscopic experiment. For systems at or close to thermal equilibrium, statistical mechanics provides a…

Statistical Mechanics · Physics 2016-03-03 Peter Reimann

Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory…

Quantum Physics · Physics 2020-03-04 Philipp Strasberg

The thermodynamic uncertainty relation, which establishes a universal trade-off between nonequilibrium current fluctuations and dissipation, has been found for various Markovian systems. However, this relation has not been revealed for…

Statistical Mechanics · Physics 2019-07-24 Tan Van Vu , Yoshihiko Hasegawa

Self-propulsion allows living systems to display unusual collective behavior. Unlike passive systems in thermal equilibrium, active matter systems are not constrained by conventional thermodynamic laws. A question arises however as to what…

Soft Condensed Matter · Physics 2015-03-18 Sho C. Takatori , John F. Brady