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Using different segmental dynamics and relaxation, characteristics of the interface growth is examined in an electrophoretic deposition of polymer chains on a three (2+1) dimensional discrete lattice with a Monte Carlo simulation.…

Soft Condensed Matter · Physics 2007-05-23 Frank W. Bentrem , Jun Xie , R. B. Pandey

By means of contact-density chain-growth simulations, we investigate a simple lattice model of a flexible polymer interacting with an attractive substrate. The contact density is a function of the numbers of monomer-substrate and…

Statistical Mechanics · Physics 2011-07-04 Michael Bachmann

We report molecular dynamics simulation results on the equilibrium properties of polymer thin films adsorbed onto flat and curved substrates. We first systematically determine the contact angle of polymer droplets on flat substrates as a…

Soft Condensed Matter · Physics 2023-12-15 Gabriel Catalini , Nicolás A. García , Daniel A. Vega , Arash Nikoubashman

Polymer thin films exhibit pronounced interfacial mobility gradients that modify chain relaxation, yet how these gradients govern chain-scale dynamics across depth remains incompletely understood. Using molecular dynamics simulations of…

Soft Condensed Matter · Physics 2026-02-27 Bao T. Ma , David S. Simmons

The density relaxation phenomenon is modeled using both Monte Carlo and dissipative MD simulations to investigate the effects of regular taps applied to a vessel having a planar floor filled with monodisperse spheres. Results suggest the…

Disordered Systems and Neural Networks · Physics 2009-01-05 O. Dybenko , A. D. Rosato , D. J. Horntrop , V. Ratnaswamy , L. Kondic

Nonequilibrium molecular dynamics simulations are used to study the shear thinning behavior of immiscible symmetric polymer blends. The phase separated polymers are subjected to a simple shear flow imposed by moving a wall parallel to the…

Soft Condensed Matter · Physics 2009-11-07 Sandra Barsky , Mark O. Robbins

Growth and roughness of the interface of deposited polymer chains driven by a field onto an impenetrable adsorbing surface are studied by computer simulations in (2+1) dimensions. The evolution of the interface width W shows a crossover…

Soft Condensed Matter · Physics 2007-05-23 Frank W. Bentrem , R. B. Pandey , Fereydoon Family

In this paper, we employ Molecular Dynamics computer simulations to study and compare the statics and dynamics of linear and circular (ring) polymer chains in entangled solutions of different densities. While we confirm that linear chain…

Soft Condensed Matter · Physics 2016-02-17 Negar Nahali , Angelo Rosa

We present some results of Monte Carlo simulations for the deposition of particles of different sizes on a two-dimensional substrate. The particles are linear, height one, and can be deposited randomly only in the two, $x$ and $y$…

Statistical Mechanics · Physics 2010-06-15 F. L. Forgerini , W. Figueiredo

The morphological scaling properties of linear polymer films grown by vapor deposition polymerization (VDP) are studied by 1+1D Monte Carlo simulations. The model implements the basic processes of random angle ballistic deposition ($F$),…

Computational Physics · Physics 2010-10-25 Sairam Tangirala , David P. Landau , Y. -P. Zhao

Thermal scaling and relaxation of the interface width in an electrophoretic deposition of polymer chains is examined by a three-dimensional Monte Carlo simulation on a discrete lattice. Variation of the equilibrium interface width $W_r$…

Soft Condensed Matter · Physics 2007-05-23 Frank W. Bentrem , Ras B. Pandey

Using molecular dynamics simulations we examine the dynamics of a family of model polymers with varying chain length and torsional potential barriers. We focus on features of the dynamics of polymers that are seen experimentally but absent…

Soft Condensed Matter · Physics 2019-06-11 Daniel Fragiadakis , C. Michael Roland

We study the dynamics of a single chain polymer confined to a two dimensional cell. We introduce a kinetically constrained lattice gas model that preserves the connectivity of the chain, and we use this kinetically constrained model to…

Statistical Mechanics · Physics 2011-11-09 Armin Rahmani , Claudio Castelnovo , Jeremy Schmit , Claudio Chamon

We study the diffusion of a linear polymer in the presence of permeable membranes without excluded volume interactions, using scaling theory and Monte Carlo simulations. We find that the average time it takes for a chain with polymerization…

Condensed Matter · Physics 2016-08-31 Hyoungsoo Yoon , J. M. Deutsch

Polydisperse brushes obtained by reversible radical chain polymerization reaction onto a solid substrate with surface-attached initiators, are studied by means of an off-lattice Monte Carlo algorithm of living polymers (LP). Various…

Statistical Mechanics · Physics 2009-10-31 A. Milchev , J. P. Wittmer , D. P. Landau

Large scale Monte Carlo simulations of dense layers of grafted polymer chains in good solvent conditions are used to explore the relaxation of a polymer brush. Monomer displacements are analyzed for the directions parallel and perpendicular…

Soft Condensed Matter · Physics 2021-04-13 Michael Lang , Marco Werner , Ron Dockhorn , Torsten Kreer

We examine the phase transition of polymer adsorption as well as the underlying kinetics of polymer binding from dilute solutions on a structureless solid surface. The emphasis is put on the properties of regular multiblock copolymers,…

Soft Condensed Matter · Physics 2009-09-03 A. Milchev , V. Rostiashvili , S. Bhattacharya , T. Vilgis

An off-lattice Monte Carlo algorithm for solutions of equilibrium polymers (EP) is proposed. At low and moderate densities this is shown to reproduce faithfully the (static) properties found recently for flexible linear EP using a lattice…

Statistical Mechanics · Physics 2009-10-31 A. Milchev , J. P. Wittmer , D. P. Landau

We study the surface growth generated by the random deposition of particles of different sizes. A model is proposed where the particles are aggregated on an initially flat surface, giving rise to a rough interface and a porous bulk. By…

Statistical Mechanics · Physics 2010-03-19 F. L. Forgerini , W. Figueiredo

Nonequilibrium molecular dynamics simulations are used to study the deformation behavior of disperse polymer melts by tracking test chains of length N = Mw, the weight average molecular weight, in melts of varying dispersity. At high strain…

Soft Condensed Matter · Physics 2025-07-29 Taofeek Tejuosho , Janani Sampath
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