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This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

In this paper, we present some geometric properties of the maximum entropy (MaxEnt) Tsallis- distributions under energy constraint. In the case q > 1, these distributions are proved to be marginals of uniform distributions on the sphere; in…

Statistical Mechanics · Physics 2009-11-11 C. Vignat , A. Plastino

It is shown that Tsallis' generalized statistics provides a natural frame for the statistical-thermodynamical description of anomalous diffusion. Within this generalized theory, a maximum-entropy formalism makes it possible to derive a…

Statistical Mechanics · Physics 2015-06-25 Damian H. Zanette

The physical significance of the stochastic processes associated to the generalized Gibbs ensembles is scrutinized here with special attention to the thermodynamic fluctuations of small systems. The contact with the environment produces an…

Statistical Mechanics · Physics 2024-09-04 Amilcare Porporato , Salvatore Calabrese , Lamberto Rondoni

Depending on the exact experimental conditions, the thermodynamic properties of physical systems can be related to one or more thermostatistical ensembles. Here, we survey the notion of thermodynamic temperature in different statistical…

Statistical Mechanics · Physics 2016-05-05 Peter Hänggi , Stefan Hilbert , Jörn Dunkel

For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…

Statistical Mechanics · Physics 2010-02-08 Eliran Boksenbojm , Bram Wynants , Christopher Jarzynski

Microcanonical Thermodynamics allows the application of Statistical Mechanics on one hand to closed finite and even small systems and on the other to the largest,self-gravitating ones. However, one has to reconsider the fundamental…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Nonadditive composition rules for several physical quantities are treated in thermodynamics. It is argued that the zeroth law defines the existence of their additive forms, the formal logarithms. A further principle, the universal…

Statistical Mechanics · Physics 2013-01-08 P. Ván , G. G. Barnaföldi , T. S. Biró , K Ürmössy

Although generalized ensembles have now been in use in statistical mechanics for decades, including frameworks such as Tsallis' nonextensive statistics and superstatistics, a classification of these generalized ensembles outlining the…

Statistical Mechanics · Physics 2022-11-09 Sergio Davis

Superstatistics describes statistical systems that behave like superpositions of different inverse temperatures $\beta$, so that the probability distribution is $p(\epsilon_i) \propto \int_{0}^{\infty} f(\beta) e^{-\beta \epsilon_i}d\beta$,…

Statistical Mechanics · Physics 2016-10-03 Rudolf Hanel , Stefan Thurner , Murray Gell-Mann

Tsallis and R\'{e}nyi entropy measures are two possible different generalizations of the Boltzmann-Gibbs entropy (or Shannon's information) but are not generalizations of each others. It is however the Sharma-Mittal measure, which was…

Statistical Mechanics · Physics 2014-10-13 Marco Masi

Many complex systems are characterized by non-Boltzmann distribution functions of their statistical variables. If one wants to -- justified or not -- hold on to the maximum entropy principle for complex statistical systems (non-Boltzmann)…

Statistical Mechanics · Physics 2009-11-13 Stefan Thurner , Rudolf Hanel

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

Firstly, we calculate quantitatively decrease of entropy by the known formulas in the ordering phenomena and nucleation of thermodynamics of microstructure. They show again that a necessary condition of decrease of entropy in isolated…

General Physics · Physics 2009-05-04 Yi-Fang Chang

We present a stability analysis of the classical ideal gas in a new theory of nonextensive statistics and use the theory to understand the phenomena of negative specific heat in some self-gravitating systems. The stability analysis is made…

Statistical Mechanics · Physics 2015-08-10 Liyan Liu , Zhipeng Liu , Lina Guo

Evidence implies that basic laws of thermodynamics must be tested by experiments. In this paper, an experiment is designed to measure the entropy of a system with at least one known (measurable) equation of state, especially the gas…

General Physics · Physics 2007-05-23 Bin Zhou

The laws of thermodynamics, despite their wide range of applicability, are known to break down when systems are correlated with their environments. Here, we generalize thermodynamics to physical scenarios which allow presence of…

Quantum Physics · Physics 2018-02-06 Manabendra Nath Bera , Arnau Riera , Maciej Lewenstein , Andreas Winter

The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…

Statistical Mechanics · Physics 2017-06-07 William Griffin , Michael Matty , Robert H. Swendsen

In this letter, we study the limit behavior of the evolution of Tsallis entropy in self-gravitating systems. The study is carried out under two different situations, drawing the same conclusion. No matter in the energy transfer process or…

Statistical Mechanics · Physics 2017-10-11 Yahui Zheng , Jiulin Du , Faku Liang

In the present paper are analysed the conditions for the validity of the Tsallis Statistics. The same have been done following the analogy with the traditional case: starting from the microcanonical description of the systems and analysing…

Condensed Matter · Physics 2007-05-23 L. Velazquez , F. Guzman