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We report on the preparation and characterization of single crystal gamma phase NaxCoO2 with 0.25 < x < 0.84 using a non-aqueous electrochemical chronoamperemetry technique. By carefully mapping the overpotential versus x (for x < 0.84), we…

Strongly Correlated Electrons · Physics 2009-11-13 G. J. Shu , Andrea Prodi , S. Y. Chu , Y. S. Lee , H. S. Sheu , F. C. Chou

We have developed a novel method for crystalline hydrogenation of graphene on the nanoscale. Molecular hydrogen was physisorbed at 5 K onto pristine graphene islands grown on Cu(111) in ultrahigh vacuum. Field emission local to the tip of a…

Mesoscale and Nanoscale Physics · Physics 2017-06-06 S. J. Tjung , S. M. Hollen , G. A. Gambrel , N. M. Santagata , E. Johnston-Halperin , J. A. Gupta

Nuclear spin hyperpolarization provides a promising route to overcome the challenges imposed by the limited sensitivity of nuclear magnetic resonance. Here we demonstrate that dissolution of spin-polarized pentacene-doped naphthalene…

The atomistic structure of metallic glasses is closely related to properties such as strength and ductility. Here, Ni1-xBx metallic glass nanoparticles of two different sizes are compressed under quasi-hydrostatic high-pressure conditions…

Colloidal materials of tin(II) sulfide (SnS), as a layered semiconductor with a narrow band gap, are emerging as a potential alternative to the more toxic metal chalcogenides (PbS, PbSe, CdS, CdSe) for various applications such as…

ZnAs2 nanoclusters were fabricated by incorporation into pores of zeolite Na-X and by laser ablation. Absorption and photoluminescence spectra of ZnAs2 nanoclusters in zeolite were measured at the temperatures of 4.2, 77 and 293 K. Both…

Materials Science · Physics 2009-11-11 O. A. Yeshchenko , I. M. Dmitruk , S. V. Koryakov , M. P. Galak , I. P. Pundyk , L. M. Hohlova

The optical and vibrational properties of nanocrystalline thin films of MoS2, comprised of a mixture of edge terminated vertically aligned (ETVA) and (001)-oriented regions, on large insulating substrates are reported. From high resolution…

Recent advances in the experimental growth and control of disordered thin films, heterostructures, and interfaces provide a fertile ground for the observation and characterisation of the collective superconducting excitations emerging below…

Single-crystal nanoparticles of silicon, several tens of nm in diameter, may be suitable as building blocks for single-nanoparticle electronic devices. Previous studies of nanoparticles produced in low-pressure plasmas have demonstrated the…

Crystallization of supersaturated liquids usually starts by heterogeneous nucleation. Mounting evidence shows that even homogeneous nucleation in simple liquids takes place in two steps; first a dense amorphous precursor forms, and the…

Materials Science · Physics 2014-07-15 László Gránásy , Frigyes Podmaniczky , Gyula I. Tóth , György Tegze , Tamás Pusztai

We demonstrate the growth of graphene nanocrystals by molecular beam methods that employ a solid carbon source, and that can be used on a diverse class of large area dielectric substrates. Characterization by Raman and Near Edge X-ray…

Metal halide perovskites represent a flourishing area of research, driven by both their potential application in photo-voltaics and optoelectronics, and for the fundamental science underpinning their unique optoelectronic properties. The…

Materials Science · Physics 2020-10-29 Javad Shamsi , Alexander S. Urban , Muhammad Imran , Luca De Trizio , Liberato Manna

Embedded Si and Ge nanocrystals (NCs) in wide band-gap matrices are studied theoretically using an atomistic pseudopotential approach. From small clusters to large NCs containing on the order of several thousand atoms are considered.…

Materials Science · Physics 2007-11-27 C. Bulutay

A number of metal-based nanopowders such kinds as Fe, Co, Fe/Co alloy, Fe/C, Fe/organic shell were successfully produced by aerosol synthesis method. The mechanism of nanoparticles formation and the influence of experimental parameters on…

Materials Science · Physics 2007-08-13 E. S. Vasilieva , O. V. Tolochko , V. E. Yudin , D. Kim , D. -W. Lee

We report on the production of ordered assemblies of silicon nanostructures by means of irradiation of a Si(100) substrate with 1.2 keV Ar ions at normal incidence. Atomic Force and High-Resolution Transmission Electron microscopies show…

Materials Science · Physics 2009-11-07 Raul Gago , Luis Vazquez , Rodolfo Cuerno , Maria Varela , Carmen Ballesteros , Jose M. Albella

Single crystals of MgB2 with a size up to 1.5x0.9x0.2 mm3 have been grown with a high pressure cubic anvil technique. The crystal growth process is very peculiar and involves an intermediate nitride, namely MgNB9. Single crystals of BN and…

Embedded germanium nanocrystals (NCs) in a silica host matrix are theoretically analyzed to identify their third-order bound-state nonlinearities. A rigorous atomistic pseudopotential approach is used for determining the electronic…

Materials Science · Physics 2008-08-18 Hasan Yildirim , Ceyhun Bulutay

Periodic structures of phases with orientational order of molecules, but homogenous electron density distribution: a short pitch cholesteric, blue phase and twist-bend nematic phase, were probed by a resonant soft x-ray scattering (RSoXS)…

Soft Condensed Matter · Physics 2017-04-19 Mirosław Salamończyk , Nataša Vaupotič , Damian Pociecha , Cheng Wang , Chenhui Zhu , Ewa Gorecka

A water soluble amorphous form of silk was made by ultra-short laser pulse irradiation and detected by nanoscale IR mapping. An optical absorption-induced nanoscale surface expansion was probed to yield the spectral response of silk at IR…

This work presents a cost-effective alternative technology for the formation of nanostructured semiconductor materials for tunable light emitting devices. CdS and ZnS semiconducting colloid nanoparticles coated with organic shell,…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Suryajaya , A. Nabok , F. Davis , A. Hassan , S. P. J. Higson , J. Evans-Freeman