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New carbon forms exhibiting extraordinary physico-chemical properties can be generated from nanostructured precursors under extreme pressure. Nevertheless, synthesis of such fascinating materials is often not well understood that results,…

Using the catalytic CO oxidation at RuO2(110) as a showcase, we employ first-principles kinetic Monte Carlo simulations to illustrate the intricate effects on temperature programmed reaction spectroscopy data brought about by the mere…

Materials Science · Physics 2009-11-13 Michael Rieger , Jutta Rogal , Karsten Reuter

We compute electrostatic fields induced deformations of cantilevered finite-length metallic carbon nanotubes, using an energy minimization method based on a charge-dipole moment interaction potential combined with an empirical many-body…

Mesoscale and Nanoscale Physics · Physics 2018-10-26 Z. Wang , M. Devel

The bending of a carbon nanotube is studied by considering the structural evolution of a carbon nanotorus from elastic deformation to the onset of the kinks and eventually to the collapse of the walls of the nanotorus. The changes in the…

Materials Science · Physics 2009-10-31 Lei Liu , C. S. Jayanthi , S. Y. Wu

The measured electric resistance of carbon nanotubes wrapped with DNA molecules depends strongly on the spin of the injected electrons. Motivated by these experiments, we study the effect of helix-shaped potentials on the electronic…

Mesoscale and Nanoscale Physics · Physics 2018-11-14 Yotam Perlitz , Karen Michaeli

We use ab initio density functional calculations to study hydrogen-induced disintegration of single- and multi-wall carbon fullerenes and nanotubes. Our results indicate that hydrogen atoms preferentially chemisorb along lines in sp2 bonded…

Mesoscale and Nanoscale Physics · Physics 2009-09-08 Savas Berber , David Tomanek

By using a newly fitted multi-parameter potential to describe the van der Waals interaction between carbon and molecular hydrogen, we study the hydrogen storage inside carbon nanotubes (CNT's) under pressure in gigapascal range. Comparing…

Materials Science · Physics 2007-07-09 X. H. Zhang , X. G. Gong , Z. F. Liu

During the catalytic synthesis of graphene, nanotubes, fibers, and other nanostructures, many intriguing phenomena occur, such as phase separation, precipitation, and analogs of capillary action. We demonstrate that catalytic nanoparticles…

Mesoscale and Nanoscale Physics · Physics 2018-04-11 Pin Ann Lin , Bharath Natarajan , Michael Zwolak , Renu Sharma

Dielectric screening plays a vital role for the physical properties in the nanoscale and also alters our ability to detect and characterize nanomaterials by optical techniques. We study the dielectric screening inside of carbon nanotubes…

Mesoscale and Nanoscale Physics · Physics 2024-04-02 Georgy Gordeev , Sören Wasserroth , Han Li , Ado Jorio , Benjamin S. Flavel , Stephanie Reich

Fullerenes, including \ce{C60} and \ce{C70}, have been detected in various astronomical environments. Understanding how their structures evolve over time is essential for gaining insights into their life cycle and making further…

Solar and Stellar Astrophysics · Physics 2023-10-27 Zhisen Meng , Zhao Wang

A (10x10) single-walled carbon nanotube consisting of 400 atoms with 20 layers is simulated under tensile loading using our developed O(N) parallel tight-binding molecular-dynamics algorithms. It is observed that the simulated carbon…

Condensed Matter · Physics 2009-11-10 G. Dereli , C. Ozdogan

Ability to encapsulate molecules is one of the outstanding features of nanotubes. The encapsulation alters physical and chemical properties of both nanotubes and guest species. The latter normally form a separate phase, exhibiting…

Materials Science · Physics 2014-07-23 Vitaly Chaban , Oleg Prezhdo

This study describes computer simulations of carbonization and graphite formation, including the effects of hydrogen, nitrogen, oxygen, and sulfur. We introduce a novel technique to simulate carbonization, "Simulation of Thermal Emission of…

Materials Science · Physics 2023-08-31 C. Ugwumadu , R. Olson , N. L. Smith , K. Nepal , Y. Al-Majali , J. Trembly , D. A. Drabold

Crystallization pressure drives deformation and damage in monuments, buildings and the Earth's crust. Even though the phenomenon has been known for 170 years there is no agreement between theoretical calculations of the maximum attainable…

Advances in first-principles computational approaches have, over the past fifteen years, made possible the investigation of physical properties of ferroelectric systems. In particular, such approaches have led to a microscopic understanding…

Materials Science · Physics 2007-05-23 Igor A. Kornev , L. Bellaiche

Carbon fiber and graphene-based nanostructures such as carbon nanotubes (CNTs) and defective structures have extraordinary potential as strong and lightweight materials. A longstanding bottleneck has been lack of understanding and…

Materials Science · Physics 2021-10-26 Qi Zhao , Jordan J. Winetrout , Yanxun Xu , Yusu Wang , Hendrik Heinz

The structural properties under hydrostatic pressure up to 3 GPa of the layered rare earth carbide halide superconductor Y2C2I2 are studied by neutron powder diffraction at room temperature. The compressibilities are anisotropic, such that…

We predict new forms of carbon consisting of one and two dimensional networks of interlinked single wall carbon nanotubes, some of which are energetically more stable than van der Waals packing of the nanotubes on a hexagonal lattice. These…

Materials Science · Physics 2009-10-31 T. Yildirim , O. Gulseren , C. Kilic , S. Ciraci

We have investigated several ultra-thin copper nanobridges between supporting layers using a classical molecular dynamics simulation and a many-body potential function of the second-moment approximation of tight-binding scheme. This…

Materials Science · Physics 2009-11-07 Jeong Won Kang , Ho Jung Hwang

In this article we investigate through molecular dynamics simulations the diffusion behavior of the TIP4P/2005 water when confined in pristine and deformed carbon nanotubes (armchair and zigzag). To analyze different diffusive mechanisms,…

Soft Condensed Matter · Physics 2021-02-03 Bruno H. S. Mendonça , Patricia Ternes , Evy Salcedo , Alan B. de Oliveira , Marcia C. Barbosa