Related papers: Nonconcave entropies from generalized canonical en…
Entropy and free-energy estimation are key in thermodynamic characterization of simulated systems ranging from spin models through polymers, colloids, protein structure, and drug-design. Current techniques suffer from being model specific,…
In the nonextensive Tsallis scenario, Page's conjecture for the average entropy of a subsystem[Phys. Rev. Lett. {\bf 71}, 1291(1993)] as well as its demonstration are generalized, i.e., when a pure quantum system, whose Hilbert space…
We devise a hierarchy of computational algorithms to enumerate the microstates of a system comprising N independent, distinguishable particles. An important challenge is to cope with integers that increase exponentially with system size,…
In complex systems with many degrees of freedom such as peptides and proteins there exist a huge number of local-minimum-energy states. Conventional simulations in the canonical ensemble are of little use, because they tend to get trapped…
In this paper, we study the physics of mesoscopic systems with noninteracting, but fixed number of electrons. From a technical point of view, this means a discussion of the differences between the canonical and the grand canonical ensemble…
We develop a generalized theory of (meta)equilibrium statistical mechanics in the thermodynamic limit valid for both smooth and fractal phase spaces. In the former case, our approach leads naturally to Boltzmann-Gibbs standard…
A thermodynamic expression for the analog of the canonical ensemble for nonequilibrium systems is described based on a purely information theoretical interpretation of entropy. As an application, it is shown that this nonequilibrium…
Equilibrium canonical distribution in statistical mechanics assumes weak system-bath coupling (SBC). In real physical situations this assumption can be invalid and equilibrium quantum statistics of the system may be non-canonical. By…
The physical meaning of entropy is analyzed in the context of statistical, nuclear, atomic physics and cosmology. Only the microcanonical Boltzmann entropy leads to no contradictions in several simple, elementary and for thermodynamics…
We study a classical integrable (Neumann) model describing the motion of a particle on the sphere, subject to harmonic forces. We tackle the problem in the infinite dimensional limit by introducing a soft version in which the spherical…
Employing different statistical ensembles may lead to qualitatively different results concerning averages of physical observables on the mesoscopic scale. Here we discuss differences between the canonical and the grandcanonical ensembles…
The particle number and energy fluctuations in the system of charged particles are studied in the canonical ensemble for non-zero net values of the conserved charge. In the thermodynamic limit the fluctuations in the canonical ensemble are…
We recently showed [Phys. Rev. Lett. 121, 220602 (2018)] that the average bipartite entanglement entropy of all energy eigenstates of the quantum Ising chain exhibits a universal (for translationally invariant quadratic fermionic models)…
Depending on the exact experimental conditions, the thermodynamic properties of physical systems can be related to one or more thermostatistical ensembles. Here, we survey the notion of thermodynamic temperature in different statistical…
Evaporation/condensation transition of the Potts model on square lattice is numerically investigated by the Wang-Landau sampling method. Intrinsically system size dependent discrete transition between supersaturation state and…
We show insurmountable contradictions which arise if statistical ensembles are considered a consequence of the influence of the environment of the physical systems. We regard the multiplicity of states with a definite energy value as a…
Molecular or condensed matter systems are often well approximated by hybrid quantum-classical models: the electrons retain their quantum character, whereas the ions are considered to be classical particles. We discuss various alternative…
Inflationary models with a non-zero background curvature require additional hypothesis or parameters compared to flat inflation and the procedure to construct them cannot be as simple as in the flat case. For this reason, there is no…
The entropy of an electronic system offers important insights into the nature of its quantum mechanical ground state. This is particularly valuable in cases where the state is difficult to identify by conventional experimental probes, such…
We propose a general definition of nonequilibrium entropy of a classical stochastic field. As an example of particular interest in cosmology we apply this definition to compute the entropy of density perturbations in an inflationary…