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Dynamics of thin films of poly(vinyl acetate) (PVAc) and poly(methyl methacrylate) (PMMA) have been investigated by dielectric relaxation spectroscopy in the frequency range from 0.1Hz to 1MHz at temperatures from 263K to 423K. The…

Soft Condensed Matter · Physics 2009-11-07 Koji Fukao , Shinobu Uno , Yoshihisa Miyamoto , Akitaka Hoshino , Hideki Miyaji

Brillouin scattering has been used to measure the dynamic structure factor of glycerol as a function of temperature from the high temperature liquid to the glassy state. Our investigation aims at understanding the number and the nature of…

Soft Condensed Matter · Physics 2009-11-10 Lucia Comez , Daniele Fioretto , Filippo Scarponi , Giulio Monaco

Significant progress has been made in recent years in understanding the dynamics of pure hydrogen-bonded systems by analyzing the spectral shape of various susceptibilities. Monohydroxy- and polyalcohols are currently considered to form…

Soft Condensed Matter · Physics 2025-11-11 Jan Philipp Gabriel

We study the pressure dependence of the superconducting transition temperature of an organic superconductor $\beta'$-(BEDT-TTF)$_2$ICl$_2$ by applying the fluctuation exchange method to the Hubbard model on the original two-band lattice at…

Superconductivity · Physics 2009-11-11 Tsuguhito Nakano , Kazuhiko Kuroki

The molecular mobility of glassy and supercooled liquid states of clotrimazole is studied using broadband dielectric spectroscopy for a wide range of temperatures and frequency. The dielectric loss data of clotrimazole below T$_{g}$, do not…

Soft Condensed Matter · Physics 2016-09-12 N S K Kumar , G Govindaraj , U Sailaja

The relaxation dynamics and thermodynamic properties of supercooled and glassy gambogic acid are investigated using both theory and experiment. We measure the temperature dependence of the relaxation times in three polymorphs (alpha-,…

The dynamic structure factor of glassy and liquid glycerol has been measured by inelastic X-ray scattering in the exchanged momentum ($Q$) region $Q$=2$\div$23 nm$^{-1}$ and in the temperature range 80$\div$570 K. Beside the propagating…

Disordered Systems and Neural Networks · Physics 2007-05-23 T. Scopigno , E. Pontecorvo , R. Di Leonardo , M. Krisch , G. Monaco , G. Ruocco , B. Ruzicka , F. Sette

There has been renewed interest in the frequency dependent specific heat of supercooled liquids in recent years with computer simulation studies exploring the whole frequency range of relaxation. The simulation studies can thus supplement…

Soft Condensed Matter · Physics 2009-11-10 Dwaipayan Chakrabarti , Biman Bagchi

The ac nonlinear dielectric response $\chi_3(\omega,T)$ of glycerol was measured close to its glass transition temperature $T_g$ to investigate the prediction that supercooled liquids respond in an increasingly non-linear way as the…

Soft Condensed Matter · Physics 2015-05-18 C. Crauste-Thibierge , C. Brun , F. Ladieu , D. L'Hote , G. Biroli , J-P. Bouchaud

Dielectric relaxation and thermal expansion spectroscopy were made for thin polystyrene films in order to measure the temperature $T_{\alpha}$ corresponding to the peak in the loss component of susceptibility due to the $\alpha$-process and…

Soft Condensed Matter · Physics 2007-05-23 Koji Fukao , Yoshihisa Miyamoto

Analysis of excess wings in broadband dielectric spectroscopy data of glass forming materials is found to provide evidence for anomalous time evolutions and fractional semigroups. Solutions of fractional evolution equations in frequency…

Soft Condensed Matter · Physics 2012-06-05 Simon Candelaresi , Rudolf Hilfer

We study theoretically the non-linear response properties of glass formers. We establish several general results which, together with the assumption of Time-Temperature Superposition, lead to a relation between the non-linear response and…

Statistical Mechanics · Physics 2009-12-19 Marco Tarzia , Giulio Biroli , Jean-Philippe Bouchaud , Alexandre Lefèvre

We assess the relative importance of spatial congestion and lowered temperature in the slowing dynamics of supercooled glycerol near the glass transition. We independently vary both volume, V, and temperature, T, by applying high pressure…

Soft Condensed Matter · Physics 2007-05-23 Kyaw Zin Win , Narayanan Menon

Anomalous temperature dependence of heat capacity of glassy systems during a cooling-heating cycle has remained an ill-understood problem for a long time. Most of the features observed in the experimental measurement of the heat capacity of…

Soft Condensed Matter · Physics 2007-05-23 Dwaipayan Chakrabarti , Biman Bagchi

Advances in high-precision dielectric spectroscopy has enabled access to non-linear susceptibilities of polar molecular liquids. The observed non-monotonic behavior has been claimed to provide strong support for theories of dynamic arrest…

Soft Condensed Matter · Physics 2021-07-07 Thomas Speck

Glasses are ubiquitous in daily life and technology. However the microscopic mechanisms generating this state of matter remain subject to debate: Glasses are considered either as merely hyper-viscous liquids or as resulting from a genuine…

Disordered Systems and Neural Networks · Physics 2016-06-14 S. Albert , Th. Bauer , M. Michl , G. Biroli , J. -P. Bouchaud , A. Loidl , P. Lunkenheimer , R. Tourbot , C. Wiertel-Gasquet , F. Ladieu

A significant deviation from the Debye model of rotational diffusion in the dynamics of orientational degrees of freedom in an equimolar mixture of ellipsoids of revolution and spheres is found to begin precisely at a temperature at which…

Soft Condensed Matter · Physics 2009-11-11 Dwaipayan Chakrabarti , Biman Bagchi

We present extensive molecular dynamics simulations of a liquid of symmetric dumbbells, for constant packing fraction, as a function of temperature and molecular elongation. For large elongations, translational and rotational degrees of…

Soft Condensed Matter · Physics 2009-11-11 Angel J. Moreno , Song-Ho Chong , Walter Kob , Francesco Sciortino

Temperature dependencies of excess conductivity, Sigma', have been studied in detail for three FeSe_{0.94} textured polycrystalline samples prepared by partial melting and solid state reaction. It was revealed that both Sigma' and its…

Superconductivity · Physics 2021-03-02 A. L. Solovjov , E. V. Petrenko , L. V. Omelchenko , E. Nazarova , K. Buchkov , K. Rogacki

In a recent publication by Li $\textit{et al.}$, two phases of beryllene - $\alpha$ and $\beta$ - were predicted to be single-gap superconductors with critical temperatures of 9.9 K and 12.6 K respectively. Moreover, the $\alpha$-beryllene…

Superconductivity · Physics 2024-07-29 Mikhail Petrov , Milorad V. Milosevic