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The dynamic and static critical behavior of five binary Lennard-Jones liquid mixtures, close to their continuous demixing points (belonging to the so-called model H' dynamic universality class), are studied computationally by combining…

Statistical Mechanics · Physics 2018-03-09 Sutapa Roy , S. Dietrich , Felix Höfling

We study equilibrium dynamics of a symmetrical binary Lennard-Jones fluid mixture near its consolute criticality. Molecular dynamics simulation results for shear viscosity, $\eta$, from microcanonical ensemble are compared with those from…

Statistical Mechanics · Physics 2018-03-09 Sutapa Roy , Subir K. Das

A symmetrical binary, A+B Lennard-Jones mixture is studied by a combination of semi-grandcanonical Monte Carlo (SGMC) and Molecular Dynamics (MD) methods near a liquid-liquid critical temperature $T_c$. Choosing equal chemical potentials…

Statistical Mechanics · Physics 2009-11-11 Subir K. Das , Juergen Horbach , Kurt Binder , Michael E. Fisher , Jan V. Sengers

Results for transport properties, in conjunction with phase behavior and thermodynamics, are presented at the criticality of a binary Lennard-Jones fluid from Monte Carlo and molecular dynamics simulations. Evidence for much stronger…

Statistical Mechanics · Physics 2018-04-17 Sutapa Roy , Subir K. Das

We report a Monte Carlo finite-size scaling study of the demixing transition of a symmetrical Lennard-Jones binary fluid mixture. For equal concentration of species, and for a choice of the unlike-to-like interaction ratio delta=0.7, this…

Statistical Mechanics · Physics 2009-11-10 Nigel B. Wilding

We use Monte Carlo and molecular dynamics simulations to study phase behavior and transport properties in a symmetric binary fluid where particles interact via Lennard-Jones potential. Our results for the critical behavior of collective…

Statistical Mechanics · Physics 2018-03-09 Sutapa Roy , Subir K. Das

We consider the liquid-gas phase boundary in a binary fluid mixture near its critical end point. Using general scaling arguments we show that the diameter of the liquid-gas coexistence curve exhibits singular behaviour as the critical end…

Statistical Mechanics · Physics 2016-08-31 Nigel B. Wilding

We investigate finite-size effects on diffusion in confined fluids using molecular dynamics simulations and hydrodynamic calculations. Specifically, we consider a Lennard-Jones fluid in slit pores without slip at the interface and show that…

Computational Physics · Physics 2017-03-16 Pauline Simonnin , Benoit Noetinger , Carlos Nieto-Draghi , Virginie Marry , Benjamin Rotenberg

We review and discuss recent advances in the simulation of bulk critical phenomena in model fluids. In particular we emphasise the extensions to finite-size scaling theory needed to cope with the lack of symmetry between coexisting fluid…

Statistical Mechanics · Physics 2009-10-28 N. B. Wilding

Monte Carlo simulations within the grand canonical ensemble are used to explore the liquid-vapour coexistence curve and critical point properties of the Lennard-Jones fluid. Attention is focused on the joint distribution of density and…

Condensed Matter · Physics 2009-10-28 Nigel B. Wilding

We use molecular dynamics simulations to study the behavior of a compressible Lennard-Jones fluid in simple shear flow in a two-dimensional nanochannel. The system is equilibrated in the fluid phase close to the triple point at which gas,…

Soft Condensed Matter · Physics 2017-03-31 Madhu Priya , Yitzhak Rabin

We show that, along the critical isobar, the complete scaling results in a unique leading scaling qualitatively distinct to that arising from the simple and the revised scalings. This is verified by a complete-field finite-time scaling…

Statistical Mechanics · Physics 2015-08-17 Yankui Wang , Ji Liu , Jiajie Xiao , Fan Zhong

We use simulation-based supervised machine learning and classical density functional theory to investigate bulk and interfacial phenomena associated with phase coexistence in binary mixtures. For a prototypical symmetrical Lennard-Jones…

Soft Condensed Matter · Physics 2025-10-23 Silas Robitschko , Florian Sammüller , Matthias Schmidt , Robert Evans

Using large-scale molecular dynamics simulations of a two-component Lennard-Jones model in three dimensions, we show that the late-time dynamics of spinodal decomposition in concentrated binary fluids reaches a viscous scaling regime with a…

Condensed Matter · Physics 2009-10-28 Mohamed Laradji , Soeren Toxvaerd , Ole G. Mouritsen

A Lennard--Jones model of a binary dense liquid (A,B) with a symmetrical miscibility gap is investigated by means of computer simulation methods. Semigrand--canonical Monte Carlo simulations yield the phase diagram in the $T$--$x$ plane…

Statistical Mechanics · Physics 2007-05-23 Subir K. Das , Jürgen Horbach , Kurt Binder

We have performed non-equilibrium dynamics simulations of a binary Lennard-Jones mixture in which an external force is applied on a single tagged particle. For the diffusive properties of this particle parallel to the force superdiffusive…

Statistical Mechanics · Physics 2015-06-11 Carsten F. E. Schroer , Andreas Heuer

Via a combination of molecular dynamics (MD) simulations and finite-size scaling (FSS) analysis, we study dynamic critical phenomena for the vapor-liquid transition in a three dimensional Lennard-Jones system. The phase behavior of the…

Statistical Mechanics · Physics 2017-08-18 Jiarul Midya , Subir K. Das

The phase separation of two-dimensional binary mixtures has been studied through numerical Langevin simulations based on a Ginzburg-Landau free energy. We have considered not symmetric mixtures with and without imposed shear flow. In the…

Soft Condensed Matter · Physics 2007-05-23 A. Lamura , G. Gonnella

A binary liquid near its consolute point exhibits critical fluctuations of the local composition; the diverging correlation length has always challenged simulations. The method of choice for the calculation of critical points in the phase…

Statistical Mechanics · Physics 2021-04-29 Yogyata Pathania , Dipanjan Chakraborty , Felix Höfling

We report an extensive Monte Carlo study of critical end point behaviour in a symmetrical binary fluid mixture. On the basis of general scaling arguments, singular behaviour is predicted in the diameter of the liquid-gas coexistence curve…

Statistical Mechanics · Physics 2009-10-30 Nigel B. Wilding
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