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We report the simultaneous measurement of the structural and electronic components of the metal-insulator transition of VO$_2$ using electron and photoelectron spectroscopies and microscopies. We show that these evolve over different…

Strongly Correlated Electrons · Physics 2014-11-18 J. Laverock , S. Kittiwatanakul , A. A. Zakharov , Y. R. Niu , B. Chen , S. A. Wolf , J. W. Lu , K. E. Smith

The insulator-to-metal transition (IMT) of the simple binary compound of vanadium dioxide VO$_2$ at $\sim 340$ K has been puzzling since its discovery more than five decades ago. A wide variety of photon and electron probes have been…

Strongly Correlated Electrons · Physics 2014-12-18 Brian T. O'Callahan , Joanna M. Atkin , Andrew C. Jones , Jae Hyung Park , David Cobden , Markus B. Raschke

Coupled structural and electronic phase transitions underlie the multifunctional properties of strongly-correlated materials. For example, colossal magnetoresistance1,2 in manganites involves phase transition from paramagnetic insulator to…

Strongly Correlated Electrons · Physics 2010-03-23 Joyeeta Nag , Richard Haglund , Andrew Payzant , Karren More

Brain-inspired non-Boolean computing offers intrinsic error tolerance and parallelism, but its practical deployment is limited by the lack of compact, energy-efficient spiking hardware compatible with large-scale integration. Mott…

Recently discovered class of 2D materials based on transition metal phosphorous trichalcogenides exhibit antiferromagnetic ground state, with potential applications in spintronics. Amongst them, FePS$ _{3} $ is a Mott insulator with a band…

We investigate phonon lifetimes in VO2 single crystals. We do so in the metallic state above the metal-insulator transition (MIT), where strong structural fluctuations are known to take place. By combining inelastic X-ray scattering and…

We present a theoretical investigation of the electronic structure of rutile (metallic) and M$_1$ and M$_2$ monoclinic (insulating) phases of VO$_2$ employing a fully self-consistent combination of density functional theory and embedded…

Strongly Correlated Electrons · Physics 2016-08-03 W. H. Brito , M. C. O. Aguiar , K. Haule , G. Kotliar

The high-pressure behavior of monoclinic VO$_2$ is revisited by a combination of Raman spectroscopy and X-ray diffraction on a single crystal under hydrostatic conditions at room temperature. A soft mode is observed up to P$_c$ = 13.9(1)…

Strongly Correlated Electrons · Physics 2025-01-14 P. Bouvier , L. Bussmann , D. Machon , I. Breslavetz , G. Garbarino , P. Strobel , V. Dmitriev

Electron transport properties in compacted VO2 nanopowders were studied. While VO2 usually exhibits a first-order metal-insulator transition (MIT) at ~340K, in our compressed nanopowder samples the MIT was significantly broadened due to…

Electrons in correlated insulators are prevented from conducting by Coulomb repulsion between them. When an insulator-to-metal transition is induced in a correlated insulator by doping or heating, the resulting conducting state can be…

VO2 is a strongly correlated material, which undergoes a reversible metal insulator transition (MIT) coupled to a structural phase transition upon heating (T= 67{\deg} C). Since its discovery the nature of the insulating state has long been…

Strongly Correlated Electrons · Physics 2020-01-14 A. D'Elia , S. J. Rezvani , A. Cossaro , M. Stredansky , C. Grazioli , B. W. Li , C. W. Zou , M. Coreno , A. Marcelli

We investigated the inhomogeneous electronic properties at the surface and interior of VO_{2} thin films that exhibit a strong first-order metal-insulator transition (MIT). Using the crystal structural change that accompanies a VO_{2} MIT,…

Strongly Correlated Electrons · Physics 2009-11-13 Y. J. Chang , J. S. Yang , Y. S. Kim , D. H. Kim , T. W. Noh , D. -W. Kim , E. OH , B. Kahng , J. -S. Chung

Vanadium dioxide (VO2) undergoes a phase transition at a temperature of 340 K between an insulating monoclinic M1 phase and a conducting rutile phase. Accurate measurements of possible anisotropy of the electronic properties and phonon…

Strongly Correlated Electrons · Physics 2013-07-24 T. J. Huffman , Peng Xu , M. M. Qazilbash , E. J. Walter , H. Krakauer , Jiang Wei , D. H. Cobden , H. A. Bechtel , M. C. Martin , G. L. Carr , D. N. Basov

Transition metal oxides such as vanadium dioxide (VO$_2$), niobium dioxide (NbO$_2$), and titanium sesquioxide (Ti$_2$O$_3$) are known to undergo a temperature-dependent metal-insulator transition (MIT) in conjunction with a structural…

The metal insulator transition of nano-scaled $VO_2$ devices is drastically different from the smooth transport curves generally reported. The temperature driven transition occurs through a series of resistance jumps ranging over 2 decades…

Mesoscale and Nanoscale Physics · Physics 2008-10-31 Amos Sharoni , Juan Gabriel Ramírez , Ivan K. Schuller

To explore the driving mechanisms of the metal-insulator transition (MIT) and the structural transition in VO2, we have investigated phonon dispersions of rutile VO2 (R-VO2) in the DFT and the DFT+U (U : Coulomb correlation) band…

Strongly Correlated Electrons · Physics 2013-05-09 Sooran Kim , Kyoo Kim , Chang-Jong Kang , B. I. Min

Resistive switching can be achieved in a Mott insulator by applying current/voltage, which triggers an insulator-metal transition (IMT). This phenomenon is key for understanding IMT physics and developing novel memory elements and…

Strongly Correlated Electrons · Physics 2020-07-15 Yoav Kalcheim , Alberto Camjayi , Javier del Valle , Pavel Salev , Marcelo Rozenberg , Ivan K. Schuller

We report on a metal-insulator transition (MIT) that is observed in an electron system at the SmTiO3/SrTiO3 interface. This MIT is characterized by an abrupt transition at a critical temperature, below which the resistance changes by more…

Strongly Correlated Electrons · Physics 2017-06-13 Kaveh Ahadi , Susanne Stemmera

Many strongly correlated transition metal oxides exhibit a metal-insulator transition (MIT), the manipulation of which is essential for their application as active device elements. However, such manipulation is hindered by lack of…

Strongly Correlated Electrons · Physics 2015-10-20 Tony Yamin , Yakov M. Strelniker , Amos Sharoni

A prototypical charge-transfer type Mott insulator NiS2 pyrite exhibits a metal-insulator transition with bandwidth control. Recent discoveries on surface-specific electronic states on other 3d transition-metal disulfide pyrites motivate us…

Strongly Correlated Electrons · Physics 2024-07-30 Yuuki Yasui , Kota Iwata , Shota Okazaki , Shigeki Miyasaka , Yoshiaki Sugimoto , Tetsuo Hanaguri , Hidenori Takagi , Takao Sasagawa