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A comparative simulation study of polymer brushes formed by grafting at a planar surface either flexible linear polymers (chain length $N_L$) or (non-catenated) ring polymers (chain length $N_R=2 N_L$) is presented. Two distinct off-lattice…

Soft Condensed Matter · Physics 2015-05-28 Daniel Reith , Andrey Milchev , Peter Virnau , Kurt Binder

We investigate theoretically the physics of diffusion-limited intramolecular polymer reactions. The present work completes and goes beyond a previous study [Nat. Chem. 4, 268 (2012)] that showed that the distribution of the polymer…

Statistical Mechanics · Physics 2015-06-12 T. Guérin , O. Bénichou , R. Voituriez

A mode-coupling theory for dense polymeric systems is developed which unifyingly incorporates the segmental cage effect relevant for structural slowing down and polymer chain conformational degrees of freedom. An ideal glass transition of…

Soft Condensed Matter · Physics 2009-11-07 S. -H. Chong , M. Fuchs

Superhydrophobic surfaces demonstrate promising potential for skin friction reduction in naval and hydrodynamic applications. Recent developments of superhydrophobic surfaces aiming for scalable applications use random distribution of…

Fluid Dynamics · Physics 2018-04-11 Jongmin Seo , Ali Mani

We study pore blockade times for a translocating polymer of length $N$, driven by a field $E$ across the pore in three dimensions. The polymer performs Rouse dynamics, i.e., we consider polymer dynamics in the absence of hydrodynamical…

Soft Condensed Matter · Physics 2008-02-15 Henk Vocks , Debabrata Panja , Gerard T. Barkema , Robin C. Ball

In this paper we consider in detail the connection between the problem of a polymer in a random medium and that of a quantum particle in a random potential. We are interested in a system of finite volume where the polymer is known to be…

Disordered Systems and Neural Networks · Physics 2009-10-31 Yohannes Shiferaw , Yadin Y. Goldschmidt

While the dynamics of polymer chains in equilibrium media is well understood by now, the polymer dynamics in active non-equilibrium environments can be very different. Here we study the dynamics of polymers in a viscous medium containing…

Soft Condensed Matter · Physics 2017-06-23 Jaeoh Shin , Andrey G. Cherstvy , Won Kyu Kim , Vasily Zaburdaev

We present the results of molecular dynamics computer simulations of a binary Lennard-Jones liquid confined between two parallel rough walls. These walls are realized by frozen amorphous configurations of the same liquid and therefore the…

Condensed Matter · Physics 2009-09-29 Peter Scheidler , Walter Kob , Kurt Binder

We study a model of "elastic" lattice polymer in which a fixed number of monomers $m$ is hosted by a self-avoiding walk with fluctuating length $l$. We show that the stored length density $\rho_m = 1 - <l>/m$ scales asymptotically for large…

Statistical Mechanics · Physics 2010-06-16 Marco Baiesi , Gerard T. Barkema , Enrico Carlon

Force induced stretching of polymers is important in a variety of contexts. We have used theory and simulations to describe the response of homopolymers, with $N$ monomers, to force ($f$) in good and poor solvents. In good solvents and for…

Soft Condensed Matter · Physics 2009-11-13 Greg Morrison , Changbong Hyeon , N. M. Toan , Bae-Yeun Ha , D. Thirumalai

Quantum simulators of lattice gauge theories involve dynamics of typically short-ranged interacting particles and dynamical fields. Elimination of the latter via Gauss law leads to infinite range interactions as exemplified by the Schwinger…

Disordered Systems and Neural Networks · Physics 2024-06-25 Arindam Mallick , Jakub Zakrzewski

We present a molecular dynamics study of the influence of knot complexity and molecular mass on glass formation upon cooling in knotted ring polymer melts. We find that cooperative motion, rigidity, and glassy dynamics can be tuned over a…

Soft Condensed Matter · Physics 2026-03-17 Yue-Tong Dong , Jack F. Douglas , Wen-Sheng Xu

The paper presents a short overview of the theoretical, numerical and experimental works on the critical behavior of a dilute polymer solution of long-flexible polymer chains confined in semi-infinite space restricted by a surface or in a…

Soft Condensed Matter · Physics 2018-01-08 Zoryana Usatenko , Krzysztof S. Danel

There is mounting evidence indicating that relaxation dynamics in liquids approaching their glass transition not only becomes increasingly cooperative (1,2) but the relaxing regions also become more compact in shape(3-7). While the surface…

Statistical Mechanics · Physics 2018-02-21 Divya Ganapathi , Hima K Nagamanasa , A. K. Sood , Rajesh Ganapathy

By quantitative studies of statistics of polymer stretching in a random flow and of a flow field we demonstrate that the stretching of polymer molecules in a 3D random flow occurs rather sharply via the coil-stretch transition at the value…

Chaotic Dynamics · Physics 2009-11-10 S. Gerashchenko , C. Chevallard , V. Steinberg

In this paper a lattice model for the diffusional transport of particles in the interphase cell nucleus is proposed. The dynamic behaviour of single chains on the lattice is investigated and Rouse scaling is verified. Dynamical dense…

Biological Physics · Physics 2015-05-13 Annika Wedemeier , Holger Merlitz , Chen-Xu Wu , Jörg Langowski

We present a Generalized Langevin Equation for the dynamics of interacting semiflexible polymer chains, undergoing slow cooperative dynamics. The calculated Gaussian intermolecular center-of-mass and monomer potentials, wich enter the GLE,…

Statistical Mechanics · Physics 2009-11-07 M. Guenza

The coil-globule transition has been studied for A-B copolymer chains both by means of lattice Monte Carlo simulations using bond fluctuation algorithm and by a numerical self-consistent field method. Copolymer chains of fixed length with A…

A brief review is presented of the scaling of complex fluids, polymers and polyelectrolytes in solution and in confined geometry, in thermodynamical, structural and rheology properties using equilibrium and nonequilibrium dissipative…

Soft Condensed Matter · Physics 2016-12-06 Armando Gama Goicochea

Atomistic (atom-scale) and coarse-grained (meso-scale) simulations of structure and dynamics of poly-isoprene melts are compared. The local structure and chain packing is mainly determined by the atomistic details of the polymer…

Soft Condensed Matter · Physics 2007-05-23 Roland Faller , Florian Mueller-Plathe
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