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We investigate mixing effects on the glass state of binary colloidal hard-sphere-like mixtures with large size asymmetry, at a constant volume fraction phi = 0.61. The structure, dynamics and viscoelastic response as a function of mixing…

Soft Condensed Matter · Physics 2015-06-12 Tatjana Sentjabrskaja , Donald Guu , M Paul Lettinga , Stefan U Egelhaaf , Marco Laurati

The glass transition in binary mixtures of star polymers is studied by mode coupling theory and extensive molecular dynamics computer simulations. In particular, we have explored vitrification in the parameter space of size asymmetry…

The configurational entropy is an indispensable tool to describe super-cooled liquids near the glass transition. Its calculation requires the enumeration of the basins in the potential energy landscape and when available, it reveals a…

Soft Condensed Matter · Physics 2023-08-16 Sachin C N , Ashwin Joy

Studies of low-frequency resistance noise show that the glassy freezing of the two-dimensional electron system (2DES) in Si in the vicinity of the metal-insulator transition (MIT) persists in parallel magnetic fields B of up to 9 T. At low…

Strongly Correlated Electrons · Physics 2009-11-10 J. Jaroszynski , Dragana Popovic , T. M. Klapwijk

We theoretically investigate the glass-transition problem for a quasi-two-dimensional colloidal dense suspension modulated by a one-dimensional periodic external potential as imposed by interfering laser beams. Relying on a mode-coupling…

Soft Condensed Matter · Physics 2025-09-10 Abolfazl Ahmadirahmat , Michele Caraglio , Vincent Krakoviack , Thomas Franosch

We investigate how structural relaxation in mixtures with strong dynamical asymmetry is affected by the microscopic dynamics. Brownian and Newtonian dynamics simulations of dense mixtures of fast and slow hard spheres reveal a striking…

Soft Condensed Matter · Physics 2017-10-02 Suvendu Mandal , Thomas Franosch , Thomas Voigtmann

The conventional approach to study glasses either requires considering the rapid drop in the excess entropy {\Delta}S_ex or the free volume V_f. As the two quantities are not directly related to each other, the viscosity in the two…

Statistical Mechanics · Physics 2018-02-27 P. D. Gujrati

Glassy soft matter is often continuously polydisperse, in which the sizes or various properties of the constituent particles are distributed continuously. However, most of the microscopic theories of the glass transition focus on the…

Soft Condensed Matter · Physics 2024-05-14 Hyonggi Kim , Atsushi Ikeda

The nature of polyamorphism and amorphous-to-amorphous transition is investigated by means of an exactly solvable model with quenched disorder, the spherical s+p multi-spin interaction model. The analysis is carried out in the framework of…

Disordered Systems and Neural Networks · Physics 2009-11-13 Andrea Crisanti , Luca Leuzzi

We compute the thermodynamic properties of the glass phase in a binary mixture of soft spheres. Our approach is a generalization to mixtures of the replica strategy, recently proposed by Mezard and Parisi, providing a first principle…

Condensed Matter · Physics 2009-10-31 Barbara Coluzzi , Marc Mezard , Giorgio Parisi , Paolo Verrocchio

Despite decades of work, gaining a first-principle understanding of amorphous materials remains an extremely challenging problem. However, recent theoretical breakthroughs have led to the formulation of an exact solution in the mean-field…

Disordered Systems and Neural Networks · Physics 2017-04-20 Patrick Charbonneau , Jorge Kurchan , Giorgio Parisi , Pierfrancesco Urbani , Francesco Zamponi

Truly stable metastable states are an artifact of the mean-field approximation or the zero temperature limit. If such appealing concepts in glass theory as configurational entropy are to have a meaning beyond these approximations, one needs…

Statistical Mechanics · Physics 2016-08-31 Giulio Biroli , Jorge Kurchan

Colloidal model systems allow for a flexible tuning of particle sizes, particle spacings and mutual interactions at constant temperature. Colloidal suspensions typically crystallize as soon as the interactions get sufficiently strong and…

We report on the results of a molecular dynamics simulation study of binodal glassy systems, formed in the process of isochoric rapid quenching from a high-temperature fluid phase. The transition to vitreous state occurs due to concurrent…

Soft Condensed Matter · Physics 2018-02-21 Maxim A. Makeev , Nikolai V. Priezjev

The postulate of the existence of a jamming phase diagram (Liu and Nagel, Nature 396, 21 EP (1998aa)) provides a theoretical basis for the classification of a wide range of amorphous solids (colloidal, molecular and emulsion glasses,…

Soft Condensed Matter · Physics 2020-02-04 Ruru Li , Daniel Lester

Recent studies of melting in hard disks have confirmed the existence of a hexatic phase occurring in a narrow window of density which is separated from the isotropic liquid phase by a first-order transition, and from the solid phase by a…

Statistical Mechanics · Physics 2017-09-20 John Russo , Nigel B. Wilding

We use computer simulations to study the microscopic dynamics of an athermal assembly of soft particles near the fluid-to-solid, jamming transition. Borrowing tools developed to study dynamic heterogeneity near glass transitions, we…

Materials Science · Physics 2010-06-24 Claus Heussinger , Ludovic Berthier , Jean-Louis Barrat

As a nontrivial solid state of matter, the glassy-crystal state embraces physical features of both crystalline and amorphous solids, where a long-range ordered periodic structure formed by the mass centers of constituent molecules…

The response of amorphous solids to an applied shear deformation is an important problem, both in fundamental and applied research. To tackle this problem, we focus on a system of hard spheres in infinite dimensions as a solvable model for…

Statistical Mechanics · Physics 2019-10-11 Ada Altieri , Francesco Zamponi

Spin glasses are a longstanding model for the sluggish dynamics that appears at the glass transition. However, spin glasses differ from structural glasses for a crucial feature: they enjoy a time reversal symmetry. This symmetry can be…