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Introducing an active space approximation is inevitable for the quantum computations of chemical systems. However, this approximation ignores the electron correlations related to non-active orbitals. Here, we propose a computational method…

Quantum Physics · Physics 2024-06-06 Luca Erhart , Yuichiro Yoshida , Viktor Khinevich , Wataru Mizukami

It has become increasingly feasible to use quantum Monte Carlo (QMC) methods to study correlated fermion systems for realistic Hamiltonians. We give a summary of these techniques targeted at researchers in the field of correlated electrons,…

Strongly Correlated Electrons · Physics 2016-08-24 Lucas K. Wagner , David M. Ceperley

We present an ab initio correlated approach to study molecules that interact strongly with quantum fields in an optical cavity. Quantum electrodynamics coupled cluster theory provides a non-perturbative description of cavity-induced effects…

Chemical Physics · Physics 2020-12-07 Tor S. Haugland , Enrico Ronca , Eirik F. Kjønstad , Angel Rubio , Henrik Koch

Electrodynamical coupled cluster (CC) methodologies have been formulated employing standard QED Hamiltonian that is written in Coulomb gauge while using the DF and the MCDF pictures of the matter field for closed-shell and open-shell cases…

Quantum Physics · Physics 2024-01-15 Sambhu N. Datta

We formulate a general setting for the cluster expansion method and we discuss sufficient criteria for its convergence. We apply the results to systems of classical and quantum particles with stable interactions.

Mathematical Physics · Physics 2009-05-08 Suren Poghosyan , Daniel Ueltschi

A new method that accurately describes strongly correlated states and captures dynamical correlation is presented. It is derived as a modification of coupled-cluster theory with single and double excitations (CCSD) through consideration of…

Chemical Physics · Physics 2013-07-15 Daniel Kats , Frederick R. Manby

Time-dependent response theories are foundational to the development of algorithms that determine quantum properties of electronic excited states of molecules and periodic systems. They are employed in wave-function, density-functional, and…

Chemical Physics · Physics 2022-11-23 Martín A. Mosquera

A family of quantum cluster algebras is introduced and studied. In general, these algebras are new, but subclasses have been studied previously by other authors. The algebras are indexed by double partitions or double flag varieties.…

Quantum Algebra · Mathematics 2012-10-09 Hans Plesner Jakobsen , Hechun Zhang

The cluster perturbation theory (CPT) is one of the simplest but systematic quantum cluster approaches to lattice models of strongly correlated electrons with local interactions. By treating the inter-cluster potential, in addition to the…

Strongly Correlated Electrons · Physics 2011-05-27 Matthias Balzer , Michael Potthoff

We propose a simple model for periodic clustering of particles under forced oscillation. Effective viscosity is assumed to increase owing to neighboring particles by analogy with the Einstein viscosity law. The linear stability analysis and…

Pattern Formation and Solitons · Physics 2026-02-12 Hidetsugu Sakaguchi

Nuclear systems are treated within a quantum statistical approach. Correlations and cluster formation are relevant for the properties of warm dense matter, but the description is challenging and different approximations are discussed. The…

Nuclear Theory · Physics 2017-03-21 G. Röpke

The main theoretical tools used in the physics of cluster-laser interaction are discussed starting from the basic principles of Quantum Mechanics and ending with purely classical methods. The schematic overview of the theory is complemented…

Atomic and Molecular Clusters · Physics 2016-10-31 Dragos I. Palade

When electron correlations are important it is often necessary to use numerical methods to solve the Hamiltonian for a finite system (cluster) "exactly". Unfortunately, such methods are restricted to small systems. We propose to combine the…

Strongly Correlated Electrons · Physics 2009-10-31 Maciej M. Maska

Arguably the most widely used approaches for obtaining highly accurate molecular ground-state energies are coupled cluster methods. Despite introducing two layers of approximation, a linear and a nonlinear one, coupled cluster methods…

Numerical Analysis · Mathematics 2026-05-22 Jonas Beck , Benjamin Stamm

We demonstrate that a numerical linked cluster expansion method is a powerful tool to calculate quantum dynamics. We calculate the dynamics of the magnetization and spin correlations in the two-dimensional transverse field Ising and XXZ…

Quantum Physics · Physics 2021-06-03 Ian G. White , Bhuvanesh Sundar , Kaden R. A. Hazzard

In recent years, a better understanding of the Monte Carlo method has provided us with many new techniques in different areas of statistical physics. Of particular interest are so called cluster methods, which exploit the considerable…

Statistical Mechanics · Physics 2007-05-23 Werner Krauth

We discuss a cluster-like 1D system with triplet interaction. We study the topological properties of this system. We find that the degeneracy depends on the topology of the system, and well protected against external local perturbations.…

Quantum Physics · Physics 2015-05-19 Yi-Xin Chen , Sheng-Wen Li , Zhi Yin

A simple, discrete, parametric model is proposed to describe conditional (correlated) deposition of particles on a surface and formation of a connecting (percolating) cluster. The surface changes spontaneously its properties (phase…

Statistical Mechanics · Physics 2007-05-23 Ana Proykova , Boris Karadjov

Electronic structure methods built around double-electron excitations have a rich history in quantum chemistry. However, it seems to be the case that such methods are only suitable in particular situations and are not naturally equipped to…

Chemical Physics · Physics 2024-07-12 Zachary W. Windom , Ajith Perera , Rodney J. Bartlett

We briefly summarize some recent theoretical developments in perturbative QCD, emphasizing new ideas which have led to widening the domain of applicability of perturbation theory. In particular, it is now possible to calculate efficiently…

High Energy Physics - Phenomenology · Physics 2009-10-30 Stefano Forte