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Advanced hydrogen lithography techniques and low-temperature epitaxial overgrowth enable patterning of highly phosphorus-doped silicon (Si:P) monolayers (ML) with atomic precision. This approach to device fabrication has made Si:P monolayer…

By means of ab initio molecular dynamics and band structure calculations, as well as using calculated STM images, we have singled out one structural model for the (3x2) reconstruction of the Si-terminated (001) surface of cubic SiC, amongst…

Materials Science · Physics 2009-10-31 L. Pizzagalli , A. Catellani , G. Galli , F. Gygi , A. Baratoff

Dimer vacancy (DV) defect complexes in the Si(001)2x1 surface were investigated using high-resolution scanning tunneling microscopy and first principles calculations. We find that under low bias filled-state tunneling conditions, isolated…

This paper presents a DFT study for phosphine adsorption on a Si(001)-2$\times$1 surface covered by a chlorine monolayer, including adsorption on local defects, i.e. mono- and bivacancies in the adsorbate layer (Cl, Cl$_2$), and combined…

Materials Science · Physics 2019-01-04 Tatiana V. Pavlova , Georgy M. Zhidomirov , Konstantin N. Eltsov

Phosphorus has received recent attention in the context of high-capacity and high-rate anodes for lithium and sodium-ion batteries. Here, we present a first principles structure prediction study combined with NMR calculations which gives us…

Materials Science · Physics 2015-10-13 Martin Mayo , Kent J. Griffith , Chris J. Pickard , Andrew J. Morris

Experimental observations of heteroepitaxial growth of Ge on Si(001) show a (2xn) reconstruction for sub-monolayer coverages, with dimer rows crossed by missing-dimer trenches. We present first-principles density-functional calculations…

Materials Science · Physics 2009-11-07 J. Oviedo , D. R. Bowler , M. J. Gillan

The downscaling of silicon-based structures and proto-devices has now reached the single atom scale, representing an important milestone for the development of a silicon-based quantum computer. One especially notable platform for atomic…

Spin qubits have attracted tremendous attention in the effort of building quantum computers over the years. Natural atomic scale candidates are group-V dopants in silicon, not only showing ultra-long lifetimes but also being compatible with…

Mesoscale and Nanoscale Physics · Physics 2023-09-07 Haonan Huang , Christian Schön , Christian Ast

The one-dimensional reconstruction of Au/Ge(001) was investigated by means of autocorrelation functions from surface x-ray diffraction (SXRD) and scanning tunneling microscopy (STM). Interatomic distances found in the SXRD-Patterson map are…

Strongly Correlated Electrons · Physics 2013-05-30 S. Meyer , T. Umbach , C. Blumenstein , J. Schäfer , R. Claessen , S. Sauer , S. J. Leake , P. R. Willmott , M. Fiedler , F. Bechstedt

In this paper we present a thorough first-principles based density functional theory study of the structural stability, electronic, magnetic, and optical properties of pristine and doped gallium phosphide (GaP) monolayers. The pristine GaP…

Materials Science · Physics 2023-09-26 Khushboo Dange , Rachana Yogi , Alok Shukla

The adequate interpretation of scanning tunneling microscopy (STM) images of the clean Si(001) surface is presented. We have performed both STM observations and {\it ab initio} simulations of STM images for buckled dimers on the clean…

Materials Science · Physics 2009-10-31 H. Okada , Y. Fujimoto , K. Endo , K. Hirose , Y. Mori

As progress is made on thin-film synthesis of Heusler compounds, a more complete understanding of the surface will be required to control their properties, especially as functional heterostructures are explored. Here, the surface…

The oxidation of {\alpha}-Ti(0001) surface was studied using density functional theory. In order to enhance the oxidation resistance, we substituted Ti atoms with Si atoms in Ti(0001) surface. We observe that Si prefers to segregate at the…

We present an experimental investigation of a new polymorphic 2D single layer of phosphorus on Ag(111). The atomically-resolved scanning tunneling microscopy (STM) images show a new 2D material composed of freely-floating phosphorus…

Recent experiments on the silicon terminated $3\times 2$ SiC(100) surface indicated an unexpected metallic character upon hydrogen adsorption. This effect was attributed to the bonding of hydrogen to a row of Si atoms and to the…

Materials Science · Physics 2009-11-11 R. Di Felice , C. M. Bertoni , C. A. Pignedoli , A. Catellani

The atomic and electronic structure of positively charged P vacancies on InP(110) surfaces is determined by combining scanning tunneling microscopy, photoelectron spectroscopy, and density-functional theory calculations. The vacancy…

Materials Science · Physics 2009-10-31 Ph. Ebert , K. Urban , L. Aballe , C. H. Chen , K. Horn , G. Schwarz , J. Neugebauer , M. Scheffler

The stability and electronic structure of a single monatomic Al wire has been studied using the ab initio pseudopotential method. The Al wire undergoes two structural rearrangements under compression, i.e., zigzag configurations at angles…

Materials Science · Physics 2015-06-24 Jin-Cheng Zheng , Hui-Qiong Wang , A. T. S. Wee , C. H. A. Huan

A scanning tunneling microscopy (STM) image of a hydrogen-adsorbed Si(001) surface is studied using first-principles electron-conduction calculation. The resultant STM image and scanning tunneling spectroscopy spectra are in agreement with…

Materials Science · Physics 2009-11-11 Tomoya Ono , Shinya Horie , Katsuyoshi Endo , Kikuji Hirose

By performing density functional theory-based calculations, we investigate how hydrogen atom interacts with the surfaces of monolayer PbI2 and how one and two side hydrogenation modify its structural, electronic, and magnetic properties.…

Mesoscale and Nanoscale Physics · Physics 2016-07-22 C. Bacaksiz , H. Sahin

We report differences in adsorption and reaction energetics for ethylene on Si(001) with respect to different dangling bond configurations induced by hydrogen precoverage as obtained via density functional theory calculations. This can help…

Chemical Physics · Physics 2016-12-06 Josua Pecher , Gerson Mette , Michael Dürr , Ralf Tonner