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The fluctuation-dissipation relation (FDR), a fundamental result of equilibrium statistical physics, ceases to be valid when a system is taken out of the equilibrium. A generalization of FDR has been theoretically proposed for…

Soft Condensed Matter · Physics 2015-06-29 Claudio Maggi , Roberto Di Leonardo , Jeppe C. Dyre , Giancarlo Ruocco

The response of physical systems to external perturbations can be used to probe both their equilibrium and non-equilibrium dynamics. While response and correlation functions are related in equilibrium by fluctuation-dissipation theorems,…

Statistical Mechanics · Physics 2014-04-24 Matteo Marcuzzi , Andrea Gambassi

Once the problem of ensemble averaging is removed, correlations between the response of a single molecule to an external driving field $F$, with the history of fluctuations of the particle, become detectable. Exact analytical theory for the…

Statistical Mechanics · Physics 2009-11-11 Eli Barkai

We measure the fluctuations of the position of a Brownian particle confined by an optical trap in an aging gelatin droplet after a fast quench. Its linear response to an external perturbation is also measured. We compute the spontaneous…

Statistical Mechanics · Physics 2012-03-05 Juan Ruben Gomez-Solano , Artyom Petrosyan , Sergio Ciliberto

We show that a generalized fluctuation-dissipation relation applies upon instantaneously increasing the temperature of a deeply supercooled liquid. This has the same two-step shape of the relation found upon cooling the liquid, but with…

Statistical Mechanics · Physics 2013-05-30 Nicoletta Gnan , Claudio Maggi , Giorgio Parisi , Francesco Sciortino

We report the results of molecular dynamics simulations of the protein myosin carried out with an elastic network model. Quenching the system, we observe glassy behavior of a density correlation function and a density response function that…

Statistical Mechanics · Physics 2007-07-09 Kumiko Hayashi , Mitsunori Takano

The experimental time scale dependence of thermodynamic relations in out-of-equilibrium systems with aging phenomena is investigated theoretically by using only aging properties of the two-time correlation functions and the generalized…

Disordered Systems and Neural Networks · Physics 2009-10-31 Mitsuhiro Kawasaki

We consider a simple model of a structural glass, represented by a lattice gas with kinetic constraints in contact with a particle reservoir. Quench below the glass transition is represented by the jump of the chemical potential above a…

Statistical Mechanics · Physics 2007-05-23 Luca Peliti , Mauro Sellitto

The fluctuation-dissipation relation (FDR) is measured on the dielectric properties a polymer glass (polycarbonate). It is observed that the fluctuation dissipation theorem is strongly violated for a quench from above to below the glass…

Disordered Systems and Neural Networks · Physics 2009-11-10 L. Buisson , S. Ciliberto

In glassy materials aging proceeds at large times via thermal activation. We show that this can lead to negative dynamical response functions and novel and well-defined violations of the fluctuation-dissipation theorem, in particular,…

Statistical Mechanics · Physics 2007-05-23 Peter Mayer , Sébastien Léonard , Ludovic Berthier , Juan P. Garrahan , Peter Sollich

Using molecular dynamics simulations we study the out of equilibrium dynamic correlations in a model glass-forming liquid. The system is quenched from a high temperature to a temperature below its glass transition temperature and the decay…

Statistical Mechanics · Physics 2009-10-30 Walter Kob , Jean-Louis Barrat

We study the off-equilibrium response and correlation functions and the corresponding fluctuation-dissipation ratio for a purely dissipative relaxation of an O(N) symmetric vector model (Model A) below its upper critical dimension. The…

Statistical Mechanics · Physics 2008-12-18 Pasquale Calabrese , Andrea Gambassi

We consider the dynamics of the disordered trap model, which is known to be completely out-of-equilibrium and to present strong localization effects in its aging phase. We are interested into the influence of an external force, when it is…

Condensed Matter · Physics 2009-11-10 Cecile Monthus

Fluctuations of energy and heat are investigated during the relaxation following the instantaneous temperature quench of an extended system. Results are obtained analytically for the Gaussian model and for the large $N$ model quenched below…

Statistical Mechanics · Physics 2015-06-22 M. Zannetti , F. Corberi , G. Gonnella , A. Piscitelli

We analyze the validity of the fluctuation-dissipation theorem for slow relaxation systems in the context of mesoscopic nonequilibrium thermodynamics. We demonstrate that the violation arises as a natural consequence of the elimination of…

Statistical Mechanics · Physics 2009-11-07 A. Perez-Madrid , D. Reguera , J. M. Rubi

The low-temperature generalization of the mode-coupling equations corresponds to the dynamics of mean-field disordered models in the glassy phase. The system never achieves equilibrium, preserving the memory of the time elapsed after the…

Disordered Systems and Neural Networks · Physics 2009-10-28 Leticia F. Cugliandolo , Jorge Kurchan

The orientation fluctuations of the director of a liquid crystal(LC) are measured after a quench near the Fr\'eedericksz transition, which is a second order transition driven by an electric field. We report experimental evidence that,…

Statistical Mechanics · Physics 2009-11-13 Sylvain Joubaud , Baptiste Percier , Artem Petrosyan , Sergio Ciliberto

Reaction-diffusion systems with reversible reactions generically display power-law relaxation towards chemical equilibrium. In this work we investigate through numerical simulations aging processes that characterize the non-equilibrium…

Statistical Mechanics · Physics 2011-06-10 Nasrin Afzal , Justin Waugh , Michel Pleimling

We investigate a general scenario for ``glassy'' or ``jammed'' systems driven by an external, non-conservative force, analogous to a shear force in a fluid. In this scenario, the drive results in the suppression of the usual aging process,…

Soft Condensed Matter · Physics 2009-10-31 Ludovic Berthier , Jean-Louis Barrat , Jorge Kurchan

We consider the dynamics of spin facilitated models of glasses in the non-equilibrium aging regime following a sudden quench from high to low temperatures. We briefly review known results obtained for the broad class of kinetically…

Statistical Mechanics · Physics 2009-11-13 Sebastien Leonard , Peter Mayer , Peter Sollich , Ludovic Berthier , Juan P. Garrahan