Related papers: Capillary condensation for fluids in spherical cav…
The nucleation of vapor bubbles within a superheated fluid is studied using density functional theory. The nudged elastic band technique is used to find the minimum energy pathway from the metastable uniform liquid to the stable uniform gas…
Simple analytical relations for predicting pressure-deformation relations of drops/bubbles on capillaries with elastocapillary interfaces confirmed by Surface Evolver simulations.
Density-functional theory is used to investigate the phase behavior of colloidal binary hard-platelet and hard-rod fluids near a single hard wall or confined in a slit pore. The Zwanzig model, in which the orientations of the particles of…
We investigate theoretically the stability of thermo-capillary convection within a droplet when heated by a point source from below. To model the droplet, we use a mathematical model based on lubrication theory. We formulate a base-state…
We introduce a new experimental approach to study the structural transitions of large numbers of nanoparticle-coated droplets as their volume is reduced. We use an emulsion system where the dispersed phase is slightly soluble in the…
The study of capillary wave scattering by a circular region with different interfacial properties from the rest of an otherwise homogeneous interface is motivated by experiments on wave attenuation at a monolayer covered air-water interface…
The remaining dynamical degrees of freedom of molecular fluids confined into capillaries of nano to sub-nanometer diameter are of fundamental relevance for future developments in the field of nanofluidics. These properties cannot be simply…
We employ a simple model to describe the phase behavior of 4He and Ar in a hypothetical porous material consisting of a regular array of infinitely long, solid, parallel cylinders. We find that high porosity geometries exhibit two…
Molecular dynamics simulations of miscible and partially miscible binary Lennard--Jones mixtures are used to study the dynamics and thermodynamics of vapor condensation onto a non-volatile liquid drop in the canonical ensemble. When the…
Fluid phase equilibria involving nano-dispersed phases, where at least one of the coexisting phases is confined to a small volume, are investigated by molecular dynamics simulation. Complementing previous studies on nanoscopic droplets,…
We examine the evaporation-induced coalescence of two droplets undergoing freezing by conducting numerical simulations employing the lubrication approximation. When two sessile drops undergo freezing in close vicinity over a substrate, they…
The formation and growth of ice particles, particularly on the surfaces of spherical water droplets, bear profound implications for localized weather systems and global climate. Herein, we develop a theoretical framework for ice nucleation…
A classical density functional theory is applied to study solvation of solutes in water. An approx- imate form of the excess functional is proposed for water. This functional requires the knowledge of pure solvent direct correlation…
The problem of two-phase flow in straight capillaries of polygonal cross section displays many of the dynamic characteristics of rapid interfacial motions associated with pore-scale displacements in porous media. Fluid inertia is known to…
Droplets, particularly water, are abundant in nature and artificial systems. Thermal fluctuations imply that droplet interfaces behave like a stormy sea at the sub-nanometer scale.Thermal capillary-waves have been widely studied since 1908…
Based on the capillary pore model (space-charge theory) for combined fluid and ion flow through cylindrical nanopores or nanotubes, we derive the continuum equations modified to include wall slip. We focus on the ionic conductance and…
The displacement of a suspension of particles by an immiscible fluid in a capillary tube or in a porous media is a canonical configuration that finds application in a large number of natural and industrial applications, including water…
By using the glassy (helium-)fluid model and boundary perturbation method, we can obtain the velocity fields (as well as the flow rate; up to the second order) inside the wavy-rough cylindrical nanopores which are of the same size as those…
We present a macroscopic theory of capillary condensation in slits formed by parallel walls of unequal length. Using the concept of an edge contact angle, we identify four distinct condensation states and derive Kelvin-like relations for…
Motivated by complex multi-fluid geometries currently being explored in fibre-device manufacturing, we study capillary instabilities in concentric cylindrical flows of $N$ fluids with arbitrary viscosities, thicknesses, densities, and…