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We report a high-resolution neutron diffraction study on the orbitally-degenerate spin-1/2 hexagonal antiferromagnet AgNiO2. A structural transition to a tripled unit cell with expanded and contracted NiO6 octahedra indicates root(3) x…

Strongly Correlated Electrons · Physics 2009-11-13 E. Wawrzynska , R. Coldea , E. M. Wheeler , I. I. Mazin , M. D. Johannes , T. Sorgel , M. Jansen , R. M. Ibberson , P. G. Radaelli

We report a high-resolution neutron diffraction study of the crystal and magnetic structure of the orbitally-degenerate frustrated metallic magnet AgNiO2. At high temperatures the structure is hexagonal with a single crystallographic Ni…

Strongly Correlated Electrons · Physics 2009-11-13 E. Wawrzynska , R. Coldea , E. M. Wheeler , T. Sorgel , M. Jansen , R. M. Ibberson , P. G. Radaelli , M. M. Koza

We derive a spin-orbital Hamiltonian for a triangular lattice of e_g orbital degenerate (Ni^{3+}) transition metal ions interacting via 90 degree superexchange involving (O^{2-}) anions, taking into account the on-site Coulomb interactions…

Strongly Correlated Electrons · Physics 2009-11-11 Albert J. W. Reitsma , Louis F. Feiner , Andrzej M. Oles'

Ag2MnO2 is studied as a possible candidate compound for an antiferromagnetic XY spin model on a triangular lattice. In spite of the large Curie-Weiss temperature of -430 K found in magnetic susceptibi-lity, Mn3+ spins with S = 2 do not…

Strongly Correlated Electrons · Physics 2009-11-13 Hiroyuki Yoshida , Sascha Ahlert , Martin Jansen , Yoshihiko Okamoto , Jun-Ichi Yamaura , Zenji Hiroi

Ag2CrO2 is an S=3/2 frustrated triangular lattice antiferromagnet without orbital degree of freedom. With decreasing temperature, a 4-sublatice spin state develops. However, a long-range partially disordered state with 5 sublattices…

Strongly Correlated Electrons · Physics 2012-04-13 M. Matsuda , H. Yoshida , M. Isobe , C. de la Cruz , R. S. Fishman

Motivated by the absence of cooperative Jahn-Teller effect and of magnetic ordering in LiNiO$_2$, a layered oxide with triangular planes, we study a general spin-orbital model on the triangular lattice. A mean-field approach reveals the…

Strongly Correlated Electrons · Physics 2009-11-10 F. Vernay , K. Penc , P. Fazekas , F. Mila

Dynamical properties of the lattice structure was studied by optical spectroscopy in ACr2O4 chromium spinel oxide magnetic semiconductors over a broad temperature region of T=10-335K. The systematic change of the A-site ions (A=Mn, Fe, Co,…

Strongly Correlated Electrons · Physics 2013-07-24 V. Kocsis , S. Bordács , D. Varjas , K. Penc , A. Abouelsayed , C. A. Kuntscher , K. Ohgushi , Y. Tokura , I. Kézsmárki

We report resonant X-ray scattering measurements on the orbitally-degenerate triangular metallic antiferromagnet 2H-AgNiO2 to probe the spontaneous transition to a triple-cell superstructure at temperatures below 365 K. We observe a strong…

Strongly Correlated Electrons · Physics 2015-05-19 G. L. Pascut , R. Coldea , P. G. Radaelli , A. Bombardi , G. Beutier , I. I. Mazin , M. D. Johannes , M. Jansen

We present our theoretical results on the ground states in layered triangular-lattice compounds ANiO2 (A=Na, Li, Ag). To describe the interplay between charge, spin, orbital, and lattice degrees of freedom in these materials, we study a…

Strongly Correlated Electrons · Physics 2015-05-27 Hiroshi Uchigaito , Masafumi Udagawa , Yukitoshi Motome

We report a 139La-NMR study of Ba2La2CoTe2O12, S = 1/2 equilateral triangular-lattice antiferromagnet with easy-plane anisotropy at low temperatures. This compound undergoes a magnetic phase transition at TN = 3.26 K into an ordered state…

Neutron scattering measurements on powder NaNiO2 reveal magnetic Bragg peaks and spin waves characteristic of strongly correlated s=1/2 magnetic moments arranged in ferromagnetic layers which are stacked antiferromagnetically. This…

Strongly Correlated Electrons · Physics 2009-11-10 M. J. Lewis , B. D. Gaulin , L. Filion , C. Kallin , A. J. Berlinsky , H. A. Dabkowska , Y. Qiu , J. R. D. Copley

We study polycrystalline samples of KCu3As2O7(OH)3, a new candidate spin-1/2 kagome antiferromagnet, by magnetic susceptibility and heat capacity measurements above 2 K. The unique arrangement of the 3z2 - r2 and x2 - y2 orbitals on the…

Materials Science · Physics 2015-06-04 Yoshihiko Okamoto , Hajime Ishikawa , Gøran J. Nilsen , Zenji Hiroi

We report the electronic and magnetic behaviour of the frustrated triangular metallic antiferromagnet 2H-AgNiO2 in high magnetic fields (54 T) using thermodynamic and transport measurements. Here localized d electrons are arranged on an…

We present a band structure study of orbital polarization and ordering in the two-dimensional triangular lattice transition metal compounds LiVO_2 and NaTiO_2. It is found that while in NaTiO_2 the degeneracy of t_{2g} orbitals is lifted…

Strongly Correlated Electrons · Physics 2009-10-30 S. Yu. Ezhov , V. I. Anisimov , H. F. Pen , D. I. Khomskii , G. A. Sawatzky

Resonant x-ray diffraction experiments were performed for the metallic iridium oxide IrO$_{2}$. We observed anisotropic tensor of susceptibility (ATS) scattering, the spectrum of which shows a sharp contrast between the $L_{3}$ and $L_{2}$…

Strongly Correlated Electrons · Physics 2015-06-12 Yasuyuki Hirata , Kenya Ohgushi , Jun-ichi Yamaura , Hiroyuki Ohsumi , Soshi Takeshita , Masaki Takata , Takahisa Arima

The layered delafossite compound AgNiO$_2$ with $2H$ stacking symmetry undergoes a structural metal-to-metal transition at $T_{\rm S}\sim 365$ K. It has been described in the past as a charge-ordering transition, where local $S=1$ spins are…

Strongly Correlated Electrons · Physics 2025-12-12 Jannik Gondolf , Ilya Eremin , Frank Lechermann

We report the crystal structure of Ba$_2$La$_2$CoTe$_2$O$_{12}$ determined by Rietveld analysis using X-ray powder diffraction data. It was found from magnetic measurements that Ba$_2$La$_2$CoTe$_2$O$_{12}$ can be described as a spin-1\2…

Strongly Correlated Electrons · Physics 2018-11-07 Yuki Kojima , Masari Watanabe , Nobuyuki Kurita , Hidekazu Tanaka , Akira Matsuo , Koichi Kindo , Maxim Avdeev

We successfully synthesized and characterized the triangular lattice anitferromagnet Ba$_8$MnNb$_6$O$_{24}$, which comprises equilateral spin-5/2 Mn$^{2+}$ triangular layers separated by six non-magnetic Nb$^{5+}$ layers. The detailed…

Materials Science · Physics 2019-06-03 R. Rawl , L. Ge , Z. Lu , Z. Evenson , C. R. Dela Cruz , Q. Huang , M. Lee , E. S. Choi , M. Mourigal , H. D. Zhou , J. Ma

The electronic structure and magnetism in the sodium nickelate NaNiO_2 in the low-temperature phase is studied from density-functional calculations using the linear muffin-tin orbitals method. An antiferromagnetic solution with a magnetic…

Strongly Correlated Electrons · Physics 2009-11-10 H. Meskine , S. Satpathy

We discuss the ground state properties of a spin 1/2 magnetic ion with threefold $t_{2g}$ orbital degeneracy on a highly frustrated pyrochlore lattice, like Ti$^{3+}$ ion in B-spinel MgTi$_2$O$_4$. We formulate an effective spin-orbital…

Strongly Correlated Electrons · Physics 2007-05-23 S. Di Matteo , G. Jackeli , N. B. Perkins
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