Related papers: Kovacs effect in solvable model glasses
We study colloidal particle dynamics of a model glass system using confocal and fluorescence microscopy as the sample evolves from a hard-sphere glass to a liquid with attractive interparticle interactions. The transition from hard-sphere…
In this article we study a simple, purely topological, cellular model which is allowed to evolve through a Glauber-Kawasaki process. We find a non-thermodynamic transition to a glassy phase in which the energy (defined as the square of the…
We have analyzed a non-randomly frustrated spin model which exhibits behavior remarkably similar to the phenomenology of structural glasses. The high-temperature disordered phase undergoes a strong first-order transition to a long-range…
We introduce a new toy model for the study of glasses: the hard-matrix model (HMM). This may be viewed as a single particle moving on $\mathrm{SO}(N)$, where there is a potential proportional to the 1-norm of the matrix. The ground states…
A simplified nonlinear memory function is proposed in the ideal time-convolutionless mode-coupling theory equation to study the dynamics of glass-forming liquids. The numerical solutions are then compared with the simulation results…
In this chapter, a study of the glass transitions in colloidal systems is presented, in connection with gelation, mainly from theoretical and simulation results. Mode Coupling Theory, which anticipated the existence of attraction driven…
In these lectures I will review the approach to glasses based on the replica formalism. Many of the physical ideas are very similar to those of older approaches. The replica approach has the advantage of describing in an unified setting…
The diffusion of small solvent molecules in glassy polymers may take on a variety of different forms. Fickian, anomalous, Case II, and super Case II diffusion have all been observed, and theoretical models exist that describe each specific…
We introduce and analytically study a generalized p-spin glass like model that captures some of the main features of attractive glasses, recently found by Mode Coupling investigations, such as a glass/glass transition line and dynamical…
We conduct experiments on two-dimensional packings of colloidal thermosensitive hydrogel particles whose packing fraction can be tuned above the jamming transition by varying the temperature. By measuring displacement correlations between…
Motivated by recent experimental studies probing i) the existence of a mobile layer at the free surface of glasses, and ii) the capillary leveling of polymer nanofilms, we study the evolution of square-wave patterns at the free surface of a…
While lot of measurements describe the relaxation dynamics of the liquid state, experimental data of the glass dynamics at high temperatures are much scarcer. We use ultrafast scanning calorimetry to expand the timescales of the glass to…
We formulate a microscopic, no adjustable parameter, theory of activated relaxation in supercooled liquids directly in terms of the repulsive and attractive forces within the framework of pair correlations. Under isochoric conditions,…
Advances in high-precision dielectric spectroscopy has enabled access to non-linear susceptibilities of polar molecular liquids. The observed non-monotonic behavior has been claimed to provide strong support for theories of dynamic arrest…
We examine nonequilibrium features of collapse behavior in model polymers with competing crystallization and glass transitions using extensive molecular dynamics simulations. By comparing to "colloidal" systems with no covalent bonds but…
In this paper, we review the general features of the out-of-equilibrium dynamics of spin glasses. We use this example as a guideline for a brief description of glassy dynamics in other disordered systems like structural and polymer glasses,…
Dynamics of spin-glasses subjected to slow continuous changes of working enviroment such as slow changes of temperature or interaction bonds are studied based on scaling arguments and numerical simulations of continuous bond changes. Such…
Similarities between fragile glasses and spin glasses (SG) suggest the study of frustrated spin model to understand the complex dynamics of glasses above the glass transition. We consider a frustrated spin model with Ising spins and s-state…
We propose a simple approach to investigate the structural relaxation time and glass transition of amorphous drugs. Amorphous materials are modeled as a set of equal sized hard spheres. The structural relaxation time over many decades in…
We report a molecular dynamics (MD) study of the collective dynamics of a simple monatomic liquid -interacting through a two body potential that mimics that of lithium- across the liquid-glass transition. In the glassy phase we find…