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In this communication, we represent a self-consistent systematic optimization procedure for the development of optimally tuned (OT) range-separated hybrid (RSH) functionals from \emph{first principles}. This is an offshoot of our recent…

Chemical Physics · Physics 2022-05-24 Abhisek Ghosal , Amlan K. Roy

Supervised fine-tuning (SFT) is a crucial step for adapting large language models (LLMs) to downstream tasks. However, conflicting objectives across heterogeneous SFT tasks often induce the "seesaw effect": optimizing for one task may…

Computation and Language · Computer Science 2026-01-27 Xiaoyu Liu , Xiaoyu Guan , Di Liang , Xianjie Wu

The work aims effective and low-dimensional systems. Some different contexts involving gravitational and electromagnetic interactions are investigated. The electromagnetic one approaches bosonic and fermionic Effective Quantum Field…

High Energy Physics - Theory · Physics 2022-10-10 M. G. Campos , L. P. R. Ospedal , J. A. Helayël-Neto

In this work, we present a nonlocal expansion scheme to study correlated electron systems aiming at a better description of its spatial fluctuations at all length scales. Taking the nonlocal coupling as a perturbation to the local degrees…

Strongly Correlated Electrons · Physics 2015-05-05 Gang Li

We present a derivation of a recently proposed theory for the time dependence of density fluctuations in stationary states of strongly interacting, athermal, self-propelled particles. The derivation consists of two steps. First, we start…

Soft Condensed Matter · Physics 2016-01-13 Grzegorz Szamel

The correlation entropy as a functional of radial distribution function $g(r)$ (or the total correlation function $h(r)=g(r)-1$) in classical fluids has been obtained from the second Legendre transform of the grand potential. We focus on…

Statistical Mechanics · Physics 2018-11-02 Hiroshi Frusawa

This paper considers an optimization problem for a dynamical system whose evolution depends on a collection of binary decision variables. We develop scalable approximation algorithms with provable suboptimality bounds to provide…

Optimization and Control · Mathematics 2016-10-31 Insoon Yang , Samuel A. Burden , Ram Rajagopal , S. Shankar Sastry , Claire J. Tomlin

Optimization methods have been broadly applied to two classes of objects viz. (i) modeling and description of data and (ii) the determination of the stationary points of functions. Here, a theoretical basis is developed that optimizes an…

Optimization and Control · Mathematics 2013-07-10 Christopher G. Jesudason

We propose a practicable method for describing linear dynamics of different finite Fermi systems. The method is based on a general self-consistent procedure for factorization of the two-body residual interaction. It is relevant for diverse…

Atomic and Molecular Clusters · Physics 2011-05-26 V. O. Nesterenko , J. Kvasil , P. -G. Reinhard

Difference schemes are considered for dynamical systems $ \dot x = f (x) $ with a quadratic right-hand side, which have $t$-symmetry and are reversible. Reversibility is interpreted in the sense that the Cremona transformation is performed…

Classical Analysis and ODEs · Mathematics 2024-12-03 Mikhail Malykh , Leonid Sevastianov

This article presents an overview on recent progress in the theory of nonequilibrium Green functions (NEGF). NEGF, presently, are the only \textit{ab-initio} quantum approach that is able to study the dynamics of correlations for long times…

Strongly Correlated Electrons · Physics 2019-12-20 N. Schluenzen , S. Hermanns , M. Scharnke , M. Bonitz

The strong-coupling perturbation theory (SCPT) for correlated electron systems is extended to the case of full Coulomb interaction. The Coulomb mechanism of the orbital polarization is discussed and attention is paid to the importance of…

Strongly Correlated Electrons · Physics 2007-05-23 I. Sandalov , U. Lundin , O. Eriksson

These lectures aim to provide a pedagogical introduction to the philosophical underpinnings and technical features of Effective Field Theory (EFT). Improving control of $S$-matrix elements in the presence of a large hierarchy of physical…

High Energy Physics - Phenomenology · Physics 2020-08-31 Timothy Cohen

To advance the foundation of one-particle reduced density matrix functional theory (1RDMFT) we refine and relate some of its fundamental features and underlying concepts. We define by concise means the scope of a 1RDMFT, identify its…

Quantum Physics · Physics 2023-10-10 Julia Liebert , Adam Yanis Chaou , Christian Schilling

Simulating the long-term dynamics of multi-scale and multi-physics systems poses a significant challenge in understanding complex phenomena across science and engineering. The complexity arises from the intricate interactions between scales…

Machine Learning · Computer Science 2025-09-22 Da Long , Shandian Zhe , Samuel Williams , Leonid Oliker , Zhe Bai

The dynamics of the spin-boson Hamiltonian is considered in the stochastic approximation. The Hamiltonian describes a two-level system coupled to an environment and is widely used in physics, chemistry and the theory of quantum measurement.…

Quantum Physics · Physics 2016-09-08 L. Accardi , S. V. Kozyrev , I. V. Volovich

Density functional theory (DFT) offers a desirable balance between quantitative accuracy and computational efficiency in practical many-electron calculations. Its central component, the exchange-correlation energy functional, has been…

In this paper we establish a connection between density functional theory (DFT) for lattice models and common real-space DFT. We consider the lattice DFT description of a two-level model subject to generic interactions in Mermin's DFT…

Strongly Correlated Electrons · Physics 2023-10-23 Nahual Sobrino , David Jacob , Stefan Kurth

Systems obtained by quotienting a subshift of finite type (SFT) by another SFT are called finitely presented in the literature. Analogously, if a sofic shift is quotiented by a sofic equivalence relation, we call the resulting system…

Dynamical Systems · Mathematics 2021-05-17 Johan Kopra , Ville Salo

We derive the self-energy functional theory for bosonic lattice systems with broken $U(1)$ symmetry by parametrizing the bosonic Baym-Kadanoff effective action in terms of one- and two-point self-energies. The formalism goes beyond other…

Quantum Gases · Physics 2016-11-14 Dario Hügel , Philipp Werner , Lode Pollet , Hugo U. R. Strand
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