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We study the coalescence of nanoscale metal clusters in an inert-gas atmosphere using constant-energy molecular dynamics. The coalescence proceeds via atomic diffusion with the release of surface energy raising the temperature. If the…

Condensed Matter · Physics 2007-05-23 Shaun C. Hendy , Simon A. Brown , Michael Hyslop

We report an x-ray scattering study of the microscopic structure of the surface of a liquid alkali metal. The bulk liquid structure factor of the eutectic K67Na33 alloy is characteristic of an ideal mixture, and so shares the properties of…

The premelting of ice is well known, but little is known about how the premelted and solid surfaces convert to each other. In this work, the transition dynamics between two phases are revealed with large-scale molecular dynamics…

Chemical Physics · Physics 2023-07-27 Shifan Cui , Haoxiang Chen

Supercooling of aqueous solutions below their melting point without any crystallization is a fundamentally and practically important physical phenomenon with numerous applications in biopreservation and beyond. Under normal conditions,…

Applied Physics · Physics 2018-09-05 Haishui Huang , Martin L. Yarmush , O. Berk Usta

Molecular dynamic simulations were performed for ice Ih with a free surface. The simulations were carried out at several temperatures and each run lasted more than 7ns. At high temperatures the ice melts. It is demonstrated that the melting…

Statistical Mechanics · Physics 2013-04-19 Carlos Vega , Maria Martin-Conde , Andrzej Patrykiejew

Using Kohn-Sham wave functions and their energy levels obtained by density-functional-theory total-energy calculations, the electronic structure of the two c(2x2) phases of Na on Al(001) are analysed; namely, the metastable hollow-site…

Materials Science · Physics 2009-10-31 C. Stampfl , K. Kambe , R. Fasel , P. Aebi , M. Scheffler

A superconducting transition temperature Tc as high as 100 K was recently discovered in 1 monolayer (1ML) FeSe grown on SrTiO3 (STO). The discovery immediately ignited efforts to identify the mechanism for the dramatically enhanced Tc from…

Superconductivity · Physics 2016-04-27 J. J. Seo , B. Y. Kim , B. S. Kim , J. K. Jeong , J. M. Ok , J. S. Kim , J. D. Denlinger , C. Kim , Y. K. Kim

The lack of thermal stability, originating from their metastable nature, has been one of the paramount obstacles that hinder the wide range of applications of metallic glasses. We report that the stability of a metallic glass can be…

Life on Earth depends upon the dissolution of ionic salts in water, particularly NaCl. However, an atomistic scale understanding of the process remains elusive. Simulations lend themselves conveniently to studying dissolution since they…

Chemical Physics · Physics 2022-11-09 Niamh O'Neill , Christoph Schran , Stephen J. Cox , Angelos Michaelides

Faraday surface instability measurements of the critical acceleration, a_c, and wavenumber, k_c, for standing surface waves on a tetracosanol (C_24H_50) melt exhibit abrupt changes at T_s=54degC above the bulk freezing temperature. The…

Fluid Dynamics · Physics 2009-11-11 Patrick Huber , Viktor Soprunyuk , Jan Embs , Christian Wagner , Moshe Deutsch , Satish Kumar

The hydrothermal carbonation of calcium hydroxide (Ca(OH)2) at high pressure of CO2 (initial PCO2 1/4 55 bar) and moderate to high temperature (30 and 90 1C) was used to synthesize fine particles of calcite. This method allows a high…

The well-known classical nucleation theory (CNT) for the free energy barrier towards formation of a nucleus of critical size of the new stable phase within the parent metastable phase fails to take into account the influence of other…

Statistical Mechanics · Physics 2015-06-18 Rakesh S. Singh , Biman Bagchi

Thin layers of water on biomolecular and other nanostructured surfaces can be supercooled to temperatures not accessible with bulk water. Chen et al. [PNAS 103, 9012 (2006)] suggested that anomalies near 220 K observed by quasi-elastic…

Soft Condensed Matter · Physics 2010-03-04 W. Doster , S. Busch , A. M. Gaspar , M. -S. Appavou , J. Wuttke , H. Scheer

We examine ice crystal growth from water vapor at temperatures near the melting point, when surface premelting creates a quasiliquid layer at the solid/vapor interface. Recent ice growth measurements as a function of vapor supersaturation…

Materials Science · Physics 2014-07-04 Kenneth G. Libbrecht

A phase eld approach is developed to model wetting and heterogeneous crystal nucleation of an undercooled pure liquid in contact with a sharp wall. We discuss various choices for the boundary condition at the wall and determine the…

Materials Science · Physics 2009-11-11 László Gránásy , Tamás Pusztai , David Saylor , James A. Warren

In this paper, thermal conductivity measurement of liquids and nanofluids is numerically investigated by the steady state method. In which, it is required to omit the natural convection effects on the inaccuracy of measurement for heat lost…

The thermal stability of nanocrystalline (nc) Al has been studied by means of positron lifetime spectroscopy and X-ray diffraction (XRD), prepared by compacting nanoparticles under high pressures. Those nanoparticles were produced by the…

Materials Science · Physics 2015-02-06 Xian-Bao Song , Zhu Wang , Peng-Fei Tai , Feng-Shou Tian , Liang-Liang Liu

Heterogeneous condensation of vapours mixed with a carrier gas in the stagnation point boundary layer flow near a cold wall is considered in the presence of solid particles much larger than the mean free path of vapour particles. The…

Other Condensed Matter · Physics 2009-07-22 J. C. Neu , A. Carpio , L. L. Bonilla

Pressure-melting temperature relationship is proposed and tested against the experiments of metals (Pt and Al), salt (NaCl), and ceramic (MgO) with positive results. The equation contains one open parameter which remains constant for the…

Chemical Physics · Physics 2009-06-19 Jozsef Garai , Jiuhua Chen

We describe several unexpected phenomena, caused by a solid-solid phase transition (gel-to-crystal) typical for all main classes of lipid substances - phospholipids, triglycerides, diglycerides, alkanes, etc. We discovered that this…

Materials Science · Physics 2020-08-26 Diana Cholakova , Desislava Glushkova , Slavka Tcholakova , Nikolai Denkov