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Wetting transitions have been predicted and observed to occur for various combinations of fluids and surfaces. This paper describes the origin of such transitions, for liquid films on solid surfaces, in terms of the gas-surface interaction…

Materials Science · Physics 2015-05-13 Silvina M. Gatica , Milton W. Cole

To elucidate the atomistic diffusion mechanism responsible for the rapid diffusion in alkali halide nano particles, called Spontaneous Mixing, we execute molecular dynamics simulations with empirical models for KCl-KBr, NaCl-NaBr, RbCl-RbBr…

Mesoscale and Nanoscale Physics · Physics 2016-01-11 Tomoaki Niiyama , Shin-ichi Sawada , Kensuke S. Ikeda , Yasushi Shimizu

Freezing in the vicinity of water-vapor interfaces is of considerable interest to a wide range of disciplines, most notably the atmospheric sciences. In this work, we use molecular dynamics and two advanced sampling techniques, forward flux…

Statistical Mechanics · Physics 2014-11-04 Amir Haji-Akbari , Ryan S. DeFever , Sapna Sarupria , Pablo G. Debenedetti

Surface energy is a fundamental property of materials and is particularly important in describing nanomaterials where atoms or molecules at the surface constitute a large fraction of the material. Traditionally, surface energy is considered…

Mesoscale and Nanoscale Physics · Physics 2024-04-24 Jason J. Calvin , Amanda S. Brewer , Michelle F. Crook , Tierni M. Kaufman , A. Paul Alivisatos

Graphite is a ubiquitous electrode material with particular promise for use in e.g., energy storage and desalination devices, but very little is known about the properties of the graphite-electrolyte double layer at technologically relevant…

Materials Science · Physics 2021-09-03 Aaron R. Finney , Ian J. McPherson , Patrick R. Unwin , Matteo Salvalaglio

Water-repellent properties of superhydrophobic surfaces make them promising for anti-icing and deicing applications. Through experimental visualization of frozen sessile droplets undergoing melting on superhydrophobic surfaces, we identify…

Fluid Dynamics · Physics 2026-02-10 Jiawang Cui , Yugang Zhao , Tianyou Wang , Zhizhao Che

In this study, molecular dynamic simulations are employed to investigate the nucleation of NaCl crystal in solutions. According to the simulations, the dissolved behaviors of NaCl in water are dependent on ion concentrations. With…

Chemical Physics · Physics 2018-11-29 Qiang Sun

The melting and crystallization of Al50Ni50} are studied by means of molecular dynamics computer simulations, using a potential of the embedded atom type to model the interactions between the particles. Systems in a slab geometry are…

Materials Science · Physics 2009-11-13 Ali Kerrache , Juergen Horbach , Kurt Binder

Knowledge of the vapor-liquid equilibrium (VLE) properties of molten salts is important in the design of thermal energy storage systems for solar power and nuclear energy production applications. The high temperatures involved make their…

Statistical Mechanics · Physics 2024-06-19 Leann Tran , Jiri Skvara , William R. Smith

The origin of ice slipperiness has been a matter of great controversy for more than a century, but an atomistic understanding of ice friction is still lacking. Here, we perform computer simulations of an atomically smooth substrate sliding…

Applied Physics · Physics 2024-02-08 Lukasz Baran , Pablo Llombart , Wojciech Rzysko , Luis G. MacDowell

Sharp nanoscale tips on metal surfaces of electrodes enhance locally applied electric fields. Strongly enhanced electric fields trigger electron field emission and atom evaporation from the apexes of the nanotips. Combined together, these…

Materials Science · Physics 2016-05-24 Ville Jansson , Ekaterina Baibuz , Flyura Djurabekova

A few experiments have already detected the presence of icosahedral superclusters in undercooled liquids, confirming a possible homogeneous nucleation of such entities as suggested by Franck. These superclusters survive in melts above the…

Materials Science · Physics 2014-07-29 Robert Felix Tournier

We characterise the structural properties of the quasi-liquid layer (QLL) at two low-index ice surfaces in the presence of sodium chloride (Na$^+/$Cl$^-$) ions by molecular dynamics simulations. We find that the presence of a high surface…

Chemical Physics · Physics 2022-09-28 Margaret L. Berrens , Fernanda C. Bononi , Davide Donadio

A heat exchange interface at subzero temperature in a water vapor environment, exhibits high probability of frost formation due to freezing condensation, a factor that markedly decreases the heat transfer efficacy due to the considerable…

Soft Condensed Matter · Physics 2017-03-23 Christos Stamatopoulos , Jaroslav Hemrle , Danhong Wang , Dimos Poulikakos

As a model for a suspension of hard-sphere like colloidal particles where small nonadsorbing dissolved polymers create a depletion attraction, we introduce an effective colloid-colloid potential closely related to the Asakura-Oosawa model…

Soft Condensed Matter · Physics 2015-10-28 Antonia Statt , Peter Virnau , Kurt Binder

X-ray measurements reveal a crystalline monolayer at the surface of the eutectic liquid Au_{82}Si_{18}, at temperatures above the alloy's melting point. Surface-induced atomic layering, the hallmark of liquid metals, is also found below the…

Quantum Monte Carlo simulations at zero temperature of an ensemble of He-3 atoms adsorbed on Mg and Alkali substrates yield strong evidence of a thermodynamically stable liquid He-3 monolayer on all Alkali substrates, with the possible…

Other Condensed Matter · Physics 2013-07-26 Michele Ruggeri , Saverio Moroni , Massimo Boninsegni

X-ray diffraction and Raman scattering measurements, and first-principles calculations are performed to search for the formation of NaCl-hydrogen compound. When NaCl and H$_{2}$ mixture is laser-heated to above 1500 K at pressures exceeding…

The influence of the external pressure and surface energy on the wetting transition at nanotextured interfaces is studied using molecular dynamics and continuum simulations. The surface roughness of the composite interface is introduced via…

Soft Condensed Matter · Physics 2018-07-12 Bishal Bhattarai , Nikolai V. Priezjev

Surfaces are able to control physical-chemical processes in multi-component solution systems and, as such, find application in a wide range of technological devices. Understanding the structure, dynamics and thermodynamics of non-ideal…

Soft Condensed Matter · Physics 2023-09-29 Aaron R. Finney , Matteo Salvalaglio