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In this chapter, a study of the glass transitions in colloidal systems is presented, in connection with gelation, mainly from theoretical and simulation results. Mode Coupling Theory, which anticipated the existence of attraction driven…

Soft Condensed Matter · Physics 2008-10-06 Antonio M. Puertas , Matthias Fuchs

A first principles approach to the nonlinear flow of dense suspensions is presented which captures shear thinning of colloidal fluids and dynamical yielding of colloidal glasses. The advection of density fluctuations plays a central role,…

Soft Condensed Matter · Physics 2009-11-07 Matthias Fuchs , Michael E. Cates

Dense assemblies of self-propelled particles undergo a nonequilibrium form of glassy dynamics. Physical intuition suggests that increasing departure from equilibrium due to active forces fluidifies a glassy system. We falsify this belief by…

Soft Condensed Matter · Physics 2017-12-08 Ludovic Berthier , Elijah Flenner , Grzegorz Szamel

Extending mode-coupling theory, we elaborate a microscopic theory for the glass transition of liquids confined between two parallel flat hard walls. The theory contains the standard MCT equations in bulk and in two dimensions as limiting…

Soft Condensed Matter · Physics 2010-09-15 Simon Lang , Vitalie Botan , Martin Oettel , David Hajnal , Thomas Franosch , Rolf Schilling

Cell migration is important in many biological processes, including embryonic development, cancer metastasis, and wound healing. In these tissues, a cell's motion is often strongly constrained by its neighbors, leading to glassy dynamics.…

Biological Physics · Physics 2016-01-20 Dapeng Bi , J. H. Lopez , J. M. Schwarz , M. Lisa Manning

We discuss the dynamic behavior of a tagged particle close to a classical localization transition in the framework of the mode-coupling theory of the glass transition. Asymptotic results are derived for the order parameter as well as the…

Disordered Systems and Neural Networks · Physics 2011-08-11 S. K. Schnyder , F. Höfling , T. Franosch , Th. Voigtmann

A simplified nonlinear memory function is proposed in the ideal time-convolutionless mode-coupling theory equation to study the dynamics of glass-forming liquids. The numerical solutions are then compared with the simulation results…

Statistical Mechanics · Physics 2020-01-22 Michio Tokuyama

Within the mode-coupling theory for ideal glass-transitions, the mean-squared displacement and the correlation function for density fluctuations are evaluated for a colloidal liquid of particles interacting with a square-well potential for…

Soft Condensed Matter · Physics 2007-05-23 M. Sperl

The interplay of slow dynamics and thermodynamic features of dense liquids is studied by examinining how the glass transition changes depending on the presence or absence of Lennard-Jones-like attractions. Quite different thermodynamic…

Materials Science · Physics 2009-11-13 Th. Voigtmann

For almost thirty years, mode-coupling theory has been the most widely discussed and used but also the most controversial theory of the glass transition. In this paper we briefly review the reasons for both its popularity and its…

Statistical Mechanics · Physics 2016-06-21 Grzegorz Szamel

Understanding the physics of glass formation remains one of the major unsolved challenges of condensed matter science. As a material solidifies into a glass, it exhibits a spectacular slowdown of the dynamics upon cooling or compression,…

Statistical Mechanics · Physics 2018-10-03 Liesbeth M. C. Janssen

We investigate the dynamics of a driven system of dissipative hard spheres in the framework of mode-coupling theory. The dissipation is modeled by normal restitution, and driving is applied to individual particles in the bulk. In such a…

Soft Condensed Matter · Physics 2010-06-29 W. Till Kranz , Matthias Sperl , Annette Zippelius

We consider the stationary state of a fluid comprised of inelastic hard spheres or disks under the influence of a random, momentum-conserving external force. Starting from the microscopic description of the dynamics, we derive a nonlinear…

Statistical Mechanics · Physics 2013-02-25 W. T. Kranz , M. Sperl , A. Zippelius

We theoretically investigate the glass-transition problem for a quasi-two-dimensional colloidal dense suspension modulated by a one-dimensional periodic external potential as imposed by interfering laser beams. Relying on a mode-coupling…

Soft Condensed Matter · Physics 2025-09-10 Abolfazl Ahmadirahmat , Michele Caraglio , Vincent Krakoviack , Thomas Franosch

Molecular fluids show rich and complicated dynamics close to the glass transition. Some of these observations are related to the fact that translational and orientational degrees of freedom couple in nontrivial ways. A model system which…

Soft Condensed Matter · Physics 2017-08-23 M. Letz , R. Schilling

The mode-coupling theory (MCT) of the glass transition ranks among the most successful first-principles kinetic theories to describe glassy dynamics. However, MCT does not fully account for crucial aspects of the dynamics near the glass…

Soft Condensed Matter · Physics 2024-08-22 Ilian Pihlajamaa , Liesbeth M. C. Janssen

Idealized glass transitions are discussed within a novel mode-coupling theory (TMCT) proposed by Tokuyama(Physica A 395,31(2014)). This is done in order to identify common grounds with and differences to the conventional mode-coupling…

Statistical Mechanics · Physics 2015-04-23 Wolfgang Götze , Rolf Schilling

We investigate the properties of a class of mode-coupling equations for the glass transition where the density mode decays into multiple relaxation channels. We prove the existence and uniqueness of the solutions for Newtonian as well as…

Soft Condensed Matter · Physics 2014-01-08 Simon Lang , Rolf Schilling , Thomas Franosch

We consider the Mode Coupling Theory (MCT) of Glass transition for a Binary fluid. The Equations of Nonlinear Fluctuating Hydrodynamics are obtained with a proper choice of the slow variables corresponding to the conservation laws. The…

Statistical Mechanics · Physics 2009-11-07 Upendra Harbola , Shankar P. Das

Building on the recently derived inhomogeneous mode-coupling theory, we extend the generalised mode-coupling theory of supercooled liquids to inhomogeneous environments. This provides a first-principles-based, systematic and rigorous way of…

Statistical Mechanics · Physics 2023-01-11 Corentin C. L. Laudicina , Chengjie Luo , Kunimasa Miyazaki , Liesbeth M. C. Janssen