Related papers: Valence and magnetic ordering in intermediate vale…
We report on the study of the response to high pressures of the electronic and magnetic properties of several Sm-based compounds, which span at ambient pressure the whole range of stable charge states between the divalent and the trivalent.…
We report a systematic study of Sm valence in the prototypical intermediate valence compound SmB$_6$. Sm mean valence, $v_{\rm Sm}$, was measured by X-ray absorption spectroscopy as functions of pressure ($1<P<13$ GPa) and temperature…
Neutron diffraction experiments on TmTe at pressures up to 7 GPa are reported. The semiconductor-to-metal transition occurring at 2 GPa in this compound is accompanied by the appearance of strong ferromagnetic exchange interactions…
We present results of magnetic susceptibility and thermal expansion measurements performed on high-quality single crystals of EuPd$_2$(Si$_{1-x}$Ge$_x$)$_2$ for 0 $\leq$ x $\leq$ 0.2 and temperatures 2 K $\leq T \leq$ 300 K. Data were taken…
We present results of the magnetic susceptibility on high-quality single crystals of EuPd$_2$(Si$_{1-x}$Ge$_x$)$_2$ for Ge concentrations 0 $\leq x \leq$ 0.105 performed under varying hydrostatic (He-gas) pressure 0 $\leq p \leq$ 0.5 GPa.…
The pressure-temperature phase diagram of an intermediate-valence compound YbPd was revealed via simultaneous ac-calorimetry and electrical resistivity measurements. Two successive structural phase transition temperatures, $T_1$ = 125 K and…
Resonant x-ray emission spectroscopy (RXES) was used to determine the pressure dependence of the f-electron occupancy in the Kondo insulator SmB6. Applied pressure reduces the f-occupancy, but surprisingly, the material maintains a…
SmB6 is a mixed-valence compound with flat f-electron bands that have a propensity to magnetism. Here, using a realistic Gamma8 quartet model, we investigate the dynamical spin susceptibility and describe the in-gap collective mode observed…
We present the magnetic and transport behavior of some Tb compounds, viz., TbIrGe2, TbFe(0.4)Ge2, and TbCo(0.4)Ge2. The stoichoometric germanide TbIrGe2 exhibits at least two distinct magnetic transitions in a close temperature interval…
The crystal structure, magnetic ordering, and electrical resistivity of TlFe1.6Se2 were studied at high pressures. Below ~7 GPa, TlFe1.6Se2 is an antiferromagnetically ordered semiconductor with a ThCr2Si2-type structure. The…
The infrared optical conductivity of intermediate valence compound TmSe reveals clear signatures for hybridization of light $d$- and heavy f-electronic states with m* ~ 1.6 m_0 and m* ~ 16 m_0, respectively. At moderate and high…
Intermediate-valence behavior is sometimes observed in lanthanide-based materials containing Ce, Yb, Sm or Eu. However, the number of actinide-based systems that exhibit this type of behavior is rather limited. In this work, we present the…
We present a comprehensive investigation of the electronic structure, magnetization, specific heat, and crystallography of TbSi (FeB structure type) and TbSi$_{0.6}$Ge$_{0.4}$ (CrB structure type) compounds. Both TbSi and…
We present a comprehensive study of the mixed valent compound, EuPd3S4, by electrical transport, X-ray diffraction, time-domain 151Eu synchrotron M\"ossbauer spectroscopy, and X-ray absorption spectroscopy measurements under high pressure.…
Magnetocaloric effect in Mn4FeGe3-xSix compounds has been studied by dc magnetization measurements. For the parent compound Mn4FeGe3, the paramagnetic to ferromagnetic transition temperature TC is above room temperature (320 K), which…
UTe$_2$ is a recently discovered unconventional superconductor that has attracted much interest due to its many intriguing properties - a large residual density-of-states in the superconducting state, re-entrant superconductivity in high…
SmS, a prototypical intermediate valence compound, has been studied by performing high-pressure nuclear magnetic resonance measurements on a $^{33}$S-enriched sample. The observation of an additional signal below 15-20 K above a…
The dependence of the magnetic ordering temperature To of Sm metal was determined through four-point electrical resistivity measurements to pressures as high as 150 GPa. A strong increase in To with pressure is observed above 85 GPa. In…
Given the parallelism between the physical properties of Ce and Yb based magnets and heavy fermions due to the electron-hole symmetry, it has been rather odd that the transition temperature of the Yb based compounds is normally very small,…
The crystallographic, magnetic and thermal properties of BiMn2PO6 and BiZn2PO6 were investigated by x-ray diffraction, magnetic susceptibility \chi, heat capacity Cp, and 31P NMR measurements as well as by density-functional band-theory…