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A series of solid organic acids were used to p-dope carbon nanotubes. The extent of doping is shown to be dependent on the pKa value of the acids. Highly fluorinated carboxylic acids and sulfonic acids are very effective in shifting the…

Materials Science · Physics 2015-07-20 Christian Klinke , Ali Afzali , Phaedon Avouris

Recently, it was suggested that the polarization dependence of light absorption to a single-walled carbon nanotube is altered by carrier doping. We specify theoretically the doping level at which the polarization anisotropy is reversed by…

Mesoscale and Nanoscale Physics · Physics 2018-03-29 Ken-ichi Sasaki , Yasuhiro Tokura

Choosing a suitable doping level of channel relevant to channel diameter is considered for determining the carbon nanotube field effect transistors' performance which seem to be the best substitute of current transistor technology. For low…

Mesoscale and Nanoscale Physics · Physics 2012-07-10 Shaahin G. Shirazi , Sattar Mirzakuchaki

We describe a robust technique for the fabrication of high performance vertically scaled n-doped field-effect transistors from large band gap carbon nanotubes. These devices have a tunable threshold voltage in the technologically relevant…

Materials Science · Physics 2009-11-10 M. Radosavljevic , J. Appenzeller , Ph. Avouris , J. Knoch

We probed the charge transfer interaction between the amine-containing molecules: hydrazine, polyaniline and aminobutyl phosphonic acid, and carbon nanotube field effect transistors (CNTFETs). We successfully converted p-type CNTFETs to…

Materials Science · Physics 2015-07-20 Christian Klinke , Jia Chen , Ali Afzali , Phaedon Avouris

High performance enhancement mode semiconducting carbon nanotube field-effect transistors (CNTFETs) are obtained by combining ohmic metal-tube contacts, high dielectric constant HfO2 films as gate insulators, and electrostatically doped…

Mesoscale and Nanoscale Physics · Physics 2015-06-24 Ali Javey , Jing Guo , Damon B. Farmer , Qian Wang , Dunwei Wang , Roy G. Gordon , Mark Lundstrom , Hongjie Dai

State-of-the-art carbon nanotube field-effect transistors (CNFETs) behave as Schottky barrier (SB)-modulated transistors. It is known that vertical scaling of the gate oxide significantly improves the performance of these devices. However,…

Materials Science · Physics 2007-12-18 Yu-Ming Lin , Joerg Appenzeller , Joachim Knoch , Phaedon Avouris

With decreasing device dimensions, the performance of carbon nanotube field-effect transistors (CNFETs) is limited by high Off currents except at low drain voltages. We show that an asymmetric design improves the performance, reducing Off…

Condensed Matter · Physics 2009-11-10 S. Heinze , J. Tersoff , Ph. Avouris

Semiconducting single-walled carbon nanotubes (SWCNTs) are a promising thermoelectric material with high power factors after chemical p- or n-doping. Understanding the impact of dopant counterions on charge transport and thermoelectric…

Two-dimensional (2D) semiconductors are likely to dominate next-generation electronics due to their advantages in compactness and low power consumption. However, challenges such as high contact resistance and inefficient doping hinder their…

Materials Science · Physics 2024-10-11 Raagya Arora , Ariel R. Barr , Daniel T. Larson , Michele Pizzochero , Efthimios Kaxiras

A mechanically bistable single-walled carbon nanotube can act as a variable-shaped capacitor with a voltage-controlled transition between collapsed and inflated states. This external control parameter provides a means to tune the system so…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Oleg E. Shklyaev , Eric Mockensturm , Vincent H. Crespi

The charge transport properties of individual, metallic nitrogen doped, single-walled carbon nanotubes are investigated. It is demonstrated that n-type conduction can be achieved by nitrogen doping. Evidence was obtained by appealing to…

Materials Science · Physics 2009-11-11 V. Krstic , G. L. J. A. Rikken , P. Bernier , S. Roth , M. Glerup

Carbon nanotubes are one-dimensional and very narrow. These obvious facts imply that under doping with boron and nitrogen, microscopic doping inhomogeneity is much more important than for bulk semiconductors. We consider the possibility of…

Materials Science · Physics 2009-11-07 Paul E. Lammert , Vincent H. Crespi , Angel Rubio

A first-principles investigation of the electronic and quantum transport properties of double-walled carbon nanotubes doped with nitrogen and boron atoms is presented. Concentric nanotube sidewalls separated by the typical graphitic van der…

Materials Science · Physics 2016-03-24 Alejandro Lopez-Bezanilla

The attachment of semiconducting nanoparticles to carbon nanotubes is one of the most challenging subjects in nanotechnology. Successful high coverage attachment and control over the charge transfer mechanism and photo-current generation…

Materials Science · Physics 2015-07-20 Alina Chanaewa , Beatriz H. Juarez , Horst Weller , Christian Klinke

High electric conductivity ~100 MegaSiemens/m and Seebeck coefficient >200 mkV/K of carbon nanotubes (CNT) make them attractive for a variety of applications. Unfortunately, a high thermal conductivity ~ 3000 W/(m*K) due to the phonon…

Mesoscale and Nanoscale Physics · Physics 2016-11-10 T. Gupta , I. P. Nevirkovets , V. Chandrasekhar , S. Shafranjuk

Efficient and controlled charge transport in networks of semiconducting single-walled carbon nanotubes is the basis for their application in electronic devices, especially in field-effect transistors and thermoelectrics. The recent advances…

Applied Physics · Physics 2021-11-19 Nicolas F. Zorn , Jana Zaumseil

Doping of semiconductors is essential in modern electronic and photonic devices. While doping is well understood in bulk semiconductors, the advent of carbon nanotubes and nanowires for nanoelectronic and nanophotonic applications raises…

Materials Science · Physics 2015-05-18 Catalin D. Spataru , François Léonard

We demonstrate an optically active nanotube-hybrid material by functionalizing single-wall nanotubes with an azo-based chromophore. Upon UV illumination, the conjugated chromophore undergoes a cis-trans isomerization leading to a charge…

Materials Science · Physics 2009-11-13 J. M. Simmons , I. In , V. E. Campbell , T. J. Mark , F. Leonard , P. Gopalan , M. A. Eriksson

Tweaking the properties of carbon nanotubes is a prerequisite for their practical applications. Here we demonstrate fine-tuning the electronic properties of single-wall carbon nanotubes via filling with ferrocene molecules. The evolution of…

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