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We present a systematic theoretical investigation of the surface properties, stability and reactivity, of rock-salt type alkaline-earth metal oxides including MgO, CaO, SrO, and BaO. The accuracy of commonly used exchange-correlation…

Materials Science · Physics 2015-06-23 Michal Bajdich , Jens K. Nørskov , Aleksandra Vojvodic

The newly observed ($\sqrt3$$\times$$\sqrt3$) surface reconstruction in heteroepitaxial Si(111) thin films on metal substrates is widely considered as a promising platform to realize 2D Dirac and topological states, yet its formation…

Materials Science · Physics 2017-06-21 Wei Jiang , Zheng Liu , Miao Zhou , Xiaojuan Ni , Feng Liu

We have carried out first-principles total-energy calculations of (001) surfaces of the tetragonal and cubic phases of BaTiO3. Both BaO-terminated (type I) and TiO2-terminated (type II) surfaces are considered, and the atomic configurations…

Materials Science · Physics 2009-10-30 J. Padilla , David Vanderbilt

We describe a recently discovered stable planar surface of silicon, Si(114). This high-index surface, oriented 19.5 degrees away from (001) toward (111), undergoes a 2x1 reconstruction. We propose a complete model for the reconstructed…

mtrl-th · Physics 2009-10-30 Steven C. Erwin , Alison A. Baski , Lloyd J. Whitman

Surfaces are at the frontier of every known solid. They provide versatile supports for functional nanostructures and mediate essential physicochemical processes. Being intimately related with 2D materials, interfaces and atomically thin…

We present first-principles total-energy calculations of (001) surfaces of SrTiO3. Both SrO-terminated and TiO2-terminated surfaces are considered, and the results are compared with previous calculations for BaTiO3 surfaces. The major…

Materials Science · Physics 2009-10-31 J. Padilla , David Vanderbilt

Co3Si was recently reported to exhibit remarkable magnetic properties in the nanoparticle form [Appl. Phys. Lett. 108, 152406 (2016)], yet better understanding of this material is to be promoted. Here we report a study on the crystal…

Materials Science · Physics 2017-07-18 Xin Zhao , Shu Yu , Shunqing Wu , Manh Cuong Nguyen , Cai-Zhuang Wang , Kai-Ming Ho

The stability and electronic structure of competing silicene phases under in-plane compressive stress, either free-standing or on the ZrB$_2$(0001) surface, has been studied by first-principles calculations. A particular…

Materials Science · Physics 2013-10-10 Chi-Cheng Lee , Antoine Fleurence , Rainer Friedlein , Yukiko Yamada-Takamura , Taisuke Ozaki

While performing molecular dynamics simulations of a simple monatomic liquid, we observed the crystallization of a material displaying octagonal symmetry in its simulated diffraction pattern. Inspection of the atomic arrangements in the…

A first-principles atomic orbital-based electronic structure method is used to investigate the low index surfaces of rutile Titanium Dioxide. The method is relatively cheap in computational terms, making it attractive for the study of oxide…

Materials Science · Physics 2009-10-28 O. Gulseren , R. James , D. W. Bullett

Molecular dynamics simulations of the liquid-vapour interfaces in simple sp-bonded liquid metals have been performed using first principles methods. Results are presented for liquid Li, Na, K, Rb, Cs, Mg, Ba, Al, Tl, and Si at thermodynamic…

Disordered Systems and Neural Networks · Physics 2009-11-11 David J. Gonzalez Luis E. Gonzalez , Malcolm J. Stott

Recent discoveries of supposedly pure alpha-tetragonal boron require to revisit its structure. The system is also interesting with respect to a new type of geometrical frustration in elemental crystals, which was found in beta-rhombohedral…

Materials Science · Physics 2016-03-23 Naoki Uemura , Koun Shirai , Hagen Eckert , Jens Kunstmann

We propose the atomic structures of the 4H-SiC/SiO$_2$ interface for the $a$, $m$, C, and Si faces after NO annealing. Our proposed structures preferentially form at the topmost layers of the SiC side of the interface, which agrees with the…

Materials Science · Physics 2024-01-09 Naoki Komatsu , Mizuho Ohmoto , Mitsuharu Uemoto , Tomoya Ono

Rearrangement of atoms due to broken translational symmetries at the surface of SrTiO$_3$ is scarcely debatable in the present day scenario. Actual concern demands to unveil the true structure and precise mechanism responsible for atomic…

Materials Science · Physics 2018-11-08 Adeel Y Abid , Ning Li , Ayaz Arif , Peng Gao

The morphology evolution of Si (100) surfaces under 1200 eV Ar+ ion bombardment at normal incidence with and without metal incorporation is presented. The formation of nanodot patterns is observed only when the stationary Fe concentration…

Materials Science · Physics 2015-05-18 Jing Zhou , Stefan Facsko , Ming Lu , Wolfhard Moeller

The finite size and interface effects on equilibrium crystal shape (ECS) have been investigated for the case of a surface free energy density including step stiffness and inverse-square step-step interactions. Explicitly including the…

Materials Science · Physics 2009-11-11 M. Degawa , F. Szalma , E. D. Williams

The structure and dynamical properties of the Fe$_3$Si/GaAs(001) interface are investigated by density functional theory and nuclear inelastic scattering measurements. The stability of four different atomic configurations of the…

We have carried out an ab-initio study of $\alpha$-Sn (111), with the aim of predicting and understanding its structure, reconstructions, and electronic states. We consider a variety of structural possibilities, and optimize them by moving…

Condensed Matter · Physics 2009-10-28 Zhong-Yi Lu , Guido L. Chiarotti , S. Scandolo , E. Tosatti

The electronic structure of monolayer hexagonal boron nitride grown on Ni by the diffusion and precipitation method was studied by x-ray absorption spectroscopy, emission spectroscopy, x-ray photoelectron spectroscopy and micro-ultraviolet…

The tensile strained Si(111) layers grown on top of Ge(111) substrates are studied by combining scanning tunneling microscopy, low energy electron diffraction and first-principles calculations. It is shown that the layers exhibit c(2x4)…

Materials Science · Physics 2017-09-04 R. Zhachuk , J. Coutinho , A. Dolbak , V. Cherepanov , B. Voigtländer