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We have developed a formulation of density functional perturbation theory for the calculation of vibrational frequencies in molecules and solids, which uses numerical atomic orbitals as a basis set for the electronic states. The (harmonic)…

Materials Science · Physics 2007-05-23 J. M. Pruneda , S. K. Estreicher , J. Junquera , J. Ferrer , P. Ordejon

Intense light with frequencies above typical atomic or molecular ionization potentials as provided by free-electron lasers couples many photons into extended targets such as clusters and biomolecules. This implies, in contrast to…

Atomic and Molecular Clusters · Physics 2011-05-25 Christian Gnodtke , Ulf Saalmann , Jan-Michael Rost

The well-known effects of the spin-orbit interaction of light are manifestations of pair mutual influence of the three types of the angular momentum of light, namely, the spin angular momentum, the extrinsic orbital angular momentum and the…

Optics · Physics 2016-08-24 Sarkew Abdulkareem , Nataliya Kundikova

The preferentially (220) orientated polycrystalline silicon films have been fabricated by performing photon-involved rapid thermal annealing upon amorphous silicon films. In contrast, conventional thermal annealing of the silicon amorphous…

Materials Science · Physics 2017-01-16 NuoFu Chen , Quanli Tao , Yiming Bai , Shaolin Ruan , Jikun Chen

The ionization of an atom by a high-frequency intense laser pulse, where the energy of a single-photon is sufficient to ionize the system, is investigated from first principles. It is shown that as a consequence of an AC Stark effect in the…

Atomic Physics · Physics 2012-06-26 Philipp V Demekhin , Lorenz S Cederbaum

We have investigated the response of amorphous silicon (a-Si), in particular crystallization, to external mechanical shear deformations using classical molecular dynamics (MD) simulations and the empirical Environment Dependent Inter-atomic…

Materials Science · Physics 2015-05-28 Ali Kerrache , Normand Mousseau , Laurent J. Lewis

The dynamics of the electron impact multiphoton ionization of a hydrogen atom in the presence of an intense laser field has been studied theoretically, with a view to comparing (qualitatively) the results with the recent kinematically…

Atomic Physics · Physics 2008-02-11 S. Ghosh Deb , S. Roy , C. Sinha

We investigate the influence of hydrogen on the electronic structure of a binary transition metallic glass of V$_{80}$Zr$_{20}$. We examine the hybridization between the hydrogen and metal atoms with the aid of hard x-ray photoelectron…

Materials Science · Physics 2024-03-21 Johan Bylin , Rebecka Lindblad , Lennart Spode , Ralph H. Scheicher , Gunnar K. Pálsson

Light-induced nonadiabatic effects can arise from the interaction of a molecule with the quantized electromagnetic field of a Fabry--P\'erot or plasmonic nanocavity. In this context, the quantized radiation field mixes the vibrational,…

Atomic and Molecular Clusters · Physics 2025-03-17 Krisztián Szabó , Csaba Fábri , Gábor J. Halász , Ágnes Vibók

The kinetics of E' centers induced in silica by 4.7eV laser irradiation was investigated observing in situ their optical absorption band at 5.8 eV. After exposure the defects decay due to reaction with diffusing molecular hydrogen of…

Materials Science · Physics 2009-11-10 F. Messina , M. Cannas

Transition metal complexes for photochemical applications often feature a high density of electron-vibrational states characterized by nonadiabatic and spin-orbit couplings. Overall, the dynamics after photoexcitation is shaped by rapid…

Chemical Physics · Physics 2023-05-16 Olga Bokareva , Oliver Kühn

We construct an effective Hamiltonian of interacting bosons, based on scattered radiation off vibrational modes of designed molecular architectures. Making use of the infinite yet countable set of spatial modes representing the scattering…

Quantum Physics · Physics 2019-12-30 Shahaf Asban , Shaul Mukamel

The molecular dynamics method is applied to simulate the recrystallization of an amorphous/crystalline silicon interface. The atomic structure of the amorphous material is constructed with the method of Wooten, Winer, and Weaire. The…

Computational Physics · Physics 2011-07-07 Christophe Krzeminski , Quentin Brulin , V. Cuny , Emmanuel Lecat , Evelyne Lampin , Fabrizio Cleri

We present a theory describing interaction of structured light, such as light carrying orbital angular momentum, with molecules. The light-matter interaction Hamiltonian we derive is expressed through couplings between spherical gradients…

Simulation of the interaction of light with matter, including at the few-photon level, is important for understanding the optical and optoelectronic properties of materials, and for modeling next-generation non-linear spectroscopies that…

Quantum Physics · Physics 2023-02-09 Steve M. Young , Hartmut Häffner , Mohan Sarovar

Based on density-functional perturbation theory we have computed from first principles the photoelastic tensor of few crystalline phases of silica at normal conditions and high pressure (quartz, $\alpha$-cristobalite, $\beta$-cristobalite)…

Condensed Matter · Physics 2016-08-31 D. Donadio , M. Bernasconi , F. Tassone

We investigate one of the consequences of the three competing models describing the mechanical interaction of light with a dielectric medium. According to both the Abraham and Minkowski models the time-averaged force density is zero inside…

Classical Physics · Physics 2013-05-02 Michiel de Reus , Neil V. Budko

The Schrodinger motion of a charged quantum particle in an electromagnetic potential can be simulated by the paraxial dynamics of photons propagating through a spatially inhomogeneous medium. The inhomogeneity induces geometric effects that…

Quantum Physics · Physics 2009-12-29 K. -P. Marzlin , Juergen Appel , A. I. Lvovsky

We theoretically investigate the interband transitions and quantum kinetics induced by light carrying orbital angular momentum, or twisted light, in bulk semiconductors. We pose the problem in terms of the Heisenberg equations of motion of…

Mesoscale and Nanoscale Physics · Physics 2011-02-24 G. F. Quinteiro , P. I. Tamborenea