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We present a new mechanism for a spin blockade effect associated with a change in the type of magnetic anisotropy over oxidation state in a single molecule transistor, by taking an example of an individual Eu$_{2}$(C$_{8}$H$_{8}$)$_{3}$…

Mesoscale and Nanoscale Physics · Physics 2016-11-23 Guangpu Luo , Kyungwha Park

By means of electronic transport, we study the transverse magnetic anisotropy of an individual Fe$_4$ single-molecule magnet (SMM) embedded in a three-terminal junction. In particular, we determine in situ the transverse anisotropy of the…

Mesoscale and Nanoscale Physics · Physics 2016-08-10 M. Misiorny , E. Burzurí , R. Gaudenzi , K. Park , M. Leijnse , M. R. Wegewijs , J. Paaske , A. Cornia , H. S. J. van der Zant

We analyze the electronic transport through a model spin-1 molecule as a function of temperature, magnetic field and bias voltage. We consider the effect of magnetic anisotropy, which can be generated experimentally by stretching the…

Strongly Correlated Electrons · Physics 2011-06-24 P. S. Cornaglia , P. Roura Bas , A. A. Aligia , C. A. Balseiro

We study the effect of magnetic anisotropy in a single electron transistor with ferromagnetic electrodes and a non-magnetic island. We identify the variation $\delta \mu$ of the chemical potential of the electrodes as a function of the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 J. Fernandez-Rossier , R. Aguado , L. Brey

We do parametric calculations to elucidate multi-terminal electron transport properties through a molecular system where a single phenalenyl molecule is attached to semi-infinite one-dimensional metallic leads. A formalism based on the…

Mesoscale and Nanoscale Physics · Physics 2010-05-25 Paramita Dutta , Santanu K. Maiti , S. N. Karmakar

Transistors, regardless of their size, rely on electrical gates to control the conductance between source and drain contacts. In atomic-scale transistors, this conductance is exquisitely sensitive to single electrons hopping via individual…

We examine theoretically coherent electron transport through the single-molecule magnet Mn$_{12}$, bridged between Au(111) electrodes, using the non-equilibrium Green's function method and the density-functional theory. We analyze the…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Kyungwha Park , Salvador Barraza-Lopez , Victor M. Garcia-Suarez , Jaime Ferrer

We present calculations of spin-dependent electron transport through single organic molecules bridging pairs of iron nanocontacts. We predict the magnetoresistance of these systems to switch from positive to negative with increasing applied…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Hugh Dalgleish , George Kirczenow

We investigate single molecule magnet transistors (SMMTs) with ligands that support transport resonances. We find the lowest unoccupied molecular orbitals of Mn12-benzoate SMMs (with and without thiol or methyl-sulfide termination) to be on…

Mesoscale and Nanoscale Physics · Physics 2011-11-23 Fatemeh Rostamzadeh Renani , George Kirczenow

The time-dependent transport through single-molecule magnets coupled to magnetic or non-magnetic electrodes is studied in the framework of the generalized master equation method. We investigate the transient regime induced by the periodic…

Mesoscale and Nanoscale Physics · Physics 2015-09-02 V. Moldoveanu , I. V. Dinu , B. Tanatar , C. P. Moca

Myoglobin single-electron transistors were investigated using nanometer- gap platinum electrodes fabricated by electromigration at cryogenic temperatures. Apomyoglobin (myoglobin without heme group) was used as a reference. The results…

Mesoscale and Nanoscale Physics · Physics 2013-12-16 Debin Li , Peter M. Gannet , David Lederman

Using first-principles methods we study theoretically the properties of an individual $\{Fe_4\}$ single-molecule magnet (SMM) attached to metallic leads in a single-electron transistor geometry. We show that the conductive leads do not…

Mesoscale and Nanoscale Physics · Physics 2014-07-01 J. F. Nossa , M. Fhokrul Islam , C. M. Canali , M. R. Pederson

We study a single electron transistor (SET) based upon a II-VI semiconductor quantum dot doped with a single Mn ion. We present evidence that this system behaves like a quantum nanomagnet whose total spin and magnetic anisotropy depend…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 J. Fernandez-Rossier , R. Aguado

We consider transport through a single N@C60 molecule, weakly coupled to metallic leads. Employing a density-matrix formalism we derive rate equations for the occupation probabilities of many-particle states of the molecule. We calculate…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Florian Elste , Carsten Timm

We consider electrical transport through molecules with Heisenberg-coupled spins arranged in a ring structure in the presence of an easy-axis anisotropy. The molecules are coupled to two metallic leads and a gate. In the charged state of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jörg Lehmann , Daniel Loss

We present an experimental and theoretical study of a magnetic single-molecule transistor based on N@C60 connected to gold electrodes. Particular attention is paid to the regime of intermediate molecule-lead coupling, where cotunneling…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Nicolas Roch , Romain Vincent , Florian Elste , Wolfgang Harneit , Wolfgang Wernsdorfer , Carsten Timm , Franck Balestro

We describe and analyze a tight-binding model of single molecule magnets (SMMs) that captures both the spin and spatial aspects of the SMM electronic structure. The model generalizes extended Huckel theory to include the effects of spin…

Mesoscale and Nanoscale Physics · Physics 2012-06-26 Fatemeh Rostamzadeh Renani , George Kirczenow

This article takes a broad view of the understanding of magnetic bistability and magnetic quantum tunneling in single-molecule magnets (SMMs), focusing on three families of relatively simple, low-nuclearity transition metal clusters: spin S…

We study numerically the low-temperature electronic transport properties of a single-ion magnet with uniaxial and transverse spin anisotropies. We find clear signatures of a Kondo effect caused by the presence of a transverse (zero-field)…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 Javier I. Romero , E. Vernek , G. B. Martins , E. R. Mucciolo

To understand the effect of molecular environment on the electronic and magnetic properties of the single-molecule magnet (SMM) Mn$_{12}$, we explore two possible means for adding extra electrons to molecule. We explore both substitution of…

Materials Science · Physics 2009-11-10 Kyungwha Park , Mark R. Pederson