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Circular dichroism (CD) spectra of chiral bare and thiol-passivated gold nanoclusters have been calculated within the dipole approximation. The calculated CD spectra show features that allow us to distinguish between clusters with different…

Materials Science · Physics 2007-05-23 Carlos E. Roman-Velazquez , Cecilia Noguez , Ignacio L. garzon

Circular dichroism (CD), induced by chirality, is an important tool for manipulating light or for characterizing morphology of molecules, proteins, crystals and nano-structures. CD is manifested over a wide size-range, from molecules to…

Explicit expressions for the wave functions and dispersion equation for the band p - electrons in single-wall carbon nanotubes are obtained within the method of zero-range potentials. They are then used to investigate the absorption…

Other Condensed Matter · Physics 2009-11-11 Vadim Adamyan , Sergey Tishchenko

Increasing the sensitivity of chiral spectroscopic techniques such as circular dichroism (CD) spectroscopy is a current aspiration in the research field of nanophotonics. Enhancing CD spectroscopy depends upon of two complementary…

Circular dichroism (CD), i.e. the differential response of a system to left and right circularly polarized light, is one of the only techniques capable of providing morphological information of certain samples. In biology, for instance, CD…

Circular dichroism is widely used for characterizing organic and biological materials, but measurements at a single molecule level are challenging because differences in absorption for opposite helicities are small. Here we show that…

Mesoscale and Nanoscale Physics · Physics 2014-01-23 A. Yokoyama , M. Yoshida , A. Ishii , Y. K. Kato

Utilizing the line-group symmetry of single-wall nanotubes, we have assigned their electron-energy bands by the symmetry-based quantum numbers. The selection rules for optical absorption are presented in terms of these quantum numbers.…

Soft Condensed Matter · Physics 2009-10-31 I. Bozovic , N. Bozovic , M. Damnjanovic

Chiral optical terahertz (THz) devices have significant technological implications for telecommunications, spectroscopy, and sensing. Engineering tunable, broadband, and cost-effective THz chiral materials has long been recognized as a…

The linear polarizability absorption spectra of the double-walled carbon nanotubes (DWNTs) have been calculated by using the tight-binding (TB) model and sum-over-state (SOS) method, supplemented by the first principles CASTEP calculations.…

Materials Science · Physics 2009-11-13 Xiaoping Yang , Jiangwei Chen , Hui Jiang , Jinming Dong

Circular dichroism (CD) is absorption difference of right-hand and left-hand circularly polarized light by components. CD spectroscopy technique is an important tool for detecting molecular chirality, but the molecular circular dichroism…

The near-field interaction of plasmonic nanostructures and chiral molecules induces circular dichroism in achiral nanostructure. The induced circular dichroism (ICD) strength is several orders greater than the molecular inherent CD (MCD),…

Two paramount challenges in carbon nanotube research are achieving chirality-controlled synthesis and understanding chirality-dependent device physics. High-throughput and in-situ chirality and electronic structural characterization of…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Kaihui Liu , Xiaoping Hong , Qin Zhou , Chenhao Jin , Jinghua Li , Weiwei Zhou , Jie Liu , Enge Wang , Alex Zettl , Feng Wang

We present a rigorous finite element method to calculate circular dichroism (CD) in various systems consisting of nanostructures and oriented chiral molecules with electric quadrupole transitions. The interaction between oriented molecule…

Optics · Physics 2017-12-27 Weixuan Zhang , Tong Wu , Rongyao Wang , Xiangdong Zhang

The ability to differentiate chiral molecules of different handedness is of great importance for chemical and life sciences. Since most of the relevant chiral molecules have their chiral transitions in the UV region, detecting their…

The theory of circular dichroism in single-wall carbon nanotubes derived within the tight-binding method by a complicated approach in previous work is rederived in a straightforward way using the multipolar expansion of the light-matter…

Mesoscale and Nanoscale Physics · Physics 2025-10-02 S. V. Goupalov

Circular Dichroism (CD) spectroscopy has evolved from a purely solution based method towards a powerful tool in the analysis of chiral thin films. Although a straightforward technique, the genuine CD signal is often accompanied by artifacts…

We consider chirality related effects in optical, photogalvanic and electron-transport properties of carbon nanotubes. We show that these properties of chiral nanotubes are determined by terms in the electron effective Hamiltonian…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 E. L. Ivchenko , B. Spivak

Circular dichroism (CD) spectroscopy is a useful technique for characterizing chiral molecules. It is more sensitive than total absorption to molecule conformation, and it is routinely used to identify enantiomers. We present here a first…

Chemical Physics · Physics 2022-12-14 Elena Molteni , Giancarlo Cappellini , Davide Sangalli

Determination of optical absorption cross-section is always among the central importance of understanding a material. However its realization on individual nanostructures, such as carbon nanotubes, is experimentally challenging due to the…

Single-walled carbon nanotubes exist in a variety of different geometries, so-called chiralities, that define their electronic properties. Chiral selectivity has been reported in catalytic chemical vapor deposition synthesis experiments,…

Mesoscale and Nanoscale Physics · Physics 2024-06-12 Georg Daniel Förster , Thomas D. Swinburne , Hua Jiang , Esko Kauppinen , Christophe Bichara
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