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Atomically sharp oxide heterostructures often exhibit unusual physical properties that are absent in the constituent bulk materials. The interplay between electrostatic boundary conditions, strain and dimensionality in ultrathin epitaxial…

Ferroelectric (FE) metals have been attracting attention as they possess both metallicity and ferroelectricity, the two seemingly incompatible physical properties. An important problem for both fundamental research and potential…

Materials Science · Physics 2022-03-22 Sheng Xu , Yanni Gu , Chuanbo Zheng , Xiao Shen

Composite materials comprised of ferroelectric nanoparticles in a dielectric matrix are being actively investigated for a variety of functional properties attractive for a wide range of novel electronic and energy harvesting devices.…

Mesoscale and Nanoscale Physics · Physics 2017-01-11 John Mangeri , Yomery Espinal , Andrea Jokisaari , S. Pamir Alpay , Serge Nakhmanson , Olle Heinonen

Harvesting low-grade heat to electricity is attractive for powering wearable electronic devices. Here, we demonstrate nW-scale thermoelectric power generation in devices from thin film assemblies of microwave-synthesized p-Sb2Te3 nanoplates…

The direction of ferroelectric polarization is prescribed by the symmetry of the crystal structure. Therefore, rotation of the polarization direction is largely limited, despite the opportunity it offers in understanding important…

We report density functional studies of electron rich interfaces between KTaO3 or KNbO3 and CaSnO3 or ZnSnO3 and in particular the nature of the interfacial electron gasses that can be formed. We find that depending on the details these may…

Materials Science · Physics 2014-03-17 X. F. Fan , W. T. Zheng , X. Chen , D. J. Singh

Doped HfO2 thin films exhibit robust ferroelectric properties even for nanometric thicknesses, are compatible with current Si technology and thus have great potential for the revival of integrated ferroelectrics. Phase control and…

Epitaxial strain provides important pathways to control the magnetic and electronic states in transition metal oxides. However, the large strain is usually accompanied by a strong reduction of the oxygen vacancy formation energy, which…

The spectacular metal-to-insulator transition of V2O3 can be progressively suppressed in thin film samples. Evidence for phase separation was observed using microbridges as a mesoscopic probe of transport properties where the same film…

Materials Science · Physics 2009-11-13 C. Grygiel , A. Pautrat , W. C. Sheets , W. Prellier , B. Mercey , L. Mechin

The atomic structures at epitaxial film-substrate interfaces determine scalability of thin films and can result in new phenomena. However, it is challenging to control the interfacial structures since they are decided by the most stable…

Materials Science · Physics 2025-09-09 Xin Li , Yu Yun , Guodong Ren , Arashdeep Singh Thind , Amit Kumar Shah , Rohan Mishra , Xiaoshan Xu

An emerging area in condensed matter physics is the use of multilayered heterostructures to enhance ferroelectricity in complex oxides. Here, we demonstrate that optically pumping carriers across the interface between thin films of a…

Materials Science · Physics 2013-07-12 Y. M. Sheu , S. A. Trugman , L. Yan , C. -P. Chuu , Z. Bi , Q. X. Jia , A. J. Taylor , R. P. Prasankumar

The evolution of tetragonality with thickness has been probed in epitaxial c-axis oriented PbTiO3 films with thicknesses ranging from 500 down to 24 Angstroms. High resolution x-ray pointed out a systematic decrease of the c-axis lattice…

Materials Science · Physics 2009-11-10 Celine Lichtensteiger , Jean-Marc Triscone , Javier Junquera , Philippe Ghosez

Proximity to phase transitions (PTs) is frequently responsible for the largest dielectric susceptibilities in ferroelectrics. The impracticality of using temperature as a control parameter to reach those large responses has motivated the…

We propose the thermodynamical theory of nanodomain tailoring with the help of atomic force microscope electric field in thin ferroelectric-semiconductor films. We modified the existing thermodynamical models of domain formation allowing…

Materials Science · Physics 2007-05-23 Anna N. Morozovska , Eugene A. Eliseev

Using Landau-Ginzburg-Devonshire theory, we considered the impact of the flexoelectro-chemical coupling on the size effects inpolar properties and phase transitions of thin ferroelectric films with a layer of elastic defects. We…

Thin films of aluminum hafnium nitride (Al$_{1-x}$Hf$_{x}$N) were synthesized via reactive magnetron sputtering for Hf contents up to $x$ = 0.13. X-ray diffraction showed a single $c$-axis oriented wurtzite phase for all films. Hard X-ray…

Ferroelectric control of two-dimensional magnetism is promising in fabricating electronic devices with high speed and low energy consumption. The newly discovered layered MnBi$_2$Te$_4$(Bi$_2$Te$_3$)$_n$ and their Sb counterparts exhibit…

Materials Science · Physics 2023-09-29 Guoliang Yu , Chuhan Tang , Zhiqiang Tian , Ziming Zhu , Anlian Pan , Mingxing Chen , Xing-Qiu Chen

The electronic and magnetic properties in ABO3 perovskite oxides are extremely sensitive to lattice structure but also the dimensionality, such as the thickness in thin film form. Here, we report the thickness-dependent electro-magnetic…

Materials Science · Physics 2022-12-26 Zeeshan Ali , Mohammad Saghayezhian , Prahald Siwakoti , Roshan Nepal , Jiandi Zhang

Intrinsic magnetoelectric coupling describes the interaction between magnetic and electric polarization through an inherent microscopic mechanism in a single phase material. This phenomenon has the potential to control the magnetic state of…

Cation displacements, oxygen octahedral tilts, and magnetism of epitaxial, ferrimagnetic, insulating GdTiO3 films sandwiched between cubic SrTiO3 layers are studied using scanning transmission electron microscopy and magnetization…

Strongly Correlated Electrons · Physics 2013-11-05 Jack Y. Zhang , Clayton A. Jackson , Santosh Raghavan , Jinwoo Hwang , Susanne Stemmer