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We determined the magnetic structure of CuCr$_2$O$_4$ using neutron diffraction and irreducible representation analysis. The measurements identified a new phase between 155 K and 125 K as nearly collinear magnetic ordering in the Cr…

Strongly Correlated Electrons · Physics 2018-03-20 K. Tomiyasu , S. Lee , H. Ishibashi , Y. Takahashi , T. Kawamata , Y. Koike , T. Nojima , S. Torii , T. Kamiyama

Motivated by recent experimental progress in transition metal oxides with the K$_2$NiF$_4$ structure, we investigate the magnetic and orbital ordering in $\alpha$-Sr$_2$CrO$_4$. Using first principles calculations, first we derive a…

Strongly Correlated Electrons · Physics 2021-01-20 Bradraj Pandey , Yang Zhang , Nitin Kaushal , Rahul Soni , Ling-Fang Lin , Wen-Jun Hu , Gonzalo Alvarez , Elbio Dagotto

KCrF3 represents another prototypical orbital-ordered perovskite, where Cr2+ possesses the same electronic configuration of 3d4 as that of strongly Jahn-Teller distorted Mn3+ in many CMR manganites. The crystal and magnetic structures of…

Strongly Correlated Electrons · Physics 2013-09-30 Y. Xiao , Y. Su , H. -F. Li , C. M. N. Kumar , R. Mittal , J. Persson , A. Senyshyn , K. Gross , Th. Brueckel

We report the synthesis, structure and physical properties of a new quaternary nitride LaCr$_2$Ge$_2$N. The compound crystallizes in the CeCr$_2$Si$_2$C-type structure (P4/mmm), featuring distinctive Cr$_2$N square sheets within…

The two-dimensional character of van der Waals magnets allows for efficient control of their properties via proximity effects and electrical stimuli, making them promising candidates for application in spin-electronics. We use…

X-ray and Neutron diffraction as well as muon spin relaxation and M\"ossbauer experiments performed on SrFe$_2$As$_2$ polycrystalls confirm a sharp first order transition at $T_0 = 205$,K corresponding to an orthorhombic phase distortion…

We found, using density-functional theory calculations within the generalized gradient approximation, that Cs$_2$AgF$_4$ is stabilized in the insulating orthorhombic phase rather than in the metallic tetragonal phase. The lattice distortion…

Materials Science · Physics 2007-10-23 Hua Wu , D. I. Khomskii

Cr2Ge2Te6 is an intrinsic ferromagnetic semiconductor with van der Waals type layered structure, thus represents a promising material for novel electronic and spintronic devices. Here we combine scanning tunneling microscopy and…

Materials Science · Physics 2019-05-08 Zhenqi Hao , Haiwei Li , Shunhong Zhang , Xintong Li , Gaoting Lin , Xuan Luo , Yuping Sun , Zheng Liu , Yayu Wang

The electronic band structures of orthorhombic (oP28) and monoclinic (mC28) MnSb_2S_4 were investigated with ab initio calculations in the local spin density approximation (LSDA) to the density functional theory (DFT). An analysis of the…

Materials Science · Physics 2016-08-31 S. F. Matar , R. Weihrich , D. Kurowski , A. Pfitzner , V. Eyert

Recent years have seen a vast increase in research into van der Waals magnetic materials. In many of these systems, magnetism is introduced via light 3\textit{d}-transition metal elements, combined with chalcogenides or halogens. Despite…

We investigate the origin of the orbital ordering in the paramagnetic phase of KCrF$_3$. All previous studies described structural parameters of the paramagnetic phase using a magnetic ordering in the compound. Our simulations of real…

Strongly Correlated Electrons · Physics 2016-08-24 D. Novoselov , Dm. M. Korotin , V. I. Anisimov

Resonant x-ray diffraction performed at the $\rm L_{II}$ and $\rm L_{III}$ absorption edges of Ru has been used to investigate the magnetic and orbital ordering in Ca$_2$RuO$_4$ single crystals. A large resonant enhancement due to electric…

With the use of the density function calculations we show that the actual crystal structure of Cs$_2$CuCl$_2$Br$_2$ should contain elongated in the $ab-$plane CuCl$_4$Br$_2$ octahedra, in contrast to the experimentally observed compression…

Strongly Correlated Electrons · Physics 2012-08-09 S. V. Streltsov , D. I. Khomskii

We report neutron scattering and transport measurements on semiconducting Rb$_{0.8}$Fe$_{1.5}$S$_2$, a compound isostructural and isoelectronic to the well-studied $A_{0.8}$Fe$_{y}$Se$_2 (A=$ K, Rb, Cs, Tl/K) superconducting systems. Both…

Superconductivity · Physics 2014-09-30 Meng Wang , Wei Tian , P. Valdivia , Songxue Chi , E. Bourret-Courchesne , Pengcheng Dai , R. J. Birgeneau

Magnetic ordering in the geometrically frustrated magnetic oxide spinels MgCr_2O_4 and ZnCr_2O_4 is accompanied by a structural change that helps relieve the frustration. Analysis of high-resolution synchrotron X-ray scattering reveals that…

Cr$_{1+\delta}$Te$_2$, a two-dimensional van der Waals ferromagnet, displays a contested magnetic structure, poised between collinear and non-collinear spin configurations. In this work, we investigate the magnetic structure of…

Inelastic neutron scattering is employed to study the reciprocal-space structure and dispersion of magnetic excitations in the normal and superconducting states of single-crystalline Rb0.8Fe1.6Se2. We show that the recently discovered…

The two-dimensional (2D) material Cr$_2$Ge$_2$Te$_6$ is a member of the class of insulating van der Waals magnets. Here, using high resolution angle-resolved photoemission spectroscopy in a detailed temperature dependence study, we identify…

The chromium arsenides BaCr2As2 and BaCrFeAs2 with ThCr2Si2 type structure (space group I4/mmm; also adopted by '122' iron arsenide superconductors) have been suggested as mother compounds for possible new superconductors. DFT-based…

Depending on the crystal growth conditions, an orthorhombic (O-type) or a tetragonal (T-type) structure can be found in the solid solution Cs2CuCl4-xBrx (0 < x < 4). Here we present measurements of the temperature-dependent magnetic…

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