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The evolution of electron conductance in the presence of inelastic effects is studied as an atomic gold contact is formed evolving from a low-conductance regime (tunneling) to a high-conductance regime (contact). In order to characterize…

Mesoscale and Nanoscale Physics · Physics 2007-06-25 Thomas Frederiksen , Nicolas Lorente , Magnus Paulsson , Mads Brandbyge

The conducting and thermodynamic properties of ballistic metallic nanocontacts with smooth shapes are investigated. All properties are related to the electronic scattering matrix, which is evaluated in the WKB approximation for independent…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 C. A. Stafford , F. Kassubek , J. Bürki , H. Grabert , D. Baeriswyl

Using density functional theory (DFT), we analyze the influence of five classes of functional groups, as exemplified by NO2, OCH3, CH3, CCl3, and I, on the transport properties of a 1,4-benzenedithiolate (BDT) and 1,4-benzenediamine (BDA)…

Materials Science · Physics 2010-01-14 D. J. Mowbray , G. Jones , K. S. Thygesen

We demonstrate that electronic transport through single molecules or molecular ensembles, commonly based on gold (Au) electrodes, can be extended to superconducting electrodes by combining gold with molybdenum-rhenium (MoRe). This…

Mesoscale and Nanoscale Physics · Physics 2015-07-23 R. Gaudenzi , J. O. Island , J. de Bruijckere , E. Burzuri , T. M. Klapwijk , H. S. J. van der Zant

In the field of molecular electronics, particularly in quantum transport studies, the orientation of molecules plays a crucial role. This orientation, with respect to the electrodes, can be defined through the cavity of ring-shaped…

Materials Science · Physics 2023-02-17 A. Martinez-Garcia , T. de Ara , L. Pastor-Amat , C. Untiedt , E. B. Lombardi , W. Dednam , C. Sabater

Thermal conduction in polymer nanocomposites depends on several parameters including the thermal conductivity and geometrical features of the nanoparticles, the particle loading, their degree of dispersion and formation of a percolating…

Applied Physics · Physics 2021-01-25 Alessandro di Pierro , Alberto Fina

We simulate the electronic and transport properties of metal/two-dimensional material/metal vertical heterostructures, with a focus on graphene, hexagonal boron nitride and two phases of molybdenum diselenide. Using density functional…

Mesoscale and Nanoscale Physics · Physics 2025-02-06 Gaëlle Bigeard , Zineb Kerrami , François Triozon , Alessandro Cresti

Using a density-functional-based transport method we study the conduction properties of several biphenyl-derived dithiol (BPDDT) molecules wired to gold electrodes. The BPDDT molecules differ in their side groups, which control the degree…

Mesoscale and Nanoscale Physics · Physics 2009-05-24 F. Pauly , J. K. Viljas , J. C. Cuevas , Gerd Schön

We have performed first-principles calculations for the mechanic and electric properties of pure Pt nano-contacts and a Pt contact with a single CO molecule adsorbed. For the pure Pt contacts we see a clear difference between point contacts…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 M. Strange , K. S. Thygesen , K. W. Jacobsen

The transport properties of nanostructured systems are deeply affected by the geometry of the effective connections to metallic leads. In this work we derive a conductance expression for interacting systems whose connectivity geometries do…

Mesoscale and Nanoscale Physics · Physics 2017-09-15 Luis G. G. V. Dias da Silva , Caio H. Lewenkopf , Edson Vernek , Gerson J. Ferreira , Sergio E. Ulloa

The interplay between groups of water molecules and single-atom contacts, as reflected in the electrical conductances and mechanical forces of copper atomic junctions, is explored by means of first-principles theory and semi-empirical…

Mesoscale and Nanoscale Physics · Physics 2020-05-19 Alireza Saffarzadeh , George Kirczenow

Ambipolar charge carrier transport in Copper phthalocyanine (CuPc) is studied experimentally in field-effect transistors and metal-insulator-semiconductor diodes at various temperatures. The electronic structure and the transport properties…

Mesoscale and Nanoscale Physics · Physics 2015-03-13 C. Schuster , M. Kraus , A. Opitz , W. Brütting , U. Eckern

We investigate charge transport in pentacene-graphene nanojunctions employing density functional theory (DFT) electronic structure calculations and the Landauer transport formalism. The results show that the unique electronic properties of…

Mesoscale and Nanoscale Physics · Physics 2013-02-26 Ivan A. Pshenichnyuk , Pedro B. Coto , Susanne Leitherer , Michael Thoss

Using density functional theory combined with nonequilibrium Green's function method, the transport properties of borophene-based nano gas sensors with gold electrodes are calculated, and comprehensive understandings regarding the effects…

Mesoscale and Nanoscale Physics · Physics 2021-06-29 Yueyue Tian , Houping Yang , Junjun Li , Shunbo Hu , Shixun Cao , Wei Ren , Yin Wang

Vibrationally inelastic electron transport through a flexible molecular junction is investigated. The study is based on a mechanistic model for a biphenyl molecule between two metal electrodes. Employing methods from electron-molecule…

Mesoscale and Nanoscale Physics · Physics 2023-07-26 Martin Cizek , Michael Thoss , Wolfgang Domcke

The interaction between electronic and vibrational degrees of freedom is an important mechanism in nonequilibrium charge transport through molecular nanojunctions. While adiabatic polaron-type coupling has been studied in great detail, new…

Mesoscale and Nanoscale Physics · Physics 2022-06-10 Christoph Kaspar , André Erpenbeck , Jakob Bätge , Christian Schinabeck , Michael Thoss

We study the transport properties of a twisted bilayer graphene flake contacted by two monolayer nanoribbons which act as leads. We analyze the conductance in terms of the spectra of the bilayer nanoribbon and the monolayer contacts. The…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 M. Pelc , E. Suárez Morell , L. Brey , L. Chico

We analyze the formation and evolution statistics of single molecule junctions bonded to gold electrodes using amine, methyl sulfide and dimethyl phosphine link groups by measuring conductance as a function of junction elongation. For each…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 M. Kamenetska , M. Koentopp , A. C. Whalley , Y. S. Park , M. L. Steigerwald , C. Nuckolls , M. S. Hybertsen , L. Venkataraman

The integration of functional molecules onto conductive or dielectric surfaces represents a promising avenue for employing molecule-centric technologies, encompassing sensor development, electrochromic, and the facilitation of charge and…

Materials Science · Physics 2024-01-17 Rajwinder Kaur , Bijai Singh , Vikram Singh , Prakash Chandra Mondal

Linear conductance of junctions formed by graphene flakes with order of nanometer-thick electrodes attached at the corners of the flakes is studied. The explored structures have sizes up to 20000 atoms and the conductance is studied as a…

Mesoscale and Nanoscale Physics · Physics 2015-10-08 Martin Konôpka