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A molecular theory of the glass transition of network forming liquids is developed using a combination of self-consistent phonon and liquid state approaches. Both the dynamical transition and the entropy crisis characteristic of random…

Condensed Matter · Physics 2009-11-07 Randall W. Hall , Peter G. Wolynes

Using the inherent structure formalism originally proposed by Stillinger and Weber [Phys. Rev. A 25, 978 (1982)], we generalize the thermodynamics of an energy landscape that has an ideal glass transition and derive the consequences for its…

Soft Condensed Matter · Physics 2009-11-07 M. S. Shell , P. G. Debenedetti , E. La Nave , F. Sciortino

Fluids consisting of hard platelike particles near a hard wall are investigated using density functional theory. The density and orientational profiles as well as the surface tension and the excess coverage are determined and compared with…

Statistical Mechanics · Physics 2009-11-07 L. Harnau , S. Dietrich

We consider a one-dimensional system comprising of $N$ run-and-tumble particles confined in a harmonic trap interacting via a repulsive inverse-square power-law interaction. We numerically compute the global density profile in the steady…

We consider crystal formation of particles with dipole-dipole interactions that are confined to move in a one-dimensional helical geometry with their dipole moments oriented along the symmetry axis of the confining helix. The stable…

Quantum Gases · Physics 2014-08-12 J. K. Pedersen , D. V. Fedorov , A. S. Jensen , N. T. Zinner

The classic Kob-Andersen (KA) binary Lennard-Jones mixtures which are designed to prevent crystallization has been extensively studied in simulation of slow dynamics. Although crystallization can occur if a liquid system is cooled slowly,…

Soft Condensed Matter · Physics 2017-03-10 Penghui Cao

We analyze the sedimentation behavior of a polydisperse two-dimensional liquid-crystal fluid using a local density functional theory based on scaled particle theory. Polydispersity is incorporated through variations in the roundness of hard…

Soft Condensed Matter · Physics 2025-11-11 Tobias Eckert , Daniel de las Heras , Enrique Velasco , Yuri Martínez-Ratón

A one-dimensional long-range model of classical rotators with an extended degree of complexity, as compared to paradigmatic long-range systems, is introduced and studied. Working at constant density, in the thermodynamic limit one can prove…

Statistical Mechanics · Physics 2015-09-03 Alessio Turchi , Duccio Fanelli , Xavier Leoncini

Structural aspects of crystal nucleation in undercooled liquids are explored using a nonlinear hydrodynamic theory of crystallization proposed recently [G. I. Toth et al., J. Phys.: Condens. Matter 26, 055001 (2014)], which is based on…

Materials Science · Physics 2017-05-24 Frigyes Podmaniczky , Gyula I. Toth , Gyorgy Tegze , Laszlo Granasy

In this note, we show that the Local Molecular Field theory of Weeks et. al. can be re-derived as an extremum problem for an approximate Helmholtz free energy. Using the resulting free energy as a classical, fluid density functional yields…

Soft Condensed Matter · Physics 2025-07-15 David M. Rogers

The topography of the free energy landscape in phase space of a dense hard sphere system characterized by a discretized free energy functional of the Ramakrishnan-Yussouff form is investigated numerically using a ``microcanonical'' Monte…

Disordered Systems and Neural Networks · Physics 2007-05-23 Chandan Dasgupta , Oriol T. Valls

Based on density-functional theory we analyze the full phase diagram, the occurrence of long-ranged orientational order, and the structural properties of dipolar fluids. As a model system we consider the Stockmayer fluid that consists of…

Soft Condensed Matter · Physics 2009-09-25 B. Groh , S. Dietrich

We experimentally investigate the crystallization of a uniformly heated quasi-2D granular fluid as a function of filling fraction. Our experimental results for the Lindemann melting criterion, the radial distribution function, the bond…

Soft Condensed Matter · Physics 2009-11-11 Pedro M. Reis , Rohit A. Ingale , Mark D. Shattuck

The rotationally-covariant renormalization group equations of motion for the density wave amplitudes in the phase field crystal model are shown to follow from a dynamical equation driven by an effective free energy density that we derive.…

Materials Science · Physics 2009-12-23 Pak Yuen Chan , Nigel Goldenfeld

Three structural populations with distinct average mobility are identified within an equilibrium two-dimensional Lennard-Jones fluid simulated via molecular dynamics at a constant temperature and varying density. Quantifying the structure…

Soft Condensed Matter · Physics 2018-02-05 Tamoghna Das , Jack F. Douglas

The relaxation dynamics of a model fluid of platelike colloidal particles is investigated by means of a phenomenological dynamic density functional theory. The model fluid approximates the particles within the Zwanzig model of restricted…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Rene van Roij

Different computational techniques in combination with molecular dynamics computer simulation are used to to determine the wall-liquid and the wall-crystal interfacial free energies of a modified Lennard-Jones (LJ) system in contact with a…

Statistical Mechanics · Physics 2015-06-16 Ronald Benjamin , Jürgen Horbach

We show that nonlinear continuum elasticity can be effective in modeling plastic flows in crystals if it is viewed as Landau theory with an infinite number of equivalent energy wells whose configuration is dictated by the symmetry group…

Materials Science · Physics 2019-11-20 R. Baggio , E. Arbib , P. Biscari , S. Conti , L. Truskinovsky , G. Zanzotto , O. U. Salman

The interplay between densification and positional ordering during the process of crystal nucleation is a greatly investigated topic. Even for the simplest colloidal model -- hard spheres -- there has been much debate regarding the…

Soft Condensed Matter · Physics 2025-02-19 Marjolein de Jager , Nena Slaats , Laura Filion

The dilute fluid phase of model globular proteins is studied. The model possesses a fluid-fluid transition buried within the fluid-crystal coexistence region, as do some globular proteins. If this fluid-fluid transition is not buried deep…

Soft Condensed Matter · Physics 2007-05-23 Richard P. Sear