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We consider viscous, heat conducting mixtures of molecularly miscible chemical species forming a fluid in which the constituents can undergo chemical reactions. Assuming a common temperature for all components, we derive a closed system of…

Fluid Dynamics · Physics 2016-04-01 Dieter Bothe , Wolfgang Dreyer

We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…

Statistical Mechanics · Physics 2011-06-13 P. D. Gujrati

A Hamiltonian-based model of many harmonically interacting massive particles that are subject to linear friction and coupled to heat baths at different temperatures is used to study the dynamic approach to equilibrium and non-equilibrium…

Statistical Mechanics · Physics 2020-09-17 Roland R. Netz

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

Mathematical Physics · Physics 2014-11-21 Gian Paolo Beretta , Enzo Zanchini

It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…

Statistical Mechanics · Physics 2015-05-14 J. M. Deutsch

We provide an extension of a recent approach to study non-equilibrium thermodynamics [Phys. Rev. E 81, 051130 (2010), to be denoted by I in this work] to inhomogeneous systems by considering the latter to be composed of quasi-independent…

Statistical Mechanics · Physics 2013-05-30 P. D. Gujrati

Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions.…

Statistical Mechanics · Physics 2009-11-07 F. Leyvraz , S. Ruffo

The property of Tsallis entropy is examined when considering tow systems with different temperatures to be in contact with each other and to reach the thermal equilibrium. It is verified that the total Tsallis entropy of the two systems…

Statistical Mechanics · Physics 2015-08-10 Jiulin Du

In this work the non-additive entropy is examined. It appears in isolated particle systems composed of few components. Therefore, the mixing of isolated particle systems S=S1+S2 has been studied. Two cases are considered T1=T2 and T1\leqT2,…

General Physics · Physics 2012-11-13 Miriam Lemanska

The microcanonical entropy s(e,m) as a function of the energy e and the magnetization m is computed analytically for the anisotropic quantum Heisenberg model with Curie-Weiss-type interactions. The result shows a number of interesting…

Statistical Mechanics · Physics 2010-07-02 Michael Kastner

Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called ``caloric'') in transformations that are not isochoric (i.e.…

Statistical Mechanics · Physics 2007-05-23 Giovanni Gallavotti

Whether long-range interactions allow for a form of causality in non-relativistic quantum models remains an open question with far-reaching implications for the propagation of information and thermalization processes. Here, we study the…

Quantum Physics · Physics 2022-03-31 J. T. Schneider , J. Despres , S. J. Thomson , L. Tagliacozzo , L. Sanchez-Palencia

The generalized zeroth law of thermodynamics indicates that the physical temperature in nonextensive statistical mechanics is different from the inverse of the Lagrange multiplier, beta. This leads to modifications of some of thermodynamic…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , S. Martinez , F. Pennini , A. Plastino

The one-dimensional Ising model in an external magnetic field with uniform long-range interactions and random short-range interactions satisfying bimodal annealed distributions is studied. This generalizes the random model discussed by…

Statistical Mechanics · Physics 2009-10-31 A. P. Vieira , L. L. Goncalves

Development of thermodynamic induction up to second order gives a dynamical bifurcation for thermodynamic variables and allows for the prediction and detailed explanation of nonequilibrium phase transitions with associated spontaneous…

Statistical Mechanics · Physics 2021-10-07 S. N. Patitsas

Entropy is a quantity for counting physical degrees of freedom in a system. At a finite temperature, one can use thermal entropy to study thermodynamical properties. At zero temperature, entanglement entropy is expected to provide a…

High Energy Physics - Theory · Physics 2018-10-29 Chen-Te Ma

We describe in detail two numerical simulation methods valid to study systems whose thermostatistics is described by generalized entropies, such as Tsallis. The methods are useful for applications to non-trivial interacting systems with a…

Statistical Mechanics · Physics 2009-10-31 R. Salazar , R. Toral

We derive generic properties of nonequilibrium phase transitions in all-to-all Ising models placed in contact with two thermal reservoirs, in which parameters (temperatures, interactions and field parameters) assume arbitrary values…

Statistical Mechanics · Physics 2026-04-03 Iago N. Mamede , Bart Cleuren , Carlos. E. Fiore

In recent years, studies of long-range interacting (LRI) systems have taken centre stage in the arena of statistical mechanics and dynamical system studies, due to new theoretical developments involving tools from as diverse a field as…

Statistical Mechanics · Physics 2017-04-05 Shamik Gupta , Stefano Ruffo

Open quantum systems are studied from the thermodynamical point of view unifying the principle of maximum informational entropy and the hypothesis of relaxation times hierarchy. The result of the unification is a non-Markovian and local in…

Quantum Physics · Physics 2014-11-24 Vitalii Semin , Francesco Petruccione